New 'diamond?' New form of superhard carbon is as strong as a diamond

ScienceDaily (Oct. 11, 2011) — Carbon is the fourth-most-abundant element in the universe and takes on a wide variety of forms, called allotropes, including diamond and graphite. Scientists at Carnegie's Geophysical Laboratory are part of a team that has discovered a new form of carbon, which is capable of withstanding extreme pressure stresses that were previously observed only in diamond.

This breakthrough discovery will be published in Physical Review Letters.

The team was led by Stanford's Wendy L. Mao and her graduate student Yu Lin and includes Carnegie's Ho-kwang (Dave) Mao, Li Zhang, Paul Chow, Yuming Xiao, Maria Baldini, and Jinfu Shu. The experiment started with a form of carbon called glassy carbon, which was first synthesized in the 1950s, and was found to combine desirable properties of glasses and ceramics with those of graphite. The team created the new carbon allotrope by compressing glassy carbon to above 400,000 times normal atmospheric pressure.

This new carbon form was capable of withstanding 1.3 million times normal atmospheric pressure in one direction while confined under a pressure of 600,000 times atmospheric levels in other directions. No substance other than diamond has been observed to withstand this type of pressure stress, indicating that the new carbon allotrope must indeed be very strong.

However, unlike diamond and other crystalline forms of carbon, the structure of this new material is not organized in repeating atomic units. It is an amorphous material, meaning that its structure lacks the long-range order of crystals. This amorphous, superhard carbon allotrope would have a potential advantage over diamond if its hardness turns out to be isotropic -- that is, having hardness that is equally strong in all directions. In contrast, diamond's hardness is highly dependent upon the direction in which the crystal is oriented.

"These findings open up possibilities for potential applications, including super hard anvils for high-pressure research and could lead to new classes of ultradense and strong materials," said Russell Hemley, director of Carnegie's Geophysical Laboratory.

This research was funded, in part, by the Department of Energy's Office of Basic Energy Sciences Division of Materials Sciences and Engineering, EFree, HPCAT, where some of the experiments were performed, is funded by DOE-BES, DOE-NNSA, NSF, and the W.M. Keck Foundation. APS, where some of the experiments were performed, is supported by DOE-BES.

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The above story is reprinted (with editorial adaptations by ScienceDaily staff) from materials provided by Carnegie Institution.

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Yu Lin, Li Zhang, Ho-kwang Mao, Paul Chow, Yuming Xiao, Maria Baldini, Jinfu Shu, and Wendy L. Mao. Amorphous diamond: A high-pressure superhard carbon allotrope. Physical Review Letters, 2011 (in press)

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New 'diamond?' New form of superhard carbon is as strong as a diamond

ScienceDaily (Oct. 11, 2011) — Carbon is the fourth-most-abundant element in the universe and takes on a wide variety of forms, called allotropes, including diamond and graphite. Scientists at Carnegie's Geophysical Laboratory are part of a team that has discovered a new form of carbon, which is capable of withstanding extreme pressure stresses that were previously observed only in diamond.

This breakthrough discovery will be published in Physical Review Letters.

The team was led by Stanford's Wendy L. Mao and her graduate student Yu Lin and includes Carnegie's Ho-kwang (Dave) Mao, Li Zhang, Paul Chow, Yuming Xiao, Maria Baldini, and Jinfu Shu. The experiment started with a form of carbon called glassy carbon, which was first synthesized in the 1950s, and was found to combine desirable properties of glasses and ceramics with those of graphite. The team created the new carbon allotrope by compressing glassy carbon to above 400,000 times normal atmospheric pressure.

This new carbon form was capable of withstanding 1.3 million times normal atmospheric pressure in one direction while confined under a pressure of 600,000 times atmospheric levels in other directions. No substance other than diamond has been observed to withstand this type of pressure stress, indicating that the new carbon allotrope must indeed be very strong.

However, unlike diamond and other crystalline forms of carbon, the structure of this new material is not organized in repeating atomic units. It is an amorphous material, meaning that its structure lacks the long-range order of crystals. This amorphous, superhard carbon allotrope would have a potential advantage over diamond if its hardness turns out to be isotropic -- that is, having hardness that is equally strong in all directions. In contrast, diamond's hardness is highly dependent upon the direction in which the crystal is oriented.

"These findings open up possibilities for potential applications, including super hard anvils for high-pressure research and could lead to new classes of ultradense and strong materials," said Russell Hemley, director of Carnegie's Geophysical Laboratory.

This research was funded, in part, by the Department of Energy's Office of Basic Energy Sciences Division of Materials Sciences and Engineering, EFree, HPCAT, where some of the experiments were performed, is funded by DOE-BES, DOE-NNSA, NSF, and the W.M. Keck Foundation. APS, where some of the experiments were performed, is supported by DOE-BES.

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The above story is reprinted (with editorial adaptations by ScienceDaily staff) from materials provided by Carnegie Institution.

Journal Reference:

Yu Lin, Li Zhang, Ho-kwang Mao, Paul Chow, Yuming Xiao, Maria Baldini, Jinfu Shu, and Wendy L. Mao. Amorphous diamond: A high-pressure superhard carbon allotrope. Physical Review Letters, 2011 (in press)

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Progress in quantum computing: Researchers control rate of photon emission from luminescent imperfections in diamond

ScienceDaily (Oct. 12, 2011) — Engineers and physicists at Harvard have managed to capture light in tiny diamond pillars embedded in silver, releasing a stream of single photons at a controllable rate.

The advance represents a milestone on the road to quantum networks in which information can be encoded in spins of electrons and carried through a network via light, one photon at a time.

The finding was published in Nature Photonics, appearing online Oct. 9.

"We can make the emission of photons faster, which will allow us to do more processing per second -- for example, more computations -- in the future quantum network," explains principal investigator Marko Loncar, Associate Professor of Electrical Engineering at the Harvard School of Engineering and Applied Sciences (SEAS).

The device Loncar's research team has built consists of parallel rows of tiny, nanofabricated diamond posts, embedded in a layer of silver, that can each act as a single photon source.

By removing the silver wrapping from their nanostructures, the team was also able to achieve a slower release of photons, which is of interest for probing the dynamics of the quantum system.

The breakthrough takes advantage of imperfections in the diamond's crystal lattice, where carbon atoms are replaced by other elements. To the naked eye, these imperfections can appear as discolorations in the diamond, turning it yellow in the case of nitrogen. Occasionally, there is also a vacancy (missing carbon atom) next to the nitrogen atom.

Each nitrogen-vacancy imperfection can serve as a nearly perfect quantum emitter, capable of emitting red photons one by one, even at room temperature. The technology is a promising candidate for realization of scalable, on-chip quantum networks.

"The color centers in diamond are very interesting as qubits for quantum information processing, where they can be used as memory to store information," says Loncar. "More importantly, they can be interrogated -- they can be written into and read out -- with light."

Loncar's team fabricates diamond posts that contain negatively charged nitrogen vacancy centers, which can absorb light and hold its energy for a given amount of time, finally releasing it in the form of photons.

"The rate at which photons are emitted can be controlled by carefully nano-engineering the center's surrounding," says co-author Irfan Bulu, a research associate in the Loncar group. Attaining fine control of that release, however, has been difficult.

"One of the main challenges has been the efficiency with which you can write information into the spin of these color centers, as well as the efficiency with which you can collect photons emitted from the color centers," explains co-author Jennifer Choy, a graduate student in Loncar's lab at SEAS. "The other challenge has been the rate -- how quickly you can perform these processes."

Previous work from Loncar's group solved the collection efficiency problem by using diamond nanowires to channel and direct the flow of photons. The new research manipulates the radius of diamond pillars and adds the silver coating. The diamond-silver construction acts as an optical nanoresonator, creating a strong electromagnetic field around the emitter and offering a new level of control over the rate of emission.

Moreover, the device functions at room temperature -- an essential requirement for practical computing applications -- and the nanostructured chips are fully scalable.

"We've designed everything in parallel in a massive system, which allows us to make thousands or millions of devices with more or less the same properties, and we use conventional microfabrication and nanofabrication techniques, unlike what has been done in this field before," says Birgit Hausmann, a graduate student in Loncar's lab at SEAS and one of the co-authors.

In addition to Loncar, Choy, Hausmann, and Bulu, co-authors included Tom Babinec, a graduate student at SEAS; Mughees Khan, a staff scientist at the Wyss Institute for Biologically Inspired Engineering at Harvard; Patrick Maletinsky, a fellow of the Department of Physics at Harvard; and Amir Jacoby, Professor of Physics in the Harvard Faculty of Arts and Sciences.

The work was supported by grants and fellowships from the U.S. Department of Defense, the Defense Advanced Research Projects Agency (DARPA) QuEST program, the National Science Foundation (NSF), the King Abdullah University of Science and Technology (KAUST), the Sloan Foundation, and the NSF-supported Nanoscale Science and Engineering Center (NSEC) at Harvard. Fabrication took place at the NSF-supported Center for Nanoscale Systems (CNS) at Harvard.

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The above story is reprinted (with editorial adaptations by ScienceDaily staff) from materials provided by Harvard University.

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Jennifer T. Choy, Birgit J. M. Hausmann, Thomas M. Babinec, Irfan Bulu, Mughees Khan, Patrick Maletinsky, Amir Yacoby, Marko Loncar. Enhanced single-photon emission from a diamond–silver aperture. Nature Photonics, 2011; DOI: 10.1038/nphoton.2011.249

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Progress in quantum computing: Researchers control rate of photon emission from luminescent imperfections in diamond

ScienceDaily (Oct. 12, 2011) — Engineers and physicists at Harvard have managed to capture light in tiny diamond pillars embedded in silver, releasing a stream of single photons at a controllable rate.

The advance represents a milestone on the road to quantum networks in which information can be encoded in spins of electrons and carried through a network via light, one photon at a time.

The finding was published in Nature Photonics, appearing online Oct. 9.

"We can make the emission of photons faster, which will allow us to do more processing per second -- for example, more computations -- in the future quantum network," explains principal investigator Marko Loncar, Associate Professor of Electrical Engineering at the Harvard School of Engineering and Applied Sciences (SEAS).

The device Loncar's research team has built consists of parallel rows of tiny, nanofabricated diamond posts, embedded in a layer of silver, that can each act as a single photon source.

By removing the silver wrapping from their nanostructures, the team was also able to achieve a slower release of photons, which is of interest for probing the dynamics of the quantum system.

The breakthrough takes advantage of imperfections in the diamond's crystal lattice, where carbon atoms are replaced by other elements. To the naked eye, these imperfections can appear as discolorations in the diamond, turning it yellow in the case of nitrogen. Occasionally, there is also a vacancy (missing carbon atom) next to the nitrogen atom.

Each nitrogen-vacancy imperfection can serve as a nearly perfect quantum emitter, capable of emitting red photons one by one, even at room temperature. The technology is a promising candidate for realization of scalable, on-chip quantum networks.

"The color centers in diamond are very interesting as qubits for quantum information processing, where they can be used as memory to store information," says Loncar. "More importantly, they can be interrogated -- they can be written into and read out -- with light."

Loncar's team fabricates diamond posts that contain negatively charged nitrogen vacancy centers, which can absorb light and hold its energy for a given amount of time, finally releasing it in the form of photons.

"The rate at which photons are emitted can be controlled by carefully nano-engineering the center's surrounding," says co-author Irfan Bulu, a research associate in the Loncar group. Attaining fine control of that release, however, has been difficult.

"One of the main challenges has been the efficiency with which you can write information into the spin of these color centers, as well as the efficiency with which you can collect photons emitted from the color centers," explains co-author Jennifer Choy, a graduate student in Loncar's lab at SEAS. "The other challenge has been the rate -- how quickly you can perform these processes."

Previous work from Loncar's group solved the collection efficiency problem by using diamond nanowires to channel and direct the flow of photons. The new research manipulates the radius of diamond pillars and adds the silver coating. The diamond-silver construction acts as an optical nanoresonator, creating a strong electromagnetic field around the emitter and offering a new level of control over the rate of emission.

Moreover, the device functions at room temperature -- an essential requirement for practical computing applications -- and the nanostructured chips are fully scalable.

"We've designed everything in parallel in a massive system, which allows us to make thousands or millions of devices with more or less the same properties, and we use conventional microfabrication and nanofabrication techniques, unlike what has been done in this field before," says Birgit Hausmann, a graduate student in Loncar's lab at SEAS and one of the co-authors.

In addition to Loncar, Choy, Hausmann, and Bulu, co-authors included Tom Babinec, a graduate student at SEAS; Mughees Khan, a staff scientist at the Wyss Institute for Biologically Inspired Engineering at Harvard; Patrick Maletinsky, a fellow of the Department of Physics at Harvard; and Amir Jacoby, Professor of Physics in the Harvard Faculty of Arts and Sciences.

The work was supported by grants and fellowships from the U.S. Department of Defense, the Defense Advanced Research Projects Agency (DARPA) QuEST program, the National Science Foundation (NSF), the King Abdullah University of Science and Technology (KAUST), the Sloan Foundation, and the NSF-supported Nanoscale Science and Engineering Center (NSEC) at Harvard. Fabrication took place at the NSF-supported Center for Nanoscale Systems (CNS) at Harvard.

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The above story is reprinted (with editorial adaptations by ScienceDaily staff) from materials provided by Harvard University.

Journal Reference:

Jennifer T. Choy, Birgit J. M. Hausmann, Thomas M. Babinec, Irfan Bulu, Mughees Khan, Patrick Maletinsky, Amir Yacoby, Marko Loncar. Enhanced single-photon emission from a diamond–silver aperture. Nature Photonics, 2011; DOI: 10.1038/nphoton.2011.249

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Method for creating tiny diamond machines improved

ScienceDaily (Sep. 28, 2011) — Diamonds may be best known as a symbol of long-lasting love. But semiconductor makers are also hoping they'll pan out as key components of long-lasting micromachines if a new method developed at the National Institute of Standards and Technology (NIST) for carving these tough, capable crystals proves its worth.* The method offers a precise way to engineer microscopic cuts in a diamond surface, yielding potential benefits in both measurement and technological fields.

By combining their own observations with background gleaned from materials science, NIST semiconductor researchers have found a way to create unique features in diamond -- potentially leading to improvements in nanometrology in short order, as it has allowed the team to make holes of precise shape in one of the hardest known substances. But beyond the creation of virtually indestructible nanorulers, the method could one day lead to the improvement of a class of electronic devices useful in cell phones, gyroscopes and medical implants.

Well known for making the hugely complex electronic microchips that run our laptops, the semiconductor industry has expanded its portfolio by fabricating tiny devices with moving parts. Constructed with substantially the same techniques as the electronic chips, these "micro-electromechanical systems," or MEMS, are just a few micrometers in size. They can detect environmental changes such as heat, pressure and acceleration, potentially enabling them to form the basis of tiny sensors and actuators for a host of new devices. But designers must take care that tiny moving parts do not grind to a disastrous halt. One way to make the sliding parts last longer without breaking down is to make them from a tougher material than silicon.

"Diamond may be the ideal substance for MEMS devices," says NIST's Craig McGray. "It can withstand extreme conditions, plus it's able to vibrate at the very high frequencies that new consumer electronics demand. But it's very hard, of course, and there hasn't been a way to engineer it very precisely at small scales. We think our method can accomplish that."

The method uses a chemical etching process to create cavities in the diamond surface. The cubic shape of a diamond crystal can be sliced in several ways -- a fact jewelers take advantage of when creating facets on gemstones. The speed of the etching process depends on the orientation of the slice, occurring at a far slower rate in the direction of the cube's "faces" -- think of chopping the cube into smaller cubes -- and these face planes can be used as a sort of boundary where etching can be made to stop when desired. In their initial experiments, the team created cavities ranging in width from 1 to 72 micrometers, each with smooth vertical sidewalls and a flat bottom.

"We'd like to figure out how to optimize control of this process next," McGray says, "but some of the ways diamond behaved under the conditions we used were unexpected. We plan to explore some of these mysteries while we develop a prototype diamond MEMS device."

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The above story is reprinted (with editorial adaptations by ScienceDaily staff) from materials provided by National Institute of Standards and Technology (NIST).

Journal Reference:

Craig D. McGray, Richard A. Allen, Marc Cangemi, Jon Geist. Rectangular scale-similar etch pits in monocrystalline diamond. Diamond and Related Materials, 2011; DOI: 10.1016/j.diamond.2011.08.007

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Method for creating tiny diamond machines improved

ScienceDaily (Sep. 28, 2011) — Diamonds may be best known as a symbol of long-lasting love. But semiconductor makers are also hoping they'll pan out as key components of long-lasting micromachines if a new method developed at the National Institute of Standards and Technology (NIST) for carving these tough, capable crystals proves its worth.* The method offers a precise way to engineer microscopic cuts in a diamond surface, yielding potential benefits in both measurement and technological fields.

By combining their own observations with background gleaned from materials science, NIST semiconductor researchers have found a way to create unique features in diamond -- potentially leading to improvements in nanometrology in short order, as it has allowed the team to make holes of precise shape in one of the hardest known substances. But beyond the creation of virtually indestructible nanorulers, the method could one day lead to the improvement of a class of electronic devices useful in cell phones, gyroscopes and medical implants.

Well known for making the hugely complex electronic microchips that run our laptops, the semiconductor industry has expanded its portfolio by fabricating tiny devices with moving parts. Constructed with substantially the same techniques as the electronic chips, these "micro-electromechanical systems," or MEMS, are just a few micrometers in size. They can detect environmental changes such as heat, pressure and acceleration, potentially enabling them to form the basis of tiny sensors and actuators for a host of new devices. But designers must take care that tiny moving parts do not grind to a disastrous halt. One way to make the sliding parts last longer without breaking down is to make them from a tougher material than silicon.

"Diamond may be the ideal substance for MEMS devices," says NIST's Craig McGray. "It can withstand extreme conditions, plus it's able to vibrate at the very high frequencies that new consumer electronics demand. But it's very hard, of course, and there hasn't been a way to engineer it very precisely at small scales. We think our method can accomplish that."

The method uses a chemical etching process to create cavities in the diamond surface. The cubic shape of a diamond crystal can be sliced in several ways -- a fact jewelers take advantage of when creating facets on gemstones. The speed of the etching process depends on the orientation of the slice, occurring at a far slower rate in the direction of the cube's "faces" -- think of chopping the cube into smaller cubes -- and these face planes can be used as a sort of boundary where etching can be made to stop when desired. In their initial experiments, the team created cavities ranging in width from 1 to 72 micrometers, each with smooth vertical sidewalls and a flat bottom.

"We'd like to figure out how to optimize control of this process next," McGray says, "but some of the ways diamond behaved under the conditions we used were unexpected. We plan to explore some of these mysteries while we develop a prototype diamond MEMS device."

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The above story is reprinted (with editorial adaptations by ScienceDaily staff) from materials provided by National Institute of Standards and Technology (NIST).

Journal Reference:

Craig D. McGray, Richard A. Allen, Marc Cangemi, Jon Geist. Rectangular scale-similar etch pits in monocrystalline diamond. Diamond and Related Materials, 2011; DOI: 10.1016/j.diamond.2011.08.007

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Subatomic quantum memory in diamond demonstrated

ScienceDaily (June 28, 2011) — Physicists working at the University of California, Santa Barbara and the University of Konstanz in Germany have developed a breakthrough in the use of diamond in quantum physics, marking an important step toward quantum computing. The results are reported in this week's online edition of Nature Physics.

The physicists were able to coax the fragile quantum information contained within a single electron in diamond to move into an adjacent single nitrogen nucleus, and then back again using on-chip wiring.

"This ability is potentially useful to create an atomic-scale memory element in a quantum computer based on diamond, since the subatomic nuclear states are more isolated from destructive interactions with the outside world," said David Awschalom, senior author. Awschalom is director of UCSB's Center for Spintronics & Quantum Computation, professor of physics, electrical and computer engineering, and the Peter J. Clarke director of the California NanoSystems Institute.

Awschalom said the discovery shows the high-fidelity operation of a quantum mechanical gate at the atomic level, enabling the transfer of full quantum information to and from one electron spin and a single nuclear spin at room temperature. The process is scalable, and opens the door to new solid-state quantum device development.

Scientists have recently shown that it is possible to synthesize thousands of these single electron states with beams of nitrogen atoms, intentionally creating defects to trap the single electrons. "What makes this demonstration particularly exciting is that a nitrogen atom is a part of the defect itself, meaning that these sub-atomic memory elements automatically scale with the number of logical bits in the quantum computer," said lead author Greg Fuchs, a postdoctoral fellow at UCSB.

Rather than using logical elements like transistors to manipulate digital states like "0" or "1," a quantum computer needs logical elements capable of manipulating quantum states that may be "0" and "1" at the same time. Even at ambient temperature, these defects in diamond can do exactly that, and have recently become a leading candidate to form a quantum version of a transistor.

However, there are still major challenges to building a diamond-based quantum computer. One of these is finding a method to store quantum information in a scalable way. Unlike a conventional computer, where the memory and the processor are in two different physical locations, in this case they are integrated together, bit-for-bit.

"We knew that the nitrogen nuclear spin would be a good choice for a scalable quantum memory -- it was already there," said Fuchs. "The hard part was to transfer the state quickly, before it is lost to decoherence."

Awschalom explained: "A key breakthrough was to use a unique property of quantum physics -- that two quantum objects can, under special conditions, become mixed to form a new composite object." By mixing the quantum spin state of the electrons in the defect with the spin state of the nitrogen nucleus for a brief time -- less than 100 billionths of a second -- information that was originally encoded in the electrons is passed to the nucleus.

"The result is an extremely fast transfer of the quantum information to the long-lived nuclear spin, which could further enhance our capabilities to correct for errors during a quantum computation," said co-author Guido Burkard, a theoretical physicist at the University of Konstanz, who developed a model to understand the storage process.

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The above story is reprinted (with editorial adaptations by ScienceDaily staff) from materials provided by University of California - Santa Barbara, via EurekAlert!, a service of AAAS.

Journal Reference:

G. D. Fuchs, G. Burkard, P. V. Klimov, D. D. Awschalom. A quantum memory intrinsic to single nitrogen–vacancy centres in diamond. Nature Physics, 2011; DOI: 10.1038/nphys2026

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Diamond aerogel: New form of diamond is lighter than ever

ScienceDaily (May 18, 2011) — By combining high pressure with high temperature, Livermore researchers have created a nanocyrstalline diamond aerogel that could improve the optics for something as big as a telescope or as small as the lenses in eyeglasses.

Aerogels are a class of materials that exhibit the lowest density, thermal conductivity, refractive index and sound velocity of any bulk solid. Aerogels are among the most versatile materials available for technical applications due to their many exceptional properties. This material has chemists, physicists, astronomers, and materials scientists utilizing its properties in myriad applications, from a water purifier for desalinizing seawater to installation on a NASA satellite as a meteorite particle collector.

In new research appearing in the May 9-13 online edition of the Proceedings of the National Academy of Sciences, a Livermore team created a diamond aerogel from a standard carbon-based aerogel precursor using a laser-heated diamond anvil cell.

A diamond anvil cell consists of two opposing diamonds with the sample compressed between them. It can compress a small piece of material (tens of micrometers or smaller) to extreme pressures, which can exceed 3 million atmospheres. The device has been used to recreate the pressure existing deep inside planets, creating materials and phases not observed under normal conditions. Since diamonds are transparent, intense laser light also can be focused onto the sample to simultaneously heat it to thousands of degrees.

The new form of diamond has a very low density similar to that of the precursor of around 40 milligrams per cubic centimeter, which is only about 40 times denser than air.

The diamond aerogel could have applications in antireflection coatings, a type of optical coating applied to the surface of lenses and other optical devices to reduce reflection. Less light is lost, improving the efficiency of the system. It can be applied to telescopes, binoculars, eyeglasses or any other device that may require reflection reduction. It also has potential applications in enhanced or modified biocompatibility, chemical doping, thermal conduction and electrical field emission.

In creating diamond aergoels, lead researcher Peter Pauzauskie, a former Lawrence fellow now at the University of Washington, infused the pores of a standard, carbon-based aerogel with neon, preventing the entire aerogel from collapsing on itself.

At that point, the team subjected the aerogel sample to tremendous pressures and temperatures (above 200,000 atmospheres and in excess of 2,240 degrees Fahrenheit), forcing the carbon atoms within to shift their arrangement and create crystalline diamonds.

The success of this work also leads the team to speculate that additional novel forms of diamond may be obtained by exposing appropriate precursors to the right combination of high pressure and temperature.

Livermore researchers on the project include: Jonathan Crowhurst, Marcus Worsley, Ted Laurence, Yinmin "Morris" Wang, Trevor Wiley, Kenneth Visbeck, William Evans, Joseph Zaug and Joe Satcher Jr.

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The above story is reprinted (with editorial adaptations by ScienceDaily staff) from materials provided by DOE/Lawrence Livermore National Laboratory.

Journal Reference:

P. J. Pauzauskie, J. C. Crowhurst, M. A. Worsley, T. A. Laurence, A. L. D. Kilcoyne, Y. Wang, T. M. Willey, K. S. Visbeck, S. C. Fakra, W. J. Evans, J. M. Zaug, J. H. Satcher. Synthesis and characterization of a nanocrystalline diamond aerogel. Proceedings of the National Academy of Sciences, 2011; DOI: 10.1073/pnas.1010600108

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New Diamond Aerogel is the Airiest Diamond Ever Made

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