Secrets of tunneling through energy barriers: How massless electrons tunnel through energy barriers in a carbon sheet called graphene

ScienceDaily (Nov. 7, 2011) — Electrons moving in graphene behave in an unusual way, as demonstrated by 2010 Nobel Prize laureates for physics Andre Geim and Konstantin Novoselov, who performed transport experiments on this one-carbon-atom-thick material. A review article, just published in The European Physical Journal B, explores the theoretical and experimental results to date of electrons tunneling through energy barriers in graphene.

As good an electrical conductor at room temperature as copper graphene is, it also outperforms all other known materials as a heat conductor. It is both very dense due to its honeycomb lattice structure and almost completely transparent, making it suitable, among other applications, for touch screens and light panels.

What could partly explain graphene's properties is that electrons travelling inside the material behave as if they were massless. Their behavior is described by the so-called massless Dirac equation that is normally used for high-energy particles such as neutrinos nearing the speed of light. However, electrons in graphene move at a constant speed 300 times smaller than that of light.

In this review, P.E. Allain and J.N. Fuchs, both from the Université Paris-Sud, focus on the tunneling effect occurring when Dirac electrons found in graphene are transmitted through different types of energy barriers. Contrary to the laws of classical mechanics, which govern larger scale particles that cannot cross energy barriers, electron tunneling is possible in quantum mechanics -- though only under restricted conditions, depending on the width and energy height of the barrier.

However, the Dirac electrons found in graphene can tunnel through energy barriers regardless of their width and energy height; a phenomenon called Klein tunneling, described theoretically for 3D massive Dirac electrons by the Swedish physicist Oskar Klein in 1929. Graphene was the first material in which Klein tunneling was observed experimentally, as massive Dirac electrons required energy barriers too large to be observed.

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P. E. Allain, J. N. Fuchs. Klein tunneling in graphene: optics with massless electrons. The European Physical Journal B, 2011; 83 (3): 301 DOI: 10.1140/epjb/e2011-20351-3

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Secrets of tunneling through energy barriers: How massless electrons tunnel through energy barriers in a carbon sheet called graphene

ScienceDaily (Nov. 7, 2011) — Electrons moving in graphene behave in an unusual way, as demonstrated by 2010 Nobel Prize laureates for physics Andre Geim and Konstantin Novoselov, who performed transport experiments on this one-carbon-atom-thick material. A review article, just published in The European Physical Journal B, explores the theoretical and experimental results to date of electrons tunneling through energy barriers in graphene.

As good an electrical conductor at room temperature as copper graphene is, it also outperforms all other known materials as a heat conductor. It is both very dense due to its honeycomb lattice structure and almost completely transparent, making it suitable, among other applications, for touch screens and light panels.

What could partly explain graphene's properties is that electrons travelling inside the material behave as if they were massless. Their behavior is described by the so-called massless Dirac equation that is normally used for high-energy particles such as neutrinos nearing the speed of light. However, electrons in graphene move at a constant speed 300 times smaller than that of light.

In this review, P.E. Allain and J.N. Fuchs, both from the Université Paris-Sud, focus on the tunneling effect occurring when Dirac electrons found in graphene are transmitted through different types of energy barriers. Contrary to the laws of classical mechanics, which govern larger scale particles that cannot cross energy barriers, electron tunneling is possible in quantum mechanics -- though only under restricted conditions, depending on the width and energy height of the barrier.

However, the Dirac electrons found in graphene can tunnel through energy barriers regardless of their width and energy height; a phenomenon called Klein tunneling, described theoretically for 3D massive Dirac electrons by the Swedish physicist Oskar Klein in 1929. Graphene was the first material in which Klein tunneling was observed experimentally, as massive Dirac electrons required energy barriers too large to be observed.

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Journal Reference:

P. E. Allain, J. N. Fuchs. Klein tunneling in graphene: optics with massless electrons. The European Physical Journal B, 2011; 83 (3): 301 DOI: 10.1140/epjb/e2011-20351-3

Note: If no author is given, the source is cited instead.

Disclaimer: Views expressed in this article do not necessarily reflect those of ScienceDaily or its staff.

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New 'diamond?' New form of superhard carbon is as strong as a diamond

ScienceDaily (Oct. 11, 2011) — Carbon is the fourth-most-abundant element in the universe and takes on a wide variety of forms, called allotropes, including diamond and graphite. Scientists at Carnegie's Geophysical Laboratory are part of a team that has discovered a new form of carbon, which is capable of withstanding extreme pressure stresses that were previously observed only in diamond.

This breakthrough discovery will be published in Physical Review Letters.

The team was led by Stanford's Wendy L. Mao and her graduate student Yu Lin and includes Carnegie's Ho-kwang (Dave) Mao, Li Zhang, Paul Chow, Yuming Xiao, Maria Baldini, and Jinfu Shu. The experiment started with a form of carbon called glassy carbon, which was first synthesized in the 1950s, and was found to combine desirable properties of glasses and ceramics with those of graphite. The team created the new carbon allotrope by compressing glassy carbon to above 400,000 times normal atmospheric pressure.

This new carbon form was capable of withstanding 1.3 million times normal atmospheric pressure in one direction while confined under a pressure of 600,000 times atmospheric levels in other directions. No substance other than diamond has been observed to withstand this type of pressure stress, indicating that the new carbon allotrope must indeed be very strong.

However, unlike diamond and other crystalline forms of carbon, the structure of this new material is not organized in repeating atomic units. It is an amorphous material, meaning that its structure lacks the long-range order of crystals. This amorphous, superhard carbon allotrope would have a potential advantage over diamond if its hardness turns out to be isotropic -- that is, having hardness that is equally strong in all directions. In contrast, diamond's hardness is highly dependent upon the direction in which the crystal is oriented.

"These findings open up possibilities for potential applications, including super hard anvils for high-pressure research and could lead to new classes of ultradense and strong materials," said Russell Hemley, director of Carnegie's Geophysical Laboratory.

This research was funded, in part, by the Department of Energy's Office of Basic Energy Sciences Division of Materials Sciences and Engineering, EFree, HPCAT, where some of the experiments were performed, is funded by DOE-BES, DOE-NNSA, NSF, and the W.M. Keck Foundation. APS, where some of the experiments were performed, is supported by DOE-BES.

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Yu Lin, Li Zhang, Ho-kwang Mao, Paul Chow, Yuming Xiao, Maria Baldini, Jinfu Shu, and Wendy L. Mao. Amorphous diamond: A high-pressure superhard carbon allotrope. Physical Review Letters, 2011 (in press)

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Science & the Public: Study recalibrates trees' carbon uptake

Finding, based on using heavy oxygen as a photosynthetic yardstick, could alter climate projections.Web edition : Wednesday, October 5th, 2011 If trees inhale faster . . . Apparent earlier underestimate of how quickly trees and other plants take in carbon for photosynthesis could have climate implications.iStockphoto

Photosynthesis appears to be somewhat speedier than conventional wisdom had suggested, a new study finds.  If true, this could mean that computer projections are at risk of overestimating the potential for forests to sop up carbon dioxide, a major greenhouse gas.

The new study did not measure photosynthesis directly. It instead deduced photosynthetic rates from subtle variations in the molecular weight of carbon dioxide molecules in air. Samples had been collected from across the globe during a 30 year period.

Some CO2 molecules tip the scales more than usual because one of their oxygen atoms has a molecular weight of 18, not 16. (The heavies pack an extra pair of neutrons.) The likelihood that an oxygen atom in CO2 will be an O18 will depend on the proportion of heavy oxygen in a region’s water, explains biogeochemist Lisa Welp of the Scripps Institution of Oceanography in La Jolla, Calif. That ratio can vary by soil moisture and weather conditions, she explains.

As plants breathe CO2 into their leaves, that CO2 will exchange its oxygen atoms with those in water, Welp notes. A substantial amount of that CO2 will eventually be released back into the air, now bearing an O18-to-O16 ratio reflective of the plant’s water.

In the September 29 Nature, Welp — and colleagues on three continents — report finding a subtle change in the proportion of CO2 molecules hosting heavy oxygen. This anomaly appeared to start in the tropics and then quickly spread across the planet. The pattern then repeats, almost in waves.

Each wave lasted about 18 months. And the start of a new wave every four years or so generally coincided with the emergence of a prolonged spell of unusually warm ocean temperatures in the Equatorial Pacific — a climatic event known as an El Niño. Explains Welp, “We find that water’s oxygen isotopes get heavier during El Niños in the tropics.”

Using the average ratio of heavy-to-normal oxygen in CO2 (linked to an El Nino event that could be timed), Welp’s group now had a means to evaluate how long it takes plants to transfer an anomalous oxygen signature into atmospheric CO2 — and then wash it away again once an El Niño ended. With this information, the researchers attempted to validate a fairly well accepted estimate of the global rate of carbon taken up by photosynthesis in plants each year —120 petagrams (peta being 1015).

Their assessment found the 120-petagram figure looked short — by about 25 to 45 percent. As to how such a revision in the rate of carbon cycling through plants might alter estimates of future long-term carbon sequestration by forests, Welp emphasizes: "We don't know yet. It's way too early to tell."

But Matthias Cuntz, a biogeochemist with the UFZ-Helmholtz Centre for Environmental Research in Leipzig, Germany, argues that in fact, carbon-storage implications of the new numbers are not that hard to fathom.

The global value for carbon sequestered long term in plant tissue each year is fairly well established at about 1.6 billion tons, he says. That’s almost 2 percent of the 120 petagram estimate. So if the carbon throughput is revised upward by 25 to 45 percent, then the amount of carbon being sequestered long term must be substantially less than 2 percent, Cuntz says – perhaps “only about 1 percent.”

In a commentary accompanying the new Nature paper, Cuntz likens the old 120-petagram figure to a “gold standard” for the annual rate at which land plants take in carbon for photosynthesis. If Welp’s team is right, he now argues, it has just put “a dent” in that gold standard.

The new estimates in the Nature paper do, however, rest on a lot of assumptions – albeit smart ones, Cuntz explains in his commentary. So the rather unexpected result that Welp and her colleagues report will certainly need confirmation.

But if the new numbers hold up, he told me, it could mean that current computer climate models rely on overly optimistic estimates about how efficiently trees can sequester carbon. “If you change photosynthesis a little, like this,” he says, “it could lead to huge differences [in projections of how climate might change in the future].”

Indeed, it would argue that reining in global warming will prove much harder than biologists had led us to expect.

Found in: Chemistry, Climate Change, Earth Science, Environment, Molecules and Science & Society

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New 'diamond?' New form of superhard carbon is as strong as a diamond

ScienceDaily (Oct. 11, 2011) — Carbon is the fourth-most-abundant element in the universe and takes on a wide variety of forms, called allotropes, including diamond and graphite. Scientists at Carnegie's Geophysical Laboratory are part of a team that has discovered a new form of carbon, which is capable of withstanding extreme pressure stresses that were previously observed only in diamond.

This breakthrough discovery will be published in Physical Review Letters.

The team was led by Stanford's Wendy L. Mao and her graduate student Yu Lin and includes Carnegie's Ho-kwang (Dave) Mao, Li Zhang, Paul Chow, Yuming Xiao, Maria Baldini, and Jinfu Shu. The experiment started with a form of carbon called glassy carbon, which was first synthesized in the 1950s, and was found to combine desirable properties of glasses and ceramics with those of graphite. The team created the new carbon allotrope by compressing glassy carbon to above 400,000 times normal atmospheric pressure.

This new carbon form was capable of withstanding 1.3 million times normal atmospheric pressure in one direction while confined under a pressure of 600,000 times atmospheric levels in other directions. No substance other than diamond has been observed to withstand this type of pressure stress, indicating that the new carbon allotrope must indeed be very strong.

However, unlike diamond and other crystalline forms of carbon, the structure of this new material is not organized in repeating atomic units. It is an amorphous material, meaning that its structure lacks the long-range order of crystals. This amorphous, superhard carbon allotrope would have a potential advantage over diamond if its hardness turns out to be isotropic -- that is, having hardness that is equally strong in all directions. In contrast, diamond's hardness is highly dependent upon the direction in which the crystal is oriented.

"These findings open up possibilities for potential applications, including super hard anvils for high-pressure research and could lead to new classes of ultradense and strong materials," said Russell Hemley, director of Carnegie's Geophysical Laboratory.

This research was funded, in part, by the Department of Energy's Office of Basic Energy Sciences Division of Materials Sciences and Engineering, EFree, HPCAT, where some of the experiments were performed, is funded by DOE-BES, DOE-NNSA, NSF, and the W.M. Keck Foundation. APS, where some of the experiments were performed, is supported by DOE-BES.

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Journal Reference:

Yu Lin, Li Zhang, Ho-kwang Mao, Paul Chow, Yuming Xiao, Maria Baldini, Jinfu Shu, and Wendy L. Mao. Amorphous diamond: A high-pressure superhard carbon allotrope. Physical Review Letters, 2011 (in press)

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Carbon nanotube muscles generate giant twist for novel motors

ScienceDaily (Oct. 14, 2011) — New artificial muscles that twist like the trunk of an elephant, but provide a thousand times higher rotation per length, have been developed by a team of researchers from The University of Texas at Dallas, The University of Wollongong in Australia, The University of British Columbia in Canada, and Hanyang University in Korea.

The research appears in the journal Science.

These muscles, based on carbon nanotubes yarns, accelerate a 2000 times heavier paddle up to 590 revolutions per minute in 1.2 seconds, and then reverse this rotation when the applied voltage is changed. The demonstrated rotation of 250 per millimeter of muscle length is over a thousand times that of previous artificial muscles, which are based on ferroelectrics, shape memory alloys, or conducting organic polymers. The output power per yarn weight is comparable to that for large electric motors, and the weight-normalized performance of these conventional electric motors severely degrades when they are downsized to millimeter scale.

These muscles exploit strong, tough, highly flexible yarns of carbon nanotubes, which consist of nanoscale cylinders of carbon that are ten thousand times smaller in diameter than a human hair. Important for success, these nanotubes are spun into helical yarns, which means that they have left and right handed versions (like our hands), depending upon the direction of rotation during twisting the nanotubes to make yarn. Rotation is torsional, meaning that twist occurs in one direction until a limiting rotation results, and then rotation can be reversed by changing the applied voltage. Left and right hand yarns rotate in opposite directions when electrically charged, but in both cases the effect of charging is to partially untwist the yarn.

Unlike conventional motors, whose complexity makes them difficult to miniaturize, the torsional carbon nanotube muscles are simple to inexpensively construct in either very long or millimeter lengths. The nanotube torsional motors consist of a yarn electrode and a counter-electrode, which are immersed in an ionically conducting liquid. A low voltage battery can serve as the power source, which enables electrochemical charge and discharge of the yarn to provide torsional rotation in opposite directions. In the simplest case, the researchers attach a paddle to the nanotube yarn, which enables torsional rotation to do useful work -- like mixing liquids on "micro-fluidic chips" used for chemical analysis and sensing.

The mechanism of torsional rotation is remarkable. Charging the nanotube yarns is like charging a supercapacitor -- ions migrate into the yarns to electrostatically balance the electronic charge electrically injected onto the nanotubes. Although the yarns are porous, this influx of ions causes the yarn to increase volume, shrink in length by up to a percent, and torsionally rotate. This surprising shrinkage in yarn length as its volume increases is explained by the yarn's helical structure, which is similar in structure to finger cuff toys that trap a child's fingers when elongated, but frees them when shortened.

Nature has used torsional rotation based on helically wound muscles for hundreds of millions of years, and exploits this action for such tasks as twisting the trunks of elephants and octopus limbs. In these natural appendages, helically wound muscle fibers cause rotation by contracting against an essentially incompressible, bone-less core. On the other hand, the helically wound carbon nanotubes in the nanotube yarns are undergoing little change in length, but are instead causing the volume of liquid electrolyte within the porous yarn to increase during electrochemical charging, so that torsional rotation occurs.

The combination of mechanical simplicity, giant torsional rotations, high rotation rates, and micron-size yarn diameters are attractive for applications, such as microfluidic pumps, valve drives, and mixers. In a fluidic mixer demonstrated by the researchers, a 15 micron diameter yarn rotated a 200 times larger radius and 80 times heavier paddle in flowing liquids at up to one rotation per second.

"The discovery, characterization, and understanding of these high performance torsional motors shows the power of international collaborations," said Ray H. Baughman, a corresponding author of the author of the Science article and Robert A. Welch Professor of Chemistry and director of The University of Texas at Dallas Alan G. MacDiarmid NanoTech Institute. "Researchers from four universities in three different continents that were born in eight different countries made critically important contributions."

Other co-authors of this article are Javad Foroughi (first author and research fellow), Geoffrey M. Spinks (a corresponding author and professor), and Gordon G. Wallace (professor) of the University of Wollongong in Australia; Jiyoung Oh (postdoctoral fellow), Mikhail E. Kozlov (research professor), and Shaoli Fang (research professor) at The University of Texas at Dallas; Tissaphern Mirfakhrai (postdoctoral fellow) and John D. W. Madden (professor) at The University of British Columbia; and Min Kyoon Shin (postdoctoral fellow) and Seon Jeong Kim (professor) at Hanyang University.

Funding for this research was provided by grants from the Air Force Office of Scientific Research, the Air Force AOARD program, the Office of Naval Research MURI program, and the Robert A. Welch Foundation in the United States; the Creative Research Initiative Center for Bio-Artificial Muscle in Korea; the Natural Sciences and Engineering Research Council of Canada; and the Australian Research Council.

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The above story is reprinted (with editorial adaptations by ScienceDaily staff) from materials provided by University of Texas at Dallas, via EurekAlert!, a service of AAAS.

Journal Reference:

Javad Foroughi, Geoffrey M. Spinks, Gordon G. Wallace, Jiyoung Oh, Mikhail E. Kozlov, Shaoli Fang, Tissaphern Mirfakhrai, John D. W. Madden, Min Kyoon Shin, Seon Jeong Kim, Ray H. Baughman. Torsional Carbon Nanotube Artificial Muscles. Science, 2011; DOI: 10.1126/science.1211220

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Researchers use carbon nanotubes to make solar cells affordable, flexible

ScienceDaily (Sep. 27, 2011) — Researchers from Northwestern University have developed a carbon-based material that could revolutionize the way solar power is harvested. The new solar cell material -- a transparent conductor made of carbon nanotubes -- provides an alternative to current technology, which is mechanically brittle and reliant on a relatively rare mineral.

Due to Earth's abundance of carbon, carbon nanotubes have the potential to boost the long-term viability of solar power by providing a cost-efficient option as demand for the technology increases. In addition, the material's mechanical flexibility could allow solar cells to be integrated into fabrics and clothing, enabling portable energy supplies that could impact everything from personal electronics to military operations.

The research, headed by Mark C. Hersam, professor of materials science and engineering and professor of chemistry, and Tobin J. Marks, Vladimir N. Ipatieff Professor of Catalytic Chemistry and professor of materials science and engineering, is featured on the cover of the October 2011 issue of Advanced Energy Materials, a new journal that specializes in science about materials used in energy applications.

Solar cells are composed of several layers, including a transparent conductor layer that allows light to pass into the cell and electricity to pass out; for both these actions to occur, the conductor must be both electrically conductive and also optically transparent. Few materials concurrently possess both of these properties.

Currently, indium tin oxide is the dominant material used in transparent conductor applications, but the material has two potential limitations. Indium tin oxide is mechanically brittle, which precludes its use in applications that require mechanical flexibility. In addition, Indium tin oxide relies on the relatively rare element indium, so the projected increased demand for solar cells could push the price of indium to problematically high levels.

"If solar technology really becomes widespread, as everyone hopes it will, we will likely have a crisis in the supply of indium," Hersam said. "There's a great desire to identify materials -- especially earth-abundant elements like carbon -- that can take indium's place in solar technology."

Hersam and Marks' team has created an alternative to indium tin oxide using single-walled carbon nanotubes, tiny, hollow cylinders of carbon just one nanometer in diameter.

The researchers have gone further to determine the type of nanotube that is most effective in transparent conductors. Nanotubes' properties vary depending on their diameter and their chiral angle, the angle that describes the arrangement of carbon atoms along the length of the nanotube. These properties determine two types of nanotubes: metallic and semiconducting.

Metallic nanotubes, the researchers found, are 50 times more effective than semiconducting ones when used as transparent conductors in organic solar cells.

"We have now identified precisely the type of carbon nanotube that should be used in this application," Hersam said.

Because carbon nanotubes are flexible, as opposed to the brittle indium tin oxide, the researchers' findings could pave the way for many new applications in solar cells. For example, the military could incorporate the flexible solar cells into tent material to provide solar power directly to soldiers in the field, or the cells could be integrated into clothing, backpacks, or purses for wearable electronics.

"With this mechanically flexible technology, it's much easier to imagine integrating solar technology into everyday life, rather than carrying around a large, inflexible solar cell," Hersam said.

Researchers are now examining other layers of the solar cell to explore also replacing these with carbon-based nanomaterials.

Besides Hersam and Marks, other authors include Timothy P. Tyler, Ryan E. Brock, and Hunter J. Karmel. This work was supported by the Argonne Northwestern-Northwestern Solar Energy Research Center, an Energy Frontier Research Center funded by the U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences.

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The above story is reprinted (with editorial adaptations by ScienceDaily staff) from materials provided by Northwestern University, via EurekAlert!, a service of AAAS.

Journal Reference:

Timothy P. Tyler, Ryan E. Brock, Hunter J. Karmel, Tobin J. Marks, Mark C. Hersam. Organic Solar Cell Characterization: Electronically Monodisperse Single-Walled Carbon Nanotube Thin Films as Transparent Conducting Anodes in Organic Photovoltaic Devices (Adv. Energy Mater. 5/2011). Advanced Energy Materials, 2011; 1 (5): 701 DOI: 10.1002/aenm.201190021

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Edible carbon dioxide sponge: All-natural nanostructures could address pressing environmental problem

ScienceDaily (Sep. 25, 2011) — A year ago Northwestern University chemists published their recipe for a new class of nanostructures made of sugar, salt and alcohol. Now, the same team has discovered the edible compounds can efficiently detect, capture and store carbon dioxide. And the compounds themselves are carbon-neutral.

The porous crystals -- known as metal-organic frameworks (MOFs) -- are made from all-natural ingredients and are simple to prepare, giving them a huge advantage over other MOFs. Conventional MOFs, which also are effective at adsorbing carbon dioxide, are usually prepared from materials derived from crude oil and often incorporate toxic heavy metals.

Other features of the Northwestern MOFs are they turn red when completely full of carbon dioxide, and the carbon capture process is reversible.

The findings, made by scientists working in the laboratory of Sir Fraser Stoddart, Board of Trustees Professor of Chemistry in the Weinberg College of Arts and Sciences, are published in the Journal of the American Chemical Society (JACS).

"We are able to take molecules that are themselves sourced from atmospheric carbon, through photosynthesis, and use them to capture even more carbon dioxide," said Ross S. Forgan, a co-author of the study and a postdoctoral fellow in Stoddart's laboratory. "By preparing our MOFs from naturally derived ingredients, we are not only making materials that are entirely nontoxic, but we are also cutting down on the carbon dioxide emissions associated with their manufacture."

The main component, gamma-cyclodextrin, is a naturally occurring biorenewable sugar molecule that is derived from cornstarch.

The sugar molecules are held in place by metals taken from salts such as potassium benzoate or rubidium hydroxide, and it is the precise arrangement of the sugars in the crystals that is vital to their successful capture of carbon dioxide.

"It turns out that a fairly unexpected event occurs when you put that many sugars next to each other in an alkaline environment -- they start reacting with carbon dioxide in a process akin to carbon fixation, which is how sugars are made in the first place," said Jeremiah J. Gassensmith, lead author of the paper and also a postdoctoral fellow in Stoddart's laboratory. "The reaction leads to the carbon dioxide being tightly bound inside the crystals, but we can still recover it at a later date very simply."

The fact that the carbon dioxide reacts with the MOF, an unusual occurrence, led to a simple method of detecting when the crystals have reached full capacity. The researchers place an indicator molecule, which detects changes in pH by changing its color, inside each crystal. When the yellow crystals of the MOFs are full of carbon dioxide they turn red.

The simplicity of the new MOFs, allied with their low cost and green credentials, have marked them as candidates for further commercialization. Ronald A. Smaldone, also a postdoctoral fellow in Stoddart's group and a co-author of the paper, added, "I think this is a remarkable demonstration of how simple chemistry can be successfully applied to relevant problems like carbon capture and sensor technology."

The National Science Foundation, the U.S. Department of Energy, the Engineering and Physical Sciences Research Council in the U.K., the King Abdulaziz City of Science and Technology (KACST) in Saudi Arabia and the Korea Advanced Institute of Science and Technology (KAIST) in Korea supported the research.

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The above story is reprinted (with editorial adaptations by ScienceDaily staff) from materials provided by Northwestern University. The original article was written by Megan Fellman.

Journal Reference:

Jeremiah J. Gassensmith, Hiroyasu Furukawa, Ronald A. Smaldone, Ross S. Forgan, Youssry Y. Botros, Omar M. Yaghi, J. Fraser Stoddart. Strong and Reversible Binding of Carbon Dioxide in a Green Metal–Organic Framework. Journal of the American Chemical Society, 2011; 110913144109022 DOI: 10.1021/ja206525x

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Researchers use carbon nanotubes to make solar cells affordable, flexible

ScienceDaily (Sep. 27, 2011) — Researchers from Northwestern University have developed a carbon-based material that could revolutionize the way solar power is harvested. The new solar cell material -- a transparent conductor made of carbon nanotubes -- provides an alternative to current technology, which is mechanically brittle and reliant on a relatively rare mineral.

Due to Earth's abundance of carbon, carbon nanotubes have the potential to boost the long-term viability of solar power by providing a cost-efficient option as demand for the technology increases. In addition, the material's mechanical flexibility could allow solar cells to be integrated into fabrics and clothing, enabling portable energy supplies that could impact everything from personal electronics to military operations.

The research, headed by Mark C. Hersam, professor of materials science and engineering and professor of chemistry, and Tobin J. Marks, Vladimir N. Ipatieff Professor of Catalytic Chemistry and professor of materials science and engineering, is featured on the cover of the October 2011 issue of Advanced Energy Materials, a new journal that specializes in science about materials used in energy applications.

Solar cells are composed of several layers, including a transparent conductor layer that allows light to pass into the cell and electricity to pass out; for both these actions to occur, the conductor must be both electrically conductive and also optically transparent. Few materials concurrently possess both of these properties.

Currently, indium tin oxide is the dominant material used in transparent conductor applications, but the material has two potential limitations. Indium tin oxide is mechanically brittle, which precludes its use in applications that require mechanical flexibility. In addition, Indium tin oxide relies on the relatively rare element indium, so the projected increased demand for solar cells could push the price of indium to problematically high levels.

"If solar technology really becomes widespread, as everyone hopes it will, we will likely have a crisis in the supply of indium," Hersam said. "There's a great desire to identify materials -- especially earth-abundant elements like carbon -- that can take indium's place in solar technology."

Hersam and Marks' team has created an alternative to indium tin oxide using single-walled carbon nanotubes, tiny, hollow cylinders of carbon just one nanometer in diameter.

The researchers have gone further to determine the type of nanotube that is most effective in transparent conductors. Nanotubes' properties vary depending on their diameter and their chiral angle, the angle that describes the arrangement of carbon atoms along the length of the nanotube. These properties determine two types of nanotubes: metallic and semiconducting.

Metallic nanotubes, the researchers found, are 50 times more effective than semiconducting ones when used as transparent conductors in organic solar cells.

"We have now identified precisely the type of carbon nanotube that should be used in this application," Hersam said.

Because carbon nanotubes are flexible, as opposed to the brittle indium tin oxide, the researchers' findings could pave the way for many new applications in solar cells. For example, the military could incorporate the flexible solar cells into tent material to provide solar power directly to soldiers in the field, or the cells could be integrated into clothing, backpacks, or purses for wearable electronics.

"With this mechanically flexible technology, it's much easier to imagine integrating solar technology into everyday life, rather than carrying around a large, inflexible solar cell," Hersam said.

Researchers are now examining other layers of the solar cell to explore also replacing these with carbon-based nanomaterials.

Besides Hersam and Marks, other authors include Timothy P. Tyler, Ryan E. Brock, and Hunter J. Karmel. This work was supported by the Argonne Northwestern-Northwestern Solar Energy Research Center, an Energy Frontier Research Center funded by the U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences.

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The above story is reprinted (with editorial adaptations by ScienceDaily staff) from materials provided by Northwestern University, via EurekAlert!, a service of AAAS.

Journal Reference:

Timothy P. Tyler, Ryan E. Brock, Hunter J. Karmel, Tobin J. Marks, Mark C. Hersam. Organic Solar Cell Characterization: Electronically Monodisperse Single-Walled Carbon Nanotube Thin Films as Transparent Conducting Anodes in Organic Photovoltaic Devices (Adv. Energy Mater. 5/2011). Advanced Energy Materials, 2011; 1 (5): 701 DOI: 10.1002/aenm.201190021

Note: If no author is given, the source is cited instead.

Disclaimer: Views expressed in this article do not necessarily reflect those of ScienceDaily or its staff.

View the original article here

Edible carbon dioxide sponge: All-natural nanostructures could address pressing environmental problem

ScienceDaily (Sep. 25, 2011) — A year ago Northwestern University chemists published their recipe for a new class of nanostructures made of sugar, salt and alcohol. Now, the same team has discovered the edible compounds can efficiently detect, capture and store carbon dioxide. And the compounds themselves are carbon-neutral.

The porous crystals -- known as metal-organic frameworks (MOFs) -- are made from all-natural ingredients and are simple to prepare, giving them a huge advantage over other MOFs. Conventional MOFs, which also are effective at adsorbing carbon dioxide, are usually prepared from materials derived from crude oil and often incorporate toxic heavy metals.

Other features of the Northwestern MOFs are they turn red when completely full of carbon dioxide, and the carbon capture process is reversible.

The findings, made by scientists working in the laboratory of Sir Fraser Stoddart, Board of Trustees Professor of Chemistry in the Weinberg College of Arts and Sciences, are published in the Journal of the American Chemical Society (JACS).

"We are able to take molecules that are themselves sourced from atmospheric carbon, through photosynthesis, and use them to capture even more carbon dioxide," said Ross S. Forgan, a co-author of the study and a postdoctoral fellow in Stoddart's laboratory. "By preparing our MOFs from naturally derived ingredients, we are not only making materials that are entirely nontoxic, but we are also cutting down on the carbon dioxide emissions associated with their manufacture."

The main component, gamma-cyclodextrin, is a naturally occurring biorenewable sugar molecule that is derived from cornstarch.

The sugar molecules are held in place by metals taken from salts such as potassium benzoate or rubidium hydroxide, and it is the precise arrangement of the sugars in the crystals that is vital to their successful capture of carbon dioxide.

"It turns out that a fairly unexpected event occurs when you put that many sugars next to each other in an alkaline environment -- they start reacting with carbon dioxide in a process akin to carbon fixation, which is how sugars are made in the first place," said Jeremiah J. Gassensmith, lead author of the paper and also a postdoctoral fellow in Stoddart's laboratory. "The reaction leads to the carbon dioxide being tightly bound inside the crystals, but we can still recover it at a later date very simply."

The fact that the carbon dioxide reacts with the MOF, an unusual occurrence, led to a simple method of detecting when the crystals have reached full capacity. The researchers place an indicator molecule, which detects changes in pH by changing its color, inside each crystal. When the yellow crystals of the MOFs are full of carbon dioxide they turn red.

The simplicity of the new MOFs, allied with their low cost and green credentials, have marked them as candidates for further commercialization. Ronald A. Smaldone, also a postdoctoral fellow in Stoddart's group and a co-author of the paper, added, "I think this is a remarkable demonstration of how simple chemistry can be successfully applied to relevant problems like carbon capture and sensor technology."

The National Science Foundation, the U.S. Department of Energy, the Engineering and Physical Sciences Research Council in the U.K., the King Abdulaziz City of Science and Technology (KACST) in Saudi Arabia and the Korea Advanced Institute of Science and Technology (KAIST) in Korea supported the research.

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The above story is reprinted (with editorial adaptations by ScienceDaily staff) from materials provided by Northwestern University. The original article was written by Megan Fellman.

Journal Reference:

Jeremiah J. Gassensmith, Hiroyasu Furukawa, Ronald A. Smaldone, Ross S. Forgan, Youssry Y. Botros, Omar M. Yaghi, J. Fraser Stoddart. Strong and Reversible Binding of Carbon Dioxide in a Green Metal–Organic Framework. Journal of the American Chemical Society, 2011; 110913144109022 DOI: 10.1021/ja206525x

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Properties of 'confined' water within single-walled carbon nanotube pores clarified

ScienceDaily (June 23, 2011) — Water and ice may not be among the first things that come to mind when you think about single-walled carbon nanotubes (SWCNTs), but a Japan-based research team hoping to get a clearer understanding of the phase behavior of confined water in the cylindrical pores of carbon nanotubes zeroed in on confined water's properties and made some surprising discoveries.

The team, from Tokyo Metropolitan University, Nagoya University, Japan Science and Technology Agency, and National Institute of Advanced Industrial Science and Technology, describes their findings in the American Institute of Physics' Journal of Chemical Physics.

Although carbon nanotubes consist of hydrophobic (water repelling) graphene sheets, experimental studies on SWCNTs show that water can indeed be confined in open-ended carbon nanotubes.

This discovery gives us a deeper understanding of the properties of nanoconfined water within the pores of SWCNTs, which is a key to the future of nanoscience. It's anticipated that nanoconfined water within carbon nanotubes can open the door to the development of a variety of nifty new nanothings -- nanofiltration systems, molecular nanovalves, molecular water pumps, nanoscale power cells, and even nanoscale ferroelectric devices.

"When materials are confined at the atomic scale they exhibit unusual properties not otherwise observed, due to the so-called 'nanoconfinement effect.' In geology, for example, nanoconfined water provides the driving force for frost heaves in soil, and also for the swelling of clay minerals," explains Yutaka Maniwa, a professor in the Department of Physics at Tokyo Metropolitan University. "We experimentally studied this type of effect for water using SWCNTs."

Water within SWCNTs in the range of 1.68 to 2.40 nanometers undergoes a wet-dry type of transition when temperature is decreased. And the team discovered that when SWCNTs are extremely narrow, the water inside forms tubule ices that are quite different from any bulk ices known so far. Strikingly, their melting point rises as the SWCNT diameter decreases -- contrary to that of bulk water inside a large-diameter capillary. In fact, tubule ice occurred even at room temperature inside SWCNTs.

"We extended our studies to the larger diameter SWCNTs up to 2.40 nanometers and successfully proposed a global phase behavior of water," says Maniwa. "This phase diagram (see image) covers a crossover from microscopic to macroscopic regions. In the macroscopic region, a novel wet-dry transition was newly explored at low temperature."

Results such as these contribute to a greater understanding of fundamental science because nanoconfined water exists and plays a vital role everywhere on Earth -- including our bodies. "Understanding the nanoconfined effect on the properties of materials is also crucial to develop new devices, such as proton-conducting membranes and nanofiltration," Maniwa notes.

Next up, the team plans to investigate the physical properties of confined water discovered so far inside SWCNTs (such as dielectricity and proton conduction). They will pursue this to obtain a better understanding of the molecular structure and transport properties in biological systems.

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The above story is reprinted (with editorial adaptations by ScienceDaily staff) from materials provided by American Institute of Physics, via EurekAlert!, a service of AAAS.

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Fundamental question on how life started solved: Supercomputer calculates carbon nucleus

ScienceDaily (May 10, 2011) — For carbon, the basis of life, to be able to form in the stars, a certain state of the carbon nucleus plays an essential role. In cooperation with US colleagues, physicists from the University of Bonn and Ruhr-Universität Bochum have been able to calculate this legendary carbon nucleus, solving a problem that has kept science guessing for more than 50 years.

The researchers published their results in the coming issue of the scientific journal Physical Review Letters.

"Attempts to calculate the Hoyle state have been unsuccessful since 1954," said Professor Dr. Ulf-G. Meißner (Helmholtz-Institut für Strahlen- und Kernphysik der Universität Bonn). "But now, we have done it!" The Hoyle state is an energy-rich form of the carbon nucleus. It is the mountain pass over which all roads from one valley to the next lead: From the three nuclei of helium gas to the much larger carbon nucleus. This fusion reaction takes place in the hot interior of heavy stars. If the Hoyle state did not exist, only very little carbon or other higher elements such as oxygen, nitrogen and iron could have formed. Without this type of carbon nucleus, life probably also would not have been possible.

The search for the "slave transmitter"

The Hoyle state had been verified by experiments as early as 1954, but calculating it always failed. For this form of carbon consists of only three, very loosely linked helium nuclei -- more of a cloudy diffuse carbon nucleus. And it does not occur individually, only together with other forms of carbon. "This is as if you wanted to analyze a radio signal whose main transmitter and several slave transmitters are interfering with each other," explained Prof. Dr. Evgeny Epelbaum (Institute of Theoretical Physics II at Ruhr-Universität Bochum). The main transmitter is the stable carbon nucleus from which humans -- among others -- are made. "But we are interested in one of the unstable, energy-rich carbon nuclei; so we have to separate the weaker radio transmitter somehow from the dominant signal by means of a noise filter."

What made this possible was a new, improved calculating approach the researchers used that allowed calculating the forces between several nuclear particles more precisely than ever. And in JUGENE, the supercomputer at Forschungszentrum Jülich, a suitable tool was found. It took JUGENE almost a week of calculating. The results matched the experimental data so well that the researchers can be certain that they have indeed calculated the Hoyle state.

More about how the Universe came into existence

"Now we can analyze this exciting and essential form of the carbon nucleus in every detail," explained Prof. Meißner. "We will determine how big it is, and what its structure is. And it also means that we can now take a very close look at the entire chain of how elements are formed."

In future, this may even allow answering philosophical questions using science. For decades, the Hoyle state was a prime example for the theory that natural constants must have precisely their experimentally determined values, and not any different ones, since otherwise we would not be here to observe the Universe (the anthropic principle). "For the Hoyle state this means that it must have exactly the amount of energy it has, or else, we would not exist," said Prof. Meißner. "Now we can calculate whether -- in a changed world with other parameters -- the Hoyle state would indeed have a different energy when comparing the mass of three helium nuclei." If this is so, this would confirm the anthropic principle.

Story Source:

The above story is reprinted (with editorial adaptations by ScienceDaily staff) from materials provided by University of Bonn.

Journal Reference:

Evgeny Epelbaum, Hermann Krebs, Dean Lee, Ulf-G. Meißner. Ab Initio Calculation of the Hoyle State. Physical Review Letters, 2011; 106 (19) DOI: 10.1103/PhysRevLett.106.192501

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Disclaimer: Views expressed in this article do not necessarily reflect those of ScienceDaily or its staff.

View the original article here

Fundamental question on how life started solved: Supercomputer calculates carbon nucleus

ScienceDaily (May 10, 2011) — For carbon, the basis of life, to be able to form in the stars, a certain state of the carbon nucleus plays an essential role. In cooperation with US colleagues, physicists from the University of Bonn and Ruhr-Universität Bochum have been able to calculate this legendary carbon nucleus, solving a problem that has kept science guessing for more than 50 years.

The researchers published their results in the coming issue of the scientific journal Physical Review Letters.

"Attempts to calculate the Hoyle state have been unsuccessful since 1954," said Professor Dr. Ulf-G. Meißner (Helmholtz-Institut für Strahlen- und Kernphysik der Universität Bonn). "But now, we have done it!" The Hoyle state is an energy-rich form of the carbon nucleus. It is the mountain pass over which all roads from one valley to the next lead: From the three nuclei of helium gas to the much larger carbon nucleus. This fusion reaction takes place in the hot interior of heavy stars. If the Hoyle state did not exist, only very little carbon or other higher elements such as oxygen, nitrogen and iron could have formed. Without this type of carbon nucleus, life probably also would not have been possible.

The search for the "slave transmitter"

The Hoyle state had been verified by experiments as early as 1954, but calculating it always failed. For this form of carbon consists of only three, very loosely linked helium nuclei -- more of a cloudy diffuse carbon nucleus. And it does not occur individually, only together with other forms of carbon. "This is as if you wanted to analyze a radio signal whose main transmitter and several slave transmitters are interfering with each other," explained Prof. Dr. Evgeny Epelbaum (Institute of Theoretical Physics II at Ruhr-Universität Bochum). The main transmitter is the stable carbon nucleus from which humans -- among others -- are made. "But we are interested in one of the unstable, energy-rich carbon nuclei; so we have to separate the weaker radio transmitter somehow from the dominant signal by means of a noise filter."

What made this possible was a new, improved calculating approach the researchers used that allowed calculating the forces between several nuclear particles more precisely than ever. And in JUGENE, the supercomputer at Forschungszentrum Jülich, a suitable tool was found. It took JUGENE almost a week of calculating. The results matched the experimental data so well that the researchers can be certain that they have indeed calculated the Hoyle state.

More about how the Universe came into existence

"Now we can analyze this exciting and essential form of the carbon nucleus in every detail," explained Prof. Meißner. "We will determine how big it is, and what its structure is. And it also means that we can now take a very close look at the entire chain of how elements are formed."

In future, this may even allow answering philosophical questions using science. For decades, the Hoyle state was a prime example for the theory that natural constants must have precisely their experimentally determined values, and not any different ones, since otherwise we would not be here to observe the Universe (the anthropic principle). "For the Hoyle state this means that it must have exactly the amount of energy it has, or else, we would not exist," said Prof. Meißner. "Now we can calculate whether -- in a changed world with other parameters -- the Hoyle state would indeed have a different energy when comparing the mass of three helium nuclei." If this is so, this would confirm the anthropic principle.

Story Source:

The above story is reprinted (with editorial adaptations by ScienceDaily staff) from materials provided by University of Bonn.

Journal Reference:

Evgeny Epelbaum, Hermann Krebs, Dean Lee, Ulf-G. Meißner. Ab Initio Calculation of the Hoyle State. Physical Review Letters, 2011; 106 (19) DOI: 10.1103/PhysRevLett.106.192501

Note: If no author is given, the source is cited instead.

Disclaimer: Views expressed in this article do not necessarily reflect those of ScienceDaily or its staff.

View the original article here

Extinctions breed carbon chaos

Massive die-offs left ecosystems vulnerable, analysis suggestsWeb edition : Friday, February 4th, 2011

Big extinctions don’t just wipe out a lot of species. They also send ecological cycles reeling for millions of years, a new study suggests.

Following massive die-offs, the natural processes that keep carbon flowing through marine ecosystems — from tiny photosynthesizers to big fish and between the bottom and the top of the ocean — get broken. For millions of years after at least two global disasters, marine communities were too unstable to keep the molecules churning, researchers report in the February issue of Geology. These “chaotic carbon episodes” could have big ramifications for extinctions in the modern era, say scientists from Brown University in Providence, R.I., and the University of Washington in Seattle.

 In healthy marine ecosystems, diverse swimming predators, lazy filter feeders and myriad other organisms keep the carbon flowing nonstop, says study coauthor Jessica Whiteside, a paleobiologist at Brown.  But after a global extinction, when only a few plants, animals or single-celled critters occupy each rung of the food chain, minicatastrophes like diseases or climatic shifts take big tolls, she says. “If you already have a weakened state of ecosystems, these things that would normally be minor variations now become wildly oscillating,” she says. 

The team looked particularly at the diversity of ancient octopus-like animals called ammonites, which were ultimately wiped out by the same extinction that killed the dinosaurs. Ammonites often swam to catch prey as well as floated idly, snagging debris from ocean currents. But for millions of years after the end-Permian mass extinction 250 million years ago, as well as after the end-Triassic mass extinction 50 million years later, few swimming ammonites survived.

The devastation of ammonites and other life forms left its mark on the geologic record, Whiteside says. Scientists recognize five mass extinctions in Earth’s history. The worst — the end-Permian extinction — killed about 90 percent of ocean-dwelling species. Scientists discovered that after most of these calamities carbon molecules in the environment, on average, got lighter. The culprits behind this drop are major volcanic events like those associated with the end-Permian mass extinction. Volcanoes spew a relatively high proportion of lighter isotopes of carbon — atoms with fewer neutrons in their nuclei — into the atmosphere, says Jean Guex, a paleobiologist with Lausanne University in Switzerland.

“They are not volcanoes like people imagine,” says Guex, who was not involved in either study. “They are fissures which are extruding millions of cubic kilometers of basalts, inducing major atmospheric pollutions with sulfur and heavy metals.”

Tiny photosynthesizers gobble down the lighter carbon in the air, introducing it to the environment and, eventually, the geologic record. In a normally functioning ecosystem, that would cause the proportion of light carbon isotopes in the record to lighten and then eventually return to normal. But when Whiteside’s team eyed carbon isotopes in sedimentary layers from the periods following the end-Permian extinction and the end-Triassic extinction, carbon weights jumped back and forth from heavier to lighter isotopes. She argues that ecosystem instabilities could easily have triggered these wild fluxes. As living organisms died, they floated to the ocean bottom, carrying the lighter carbon molecules in their bodies with them. That left the carbon in the surface waters, on average, heavier, she says. When communities rebounded, carbon weights in the upper oceans dropped back down.

But Guex says that the real chaotic factor in this picture was the environment, not the carbon flows. Undersea volcanoes erupted on and off for millions of years following each extinction event, he argues. “The carbon isotopes mainly reflect these crises.”

Whiteside agrees that such churning could have played a role but cautions against ignoring the ecological factors. Minor volcanic eruptions would have affected weak communities much more than strong ones, she says. 

The team’s conclusions are particularly relevant for the modern era — what many biologists have dubbed the sixth mass extinction, Whiteside notes. Computer simulations of climate change look 100 years into the future, but the impacts of species extinctions today may last long after human pollution has come and gone, she says. “It’s a cautionary tale for the species loss that’s going on right now.”

Found in: Earth and Environment

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Functioning synapse created using carbon nanotubes: Devices might be used in brain prostheses or synthetic brains

ScienceDaily (Apr. 22, 2011) — Engineering researchers the University of Southern California have made a significant breakthrough in the use of nanotechnologies for the construction of a synthetic brain. They have built a carbon nanotube synapse circuit whose behavior in tests reproduces the function of a neuron, the building block of the brain.

The team, which was led by Professor Alice Parker and Professor Chongwu Zhou in the USC Viterbi School of Engineering Ming Hsieh Department of Electrical Engineering, used an interdisciplinary approach combining circuit design with nanotechnology to address the complex problem of capturing brain function.

In a paper published in the proceedings of the IEEE/NIH 2011 Life Science Systems and Applications Workshop in April 2011, the Viterbi team detailed how they were able to use carbon nanotubes to create a synapse.

Carbon nanotubes are molecular carbon structures that are extremely small, with a diameter a million times smaller than a pencil point. These nanotubes can be used in electronic circuits, acting as metallic conductors or semiconductors.

"This is a necessary first step in the process," said Parker, who began the looking at the possibility of developing a synthetic brain in 2006. "We wanted to answer the question: Can you build a circuit that would act like a neuron? The next step is even more complex. How can we build structures out of these circuits that mimic the function of the brain, which has 100 billion neurons and 10,000 synapses per neuron?"

Parker emphasized that the actual development of a synthetic brain, or even a functional brain area is decades away, and she said the next hurdle for the research centers on reproducing brain plasticity in the circuits.

The human brain continually produces new neurons, makes new connections and adapts throughout life, and creating this process through analog circuits will be a monumental task, according to Parker.

She believes the ongoing research of understanding the process of human intelligence could have long-term implications for everything from developing prosthetic nanotechnology that would heal traumatic brain injuries to developing intelligent, safe cars that would protect drivers in bold new ways.

For Jonathan Joshi, a USC Viterbi Ph.D. student who is a co-author of the paper, the interdisciplinary approach to the problem was key to the initial progress. Joshi said that working with Zhou and his group of nanotechnology researchers provided the ideal dynamic of circuit technology and nanotechnology.

"The interdisciplinary approach is the only approach that will lead to a solution. We need more than one type of engineer working on this solution," said Joshi. "We should constantly be in search of new technologies to solve this problem."

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The above story is reprinted (with editorial adaptations by ScienceDaily staff) from materials provided by University of Southern California, via EurekAlert!, a service of AAAS.

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Disclaimer: This article is not intended to provide medical advice, diagnosis or treatment. Views expressed here do not necessarily reflect those of ScienceDaily or its staff.

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