Showing posts with label infrared. Show all posts
Showing posts with label infrared. Show all posts

Monday, 30 January 2012

Bilayer Graphene Works as an Insulator: Research Has Potential Applications in Digital and Infrared Technologies

ScienceDaily  — A research team led by physicists at the University of California, Riverside has identified a property of "bilayer graphene" (BLG) that the researchers say is analogous to finding the Higgs boson in particle physics.

BLG is formed when two graphene sheets are stacked in a special manner. Like graphene, BLG has high current-carrying capacity, also known as high electron conductivity. The high current-carrying capacity results from the extremely high velocities that electrons can acquire in a graphene sheet.Graphene, nature's thinnest elastic material, is a one-atom thick sheet of carbon atoms arranged in a hexagonal lattice. Because of graphene's planar and chicken wire-like structure, sheets of it lend themselves well to stacking.
The physicists report online Jan. 22 in Nature Nanotechnology that in investigating BLG's properties they found that when the number of electrons on the BLG sheet is close to 0, the material becomes insulating (that is, it resists flow of electrical current) -- a finding that has implications for the use of graphene as an electronic material in the semiconductor and electronics industries.
"BLG becomes insulating because its electrons spontaneously organize themselves when their number is small," said Chun Ning (Jeanie) Lau, an associate professor of physics and astronomy and the lead author of the research paper. "Instead of moving around randomly, the electrons move in an orderly fashion. This is called 'spontaneous symmetry breaking' in physics, and is a very important concept since it is the same principle that 'endows' mass for particles in high energy physics."
Lau explained that a typical conductor has a huge number of electrons, which move around randomly, rather like a party with ten thousand guests with no assigned seats at dining tables. If the party only has four guests, however, then the guests will have to interact with each other and sit down at a table. Similarly, when BLG has only a few electrons the interactions cause the electrons to behave in an orderly manner.
New quantum particle
Allan MacDonald, the Sid W. Richardson Foundation Regents Chair in the Department of Physics at The University of Texas at Austin and a coauthor on the research paper, noted that team has measured the mass of a new type of massive quantum particle that can be found only inside BLG crystals.
"The physics which gives these particles their mass is closely analogous to the physics which makes the mass of a proton inside an atomic nucleus very much larger than the mass of the quarks from which it is formed," he said. "Our team's particle is made of electrons, however, not quarks."
MacDonald explained that the experiment the research team conducted was motivated by theoretical work which anticipated that new particles would emerge from the electron sea of a BLG crystal.
"Now that the eagerly anticipated particles have been found, future experiments will help settle an ongoing theoretical debate on their properties," he said.
Practical applications
An important finding of the research team is that the intrinsic "energy gap" in BLG grows with increasing magnetic field.
In solid state physics, an energy gap (or band gap) refers to an energy range in a solid where no electron states can exist. Generally, the size of the energy gap of a material determines whether it is a metal (no gap), semiconductor (small gap) or insulator (large gap). The presence of an energy gap in silicon is critical to the semiconductor industry since, for digital applications, engineers need to turn the device 'on' or conductive, and 'off' or insulating.
Single layer graphene (SLG) is gapless, however, and cannot be completely turned off because regardless of the number of electrons on SLG, it always remains metallic and a conductor.
"This is terribly disadvantageous from an electronics point of view," said Lau, a member of UC Riverside's Center for Nanoscale Science and Engineering. "BLG, on the other hand, can in fact be turned off. Our research is in the initial phase, and, presently, the band gap is still too small for practical applications. What is tremendously exciting though is that this work suggests a promising route -- trilayer graphene and tetralayer graphene, which are likely to have much larger energy gaps that can be used for digital and infrared technologies. We already have begun working with these materials."
Lau and MacDonald were joined in the research by J. Velasco Jr. (the first author of the research paper), L. Jing, W. Bao, Y. Lee, P. Kratz, V. Aji, M. Bockrath, and C. Varma at UCR; R. Stillwell and D. Smirnov at the National High Magnetic Field Laboratory, Tallahassee, Fla.; and Fan Zhang and J. Jung at The University of Texas at Austin.
The research was supported by grants from the National Science Foundation, Office of Naval Research, FENA Focus Center, and other agencies.


Story Source:
The above story is reprinted from materials provided by University of California - Riverside.
Note: Materials may be edited for content and length. For further information, please contact the source cited above.

Journal Reference:
  1. J. Velasco, L. Jing, W. Bao, Y. Lee, P. Kratz, V. Aji, M. Bockrath, C. N. Lau, C. Varma, R. Stillwell, D. Smirnov, Fan Zhang, J. Jung, A. H. MacDonald. Transport spectroscopy of symmetry-broken insulating states in bilayer graphene. Nature Nanotechnology, 2012; DOI:10.1038/nnano.2011.251

Friday, 20 May 2011

Measurement of 'hot' electrons could have solar energy payoff; Nanoantennas hold promise for infrared photovoltaics

ScienceDaily (May 9, 2011) — Basic scientific curiosity paid off in unexpected ways when Rice University researchers investigating the fundamental physics of nanomaterials discovered a new technology that could dramatically improve solar energy panels.

The research is described in a new paper in the journal Science.

"We're merging the optics of nanoscale antennas with the electronics of semiconductors," said lead researcher Naomi Halas, Rice's Stanley C. Moore Professor in Electrical and Computer Engineering. "There's no practical way to directly detect infrared light with silicon, but we've shown that it is possible if you marry the semiconductor to a nanoantenna. We expect this technique will be used in new scientific instruments for infrared-light detection and for higher-efficiency solar cells."

More than a third of the solar energy on Earth arrives in the form of infrared light. But silicon -- the material that's used to convert sunlight into electricity in the vast majority of today's solar panels -- cannot capture infrared light's energy. Every semiconductor, including silicon, has a "bandgap" where light below a certain frequency passes directly through the material and is unable to generate an electrical current. By attaching a metal nanoantenna to the silicon, where the tiny antenna is specially tuned to interact with infrared light, the Rice team showed they could extend the frequency range for electricity generation into the infrared. When infrared light hits the antenna, it creates a "plasmon," a wave of energy that sloshes through the antenna's ocean of free electrons. The study of plasmons is one of Halas' specialties, and the new paper resulted from basic research into the physics of plasmons that began in her lab years ago.

It has been known that plasmons decay and give up their energy in two ways; they either emit a photon of light or they convert the light energy into heat. The heating process begins when the plasmon transfers its energy to a single electron -- a 'hot' electron. Rice graduate student Mark Knight, lead author on the paper, together with Rice theoretical physicist Peter Nordlander, his graduate student Heidar Sobhani, and Halas set out to design an experiment to directly detect the hot electrons resulting from plasmon decay.

Patterning a metallic nanoantenna directly onto a semiconductor to create a "Schottky barrier," Knight showed that the infrared light striking the antenna would result in a hot electron that could jump the barrier, which creates an electrical current. This works for infrared light at frequencies that would otherwise pass directly through the device.

"The nanoantenna-diodes we created to detect plasmon-generated hot electrons are already pretty good at harvesting infrared light and turning it directly into electricity," Knight said. "We are eager to see whether this expansion of light-harvesting to infrared frequencies will directly result in higher-efficiency solar cells."

Story Source:

The above story is reprinted (with editorial adaptations by ScienceDaily staff) from materials provided by Rice University, via EurekAlert!, a service of AAAS.

Journal Reference:

Mark W. Knight, Heidar Sobhani, Peter Nordlander, and Naomi J. Halas. Photodetection with Active Optical Antennas. Science, 2011; 332 (6030): 702-704 DOI: 10.1126/science.1203056

Note: If no author is given, the source is cited instead.

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