Ionic liquid catalyst helps turn emissions into fuel

ScienceDaily (Oct. 7, 2011) — An Illinois research team has succeeded in overcoming one major obstacle to a promising technology that simultaneously reduces atmospheric carbon dioxide and produces fuel.

University of Illinois chemical and biological engineering professor Paul Kenis and his research group joined forces with researchers at Dioxide Materials, a startup company, to produce a catalyst that improves artificial photosynthesis. The company, in the university Research Park, was founded by retired chemical engineering professor Richard Masel. The team reported their results in the journal Science.

Artificial photosynthesis is the process of converting carbon dioxide gas into useful carbon-based chemicals, most notably fuel or other compounds usually derived from petroleum, as an alternative to extracting them from biomass.

In plants, photosynthesis uses solar energy to convert carbon dioxide (CO2) and water to sugars and other hydrocarbons. Biofuels are refined from sugars extracted from crops such as corn. However, in artificial photosynthesis, an electrochemical cell uses energy from a solar collector or a wind turbine to convert CO2 to simple carbon fuels such as formic acid or methanol, which are further refined to make ethanol and other fuels.

"The key advantage is that there is no competition with the food supply," said Masel, a co-principal investigator of the paper and CEO of Dioxide Materials, "and it is a lot cheaper to transmit electricity than it is to ship biomass to a refinery."

However, one big hurdle has kept artificial photosynthesis from vaulting into the mainstream: The first step to making fuel, turning carbon dioxide into carbon monoxide, is too energy intensive. It requires so much electricity to drive this first reaction that more energy is used to produce the fuel than can be stored in the fuel.

The Illinois group used a novel approach involving an ionic liquid to catalyze the reaction, greatly reducing the energy required to drive the process. The ionic liquids stabilize the intermediates in the reaction so that less electricity is needed to complete the conversion.

The researchers used an electrochemical cell as a flow reactor, separating the gaseous CO2 input and oxygen output from the liquid electrolyte catalyst with gas-diffusion electrodes. The cell design allowed the researchers to fine-tune the composition of the electrolyte stream to improve reaction kinetics, including adding ionic liquids as a co-catalyst.

"It lowers the overpotential for CO2 reduction tremendously," said Kenis, who is also a professor of mechanical science and engineering and affiliated with the Beckman Institute for Advanced Science and Technology. "Therefore, a much lower potential has to be applied. Applying a much lower potential corresponds to consuming less energy to drive the process."

Next, the researchers hope to tackle the problem of throughput. To make their technology useful for commercial applications, they need to speed up the reaction and maximize conversion.

"More work is needed, but this research brings us a significant step closer to reducing our dependence on fossil fuels while simultaneously reducing CO2 emissions that are linked to unwanted climate change," Kenis said.

Graduate students Brian Rosen, Michael Thorson, Wei Zhu and Devin Whipple and postdoctoral researcher Amin Salehi-Khojin were co-authors of the paper. The U.S. Department of Energy supported this work.

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The above story is reprinted (with editorial adaptations by ScienceDaily staff) from materials provided by University of Illinois at Urbana-Champaign.

Journal Reference:

B. A. Rosen, A. Salehi-Khojin, M. R. Thorson, W. Zhu, D. T. Whipple, P. J. A. Kenis, R. I. Masel. Ionic Liquid-Mediated Selective Conversion of CO2 to CO at Low Overpotentials. Science, 2011; DOI: 10.1126/science.1209786

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Disclaimer: Views expressed in this article do not necessarily reflect those of ScienceDaily or its staff.

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Ionic liquid catalyst helps turn emissions into fuel

ScienceDaily (Oct. 7, 2011) — An Illinois research team has succeeded in overcoming one major obstacle to a promising technology that simultaneously reduces atmospheric carbon dioxide and produces fuel.

University of Illinois chemical and biological engineering professor Paul Kenis and his research group joined forces with researchers at Dioxide Materials, a startup company, to produce a catalyst that improves artificial photosynthesis. The company, in the university Research Park, was founded by retired chemical engineering professor Richard Masel. The team reported their results in the journal Science.

Artificial photosynthesis is the process of converting carbon dioxide gas into useful carbon-based chemicals, most notably fuel or other compounds usually derived from petroleum, as an alternative to extracting them from biomass.

In plants, photosynthesis uses solar energy to convert carbon dioxide (CO2) and water to sugars and other hydrocarbons. Biofuels are refined from sugars extracted from crops such as corn. However, in artificial photosynthesis, an electrochemical cell uses energy from a solar collector or a wind turbine to convert CO2 to simple carbon fuels such as formic acid or methanol, which are further refined to make ethanol and other fuels.

"The key advantage is that there is no competition with the food supply," said Masel, a co-principal investigator of the paper and CEO of Dioxide Materials, "and it is a lot cheaper to transmit electricity than it is to ship biomass to a refinery."

However, one big hurdle has kept artificial photosynthesis from vaulting into the mainstream: The first step to making fuel, turning carbon dioxide into carbon monoxide, is too energy intensive. It requires so much electricity to drive this first reaction that more energy is used to produce the fuel than can be stored in the fuel.

The Illinois group used a novel approach involving an ionic liquid to catalyze the reaction, greatly reducing the energy required to drive the process. The ionic liquids stabilize the intermediates in the reaction so that less electricity is needed to complete the conversion.

The researchers used an electrochemical cell as a flow reactor, separating the gaseous CO2 input and oxygen output from the liquid electrolyte catalyst with gas-diffusion electrodes. The cell design allowed the researchers to fine-tune the composition of the electrolyte stream to improve reaction kinetics, including adding ionic liquids as a co-catalyst.

"It lowers the overpotential for CO2 reduction tremendously," said Kenis, who is also a professor of mechanical science and engineering and affiliated with the Beckman Institute for Advanced Science and Technology. "Therefore, a much lower potential has to be applied. Applying a much lower potential corresponds to consuming less energy to drive the process."

Next, the researchers hope to tackle the problem of throughput. To make their technology useful for commercial applications, they need to speed up the reaction and maximize conversion.

"More work is needed, but this research brings us a significant step closer to reducing our dependence on fossil fuels while simultaneously reducing CO2 emissions that are linked to unwanted climate change," Kenis said.

Graduate students Brian Rosen, Michael Thorson, Wei Zhu and Devin Whipple and postdoctoral researcher Amin Salehi-Khojin were co-authors of the paper. The U.S. Department of Energy supported this work.

Recommend this story on Facebook, Twitter,
and Google +1:

Other bookmarking and sharing tools:

Story Source:

The above story is reprinted (with editorial adaptations by ScienceDaily staff) from materials provided by University of Illinois at Urbana-Champaign.

Journal Reference:

B. A. Rosen, A. Salehi-Khojin, M. R. Thorson, W. Zhu, D. T. Whipple, P. J. A. Kenis, R. I. Masel. Ionic Liquid-Mediated Selective Conversion of CO2 to CO at Low Overpotentials. Science, 2011; DOI: 10.1126/science.1209786

Note: If no author is given, the source is cited instead.

Disclaimer: Views expressed in this article do not necessarily reflect those of ScienceDaily or its staff.

View the original article here

It's not easy flying green: Large variability in greenhouse gas emissions from alternative fuels

ScienceDaily (May 11, 2011) — There's a race afoot to give biofuel wings in the aviation industry, part of an effort to combat soaring fuel prices and cut greenhouse gas emissions. In 2008, Virgin Atlantic became the first commercial airline to fly a plane on a blend of biofuel and petroleum. Since then, Air New Zealand, Qatar Airways and Continental Airlines, among others, have flown biofuel test flights, and Lufthansa is racing to be the first carrier to run daily flights on a biofuel blend.

However, researchers at MIT say the industry may want to cool its jets and make sure it has examined biofuels' complete carbon footprint before making an all-out push. They say that when a biofuel's origins are factored in -- for example, taking into account whether the fuel is made from palm oil grown in a clear-cut rainforest -- conventional fossil fuels may sometimes be the "greener" choice.

"What we found was that technologies that look very promising could also result in high emissions, if done improperly," says James Hileman, principal research engineer in the Department of Aeronautics and Astronautics, who has published the results of a study conducted with MIT graduate students Russell Stratton and Hsin Min Wong in the online version of the journal Environmental Science and Technology. "You can't simply say a biofuel is good or bad -- it depends on how it's produced and processed, and that's part of the debate that hasn't been brought forward."

Hileman and his team performed a life-cycle analysis of 14 fuel sources, including conventional petroleum-based jet fuel and "drop-in" biofuels: alternatives that can directly replace conventional fuels with little or no change to existing infrastructure or vehicles. In a previous report for the Federal Aviation Administration's Partnership for Air Transportation Noise and Emissions Reduction, they calculated the emissions throughout the life cycle of a biofuel, "from well to wake" -- from acquiring the biomass to transporting it to converting it to fuel, as well as its combustion.

"All those processes require energy," Hileman says, "and that ends up in the release of carbon dioxide."

In the current Environmental Science and Technology paper, Hileman considered the entire biofuel life cycle of diesel engine fuel compared with jet fuel, and found that changing key parameters can dramatically change the total greenhouse gas emissions from a given biofuel.

Land-locked

In particular, the team found that emissions varied widely depending on the type of land used to grow biofuel components such as soy, palm and rapeseed. For example, Hileman and his team calculated that biofuels derived from palm oil emitted 55 times more carbon dioxide if the palm oil came from a plantation located in a converted rainforest rather than a previously cleared area. Depending on the type of land used, biofuels could ultimately emit 10 times more carbon dioxide than conventional fuel.

"Severe cases of land-use change could make coal-to-liquid fuels look green," says Hileman, noting that by conventional standards, "coal-to-liquid is not a green option."

Hileman says the airline industry needs to account for such scenarios when thinking about how to scale up biofuel production. The problem, he says, is not so much the technology to convert biofuels: Companies like Choren and Rentech have successfully built small-scale biofuel production facilities and are looking to expand in the near future. Rather, Hileman says the challenge is in allocating large swaths of land to cultivate enough biomass, in a sustainable fashion, to feed the growing demand for biofuels.

He says one solution to the land-use problem may be to explore crops like algae and salicornia that don't require deforestation or fertile soil to grow. Scientists are exploring these as a fuel source, particularly since they also do not require fresh water.

Feeding the tank

Total emissions from biofuel production may also be mitigated by a biofuel's byproducts. For example, the process of converting jatropha to biofuel also yields solid biomass: For every kilogram of jatropha oil produced, 0.8 kilograms of meal, 1.1 kilograms of shells and 1.7 kilograms of husks are created. These co-products could be used to produce electricity, for animal feed or as fertilizer. Hileman says that this is a great example of how co-products can have a large impact on the carbon dioxide emissions of a fuel.

Hileman says his analysis is one lens through which policymakers can view biofuel production. In making decisions on how to build infrastructure and resources to support a larger biofuel economy, he says researchers also need to look at the biofuel life cycle in terms of cost and yield.

"We need to have fuels that can be made at an economical price, and at large quantity," Hileman says. "Greenhouse gases [are] just part of the equation, and there's a lot of interesting work going on in this field."

The study is the culmination of four years of research by Hileman, Stratton and Wong. The work was funded by the Federal Aviation Administration and Air Force Research Labs.

Story Source:

The above story is reprinted (with editorial adaptations by ScienceDaily staff) from materials provided by Massachusetts Institute of Technology. The original article was written by Jennifer Chu, MIT News Office.

Journal Reference:

Russell W. Stratton, Hsin Min Wong, James I. Hileman. Quantifying Variability in Life Cycle Greenhouse Gas Inventories of Alternative Middle Distillate Transportation Fuels. Environmental Science & Technology, 2011; : 110422101727045 DOI: 10.1021/es102597f

Note: If no author is given, the source is cited instead.

Disclaimer: Views expressed in this article do not necessarily reflect those of ScienceDaily or its staff.

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