Graphene Supermaterial Goes Superpermeable: Can Be Used to Distill Alcohol

Dr Nair with the membrane. (Credit: Image courtesy of Manchester University)

Wonder material graphene has revealed another of its extraordinary properties -- University of Manchester researchers have found that it is superpermeable with respect to water.

Graphene is one of the wonders of the science world, with the potential to create foldaway mobile phones, wallpaper-thin lighting panels and the next generation of aircraft. The new finding at the University of Manchester gives graphene's potential a most surprising dimension -- graphene can also be used for distilling alcohol.

In a report published in Science, a team led by Professor Sir Andre Geim shows that graphene-based membranes are impermeable to all gases and liquids (vacuum-tight). However, water evaporates through them as quickly as if the membranes were not there at all.

This newly-found property can now be added to the already long list of superlatives describing graphene. It is the thinnest known material in the universe and the strongest ever measured. It conducts electricity and heat better than any other material. It is the stiffest one too and, at the same time, it is the most ductile. Demonstrating its remarkable properties won University of Manchester academics the Nobel Prize in Physics in 2010.

Now the University of Manchester scientists have studied membranes from a chemical derivative of graphene called graphene oxide. Graphene oxide is the same graphene sheet but it is randomly covered with other molecules such as hydroxyl groups OH-. Graphene oxide sheets stack on top of each other and form a laminate.

The researchers prepared such laminates that were hundreds times thinner than a human hair but remained strong, flexible and were easy to handle.

When a metal container was sealed with such a film, even the most sensitive equipment was unable to detect air or any other gas, including helium, to leak through.

It came as a complete surprise that, when the researchers tried the same with ordinary water, they found that it evaporates without noticing the graphene seal. Water molecules diffused through the graphene-oxide membranes with such a great speed that the evaporation rate was the same independently whether the container was sealed or completely open.

Dr Rahul Nair, who was leading the experimental work, offers the following explanation: "Graphene oxide sheets arrange in such a way that between them there is room for exactly one layer of water molecules. They arrange themselves in one molecule thick sheets of ice which slide along the graphene surface with practically no friction.

"If another atom or molecule tries the same trick, it finds that graphene capillaries either shrink in low humidity or get clogged with water molecules."

"Helium gas is hard to stop. It slowly leaks even through a millimetre -thick window glass but our ultra-thin films completely block it. At the same time, water evaporates through them unimpeded. Materials cannot behave any stranger," comments Professor Geim. "You cannot help wondering what else graphene has in store for us."

"This unique property can be used in situations where one needs to remove water from a mixture or a container, while keeping in all the other ingredients," says Dr Irina Grigorieva who also participated in the research.

"Just for a laugh, we sealed a bottle of vodka with our membranes and found that the distilled solution became stronger and stronger with time. Neither of us drinks vodka but it was great fun to do the experiment," adds Dr Nair.

The Manchester researchers report this experiment in theirScience paper, too, but they say they do not envisage use of graphene in distilleries, nor offer any immediate ideas for applications.

However, Professor Geim adds 'The properties are so unusual that it is hard to imagine that they cannot find some use in the design of filtration, separation or barrier membranes and for selective removal of water'.

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The above story is reprinted from materials provided byManchester University, via AlphaGalileo.

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Journal Reference:

1. R. R. Nair, H. A. Wu, P. N. Jayaram, I. V. Grigorieva, A. K. Geim. Unimpeded Permeation of Water Through Helium-Leak-Tight Graphene-Based Membranes.Science, 2012; 335 (6067): 442 DOI:10.1126/science.1211694

Bilayer Graphene Works as an Insulator: Research Has Potential Applications in Digital and Infrared Technologies

ScienceDaily  — A research team led by physicists at the University of California, Riverside has identified a property of "bilayer graphene" (BLG) that the researchers say is analogous to finding the Higgs boson in particle physics.

BLG is formed when two graphene sheets are stacked in a special manner. Like graphene, BLG has high current-carrying capacity, also known as high electron conductivity. The high current-carrying capacity results from the extremely high velocities that electrons can acquire in a graphene sheet.Graphene, nature's thinnest elastic material, is a one-atom thick sheet of carbon atoms arranged in a hexagonal lattice. Because of graphene's planar and chicken wire-like structure, sheets of it lend themselves well to stacking.

The physicists report online Jan. 22 in Nature Nanotechnology that in investigating BLG's properties they found that when the number of electrons on the BLG sheet is close to 0, the material becomes insulating (that is, it resists flow of electrical current) -- a finding that has implications for the use of graphene as an electronic material in the semiconductor and electronics industries.

"BLG becomes insulating because its electrons spontaneously organize themselves when their number is small," said Chun Ning (Jeanie) Lau, an associate professor of physics and astronomy and the lead author of the research paper. "Instead of moving around randomly, the electrons move in an orderly fashion. This is called 'spontaneous symmetry breaking' in physics, and is a very important concept since it is the same principle that 'endows' mass for particles in high energy physics."

Lau explained that a typical conductor has a huge number of electrons, which move around randomly, rather like a party with ten thousand guests with no assigned seats at dining tables. If the party only has four guests, however, then the guests will have to interact with each other and sit down at a table. Similarly, when BLG has only a few electrons the interactions cause the electrons to behave in an orderly manner.

New quantum particle

Allan MacDonald, the Sid W. Richardson Foundation Regents Chair in the Department of Physics at The University of Texas at Austin and a coauthor on the research paper, noted that team has measured the mass of a new type of massive quantum particle that can be found only inside BLG crystals.

"The physics which gives these particles their mass is closely analogous to the physics which makes the mass of a proton inside an atomic nucleus very much larger than the mass of the quarks from which it is formed," he said. "Our team's particle is made of electrons, however, not quarks."

MacDonald explained that the experiment the research team conducted was motivated by theoretical work which anticipated that new particles would emerge from the electron sea of a BLG crystal.

"Now that the eagerly anticipated particles have been found, future experiments will help settle an ongoing theoretical debate on their properties," he said.

Practical applications

An important finding of the research team is that the intrinsic "energy gap" in BLG grows with increasing magnetic field.

In solid state physics, an energy gap (or band gap) refers to an energy range in a solid where no electron states can exist. Generally, the size of the energy gap of a material determines whether it is a metal (no gap), semiconductor (small gap) or insulator (large gap). The presence of an energy gap in silicon is critical to the semiconductor industry since, for digital applications, engineers need to turn the device 'on' or conductive, and 'off' or insulating.

Single layer graphene (SLG) is gapless, however, and cannot be completely turned off because regardless of the number of electrons on SLG, it always remains metallic and a conductor.

"This is terribly disadvantageous from an electronics point of view," said Lau, a member of UC Riverside's Center for Nanoscale Science and Engineering. "BLG, on the other hand, can in fact be turned off. Our research is in the initial phase, and, presently, the band gap is still too small for practical applications. What is tremendously exciting though is that this work suggests a promising route -- trilayer graphene and tetralayer graphene, which are likely to have much larger energy gaps that can be used for digital and infrared technologies. We already have begun working with these materials."

Lau and MacDonald were joined in the research by J. Velasco Jr. (the first author of the research paper), L. Jing, W. Bao, Y. Lee, P. Kratz, V. Aji, M. Bockrath, and C. Varma at UCR; R. Stillwell and D. Smirnov at the National High Magnetic Field Laboratory, Tallahassee, Fla.; and Fan Zhang and J. Jung at The University of Texas at Austin.

The research was supported by grants from the National Science Foundation, Office of Naval Research, FENA Focus Center, and other agencies.

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Journal Reference:

1. J. Velasco, L. Jing, W. Bao, Y. Lee, P. Kratz, V. Aji, M. Bockrath, C. N. Lau, C. Varma, R. Stillwell, D. Smirnov, Fan Zhang, J. Jung, A. H. MacDonald. Transport spectroscopy of symmetry-broken insulating states in bilayer graphene. Nature Nanotechnology, 2012; DOI:10.1038/nnano.2011.251

Graphene 'Invisible' to Water: How the Extreme Thinness of Graphene Enables Near-Perfect Wetting Transparency

Graphene is the thinnest material known to science. The nanomaterial is so thin, in fact, water often doesn’t even know it’s there. A new study from Rensselaer Polytechnic Institute shows how the extreme thinness of graphene enables near-perfect wetting transparency. The findings could help inform a new generation of graphene-based flexible electronic devices. Additionally, the research suggests a new type of heat pipe that uses graphene-coated copper to cool computer chips. (Credit: Rensselaer/Koratkar)

ScienceDaily (Jan. 23, 2012) — Graphene is the thinnest material known to science. The nanomaterial is so thin, in fact, water often doesn't even know it's there.

Results of the study were published in the journal Nature Materials. The findings could help inform a new generation of graphene-based flexible electronic devices. Additionally, the research suggests a new type of heat pipe that uses graphene-coated copper to cool computer chips.Engineering researchers at Rensselaer Polytechnic Institute and Rice University coated pieces of gold, copper, and silicon with a single layer of graphene, and then placed a drop of water on the coated surfaces. Surprisingly, the layer of graphene proved to have virtually no impact on the manner in which water spreads on the surfaces.

The discovery stemmed from a cross-university collaboration led by Rensselaer Professor Nikhil Koratkar and Rice Professor Pulickel Ajayan.

"We coated several different surfaces with graphene, and then put a drop of water on them to see what would happen. What we saw was a big surprise -- nothing changed. The graphene was completely transparent to the water," said Koratkar, a faculty member in the Department of Mechanical, Aerospace, and Nuclear Engineering and the Department of Materials Science and Engineering at Rensselaer. "The single layer of graphene was so thin that it did not significantly disrupt the non-bonding van der Waals forces that control the interaction of water with the solid surface. It's an exciting discovery, and is another example of the unique and extraordinary characteristics of graphene."

Results of the study are detailed in the Nature Materials paper "Wetting transparency of graphene."

Essentially an isolated layer of the graphite found commonly in our pencils or the charcoal we burn on our barbeques, graphene is single layer of carbon atoms arranged like a nanoscale chicken-wire fence. Graphene is known to have excellent mechanical properties. The material is strong and tough and because of its flexibility can evenly coat nearly any surface. Many researchers and technology leaders see graphene as an enabling material that could greatly advance the advent of flexible, paper-thin devices and displays. Used as a coating for such devices, the graphene would certainly come into contact with moisture. Understanding how graphene interacts with moisture was the impetus behind this new study.

The spreading of water on a solid surface is called wetting. Calculating wettability involves placing a drop of water on a surface, and then measuring the angle at which the droplet meets the surface. The droplet will ball up and have a high contact angle on a hydrophobic surface. Inversely, the droplet will spread out and have a low contact angle on a hydrophilic surface.

The contact angle of gold is about 77 degrees. Koratkar and Ajayan found that after coating a gold surface with a single layer of graphene, the contact angle became about 78 degrees. Similarly, the contact angle of silicon rose from roughly 32 degrees to roughly 33 degrees, and copper increased from around 85 degrees to around 86 degrees, after adding a layer of graphene.

These results surprised the researchers. Graphene is impermeable, as the tiny spaces between its linked carbon atoms are too small for water, or a single proton, or anything else to fit through. Because of this, one would expect that water would not act as if it were on gold, silicon, or copper, since the graphene coating prevents the water from directly contacting these surfaces. But the research findings clearly show how the water is able to sense the presence of the underlying surface, and spreads on those surfaces as if the graphene were not present at all.

As the researchers increased the number of layers of graphene, however, it became less transparent to the water and the contact angles jumped significantly. After adding six layers of graphene, the water no longer saw the gold, copper, or silicon and instead behaved as if it was sitting on graphite.

The reason for this perplexing behavior is subtle. Water forms chemical or hydrogen bonds with certain surfaces, while the attraction of water to other surfaces is dictated by non-bonding interactions called van der Waals forces. These non-bonding forces are not unlike a nanoscale version of gravity, Koratkar said. Similar to how gravity dictates the interaction between Earth and the sun, van der Waals forces dictate the interaction between atoms and molecules.

In the case of gold, copper, silicon, and other materials, the van der Waals forces between the surface and water droplet determine the attraction of water to the surface and dictate how water spreads on the solid surface. In general, these forces have a range of at least several nanometers. Because of the long range, these forces are not disrupted by the presence of a single-atom-thick layer of graphene between the surface and the water. In other words, the van der Waals forces are able to "look through" ultra-thin graphene coatings, Koratkar said.

If you continue to add additional layers of graphene, however, the van der Waals forces increasingly "see" the carbon coating on top of the material instead of the underlying surface material. After stacking six layers of graphene, the separation between the graphene and the surface is sufficiently large to ensure that the van der Waals forces can now no longer sense the presence of the underlying surface and instead only see the graphene coating. On surfaces where water forms hydrogen bonds with the surface, the wetting transparency effect described above does not hold because such chemical bonds cannot form through the graphene layer.

Along with conducting physical experiments, the researchers verified their findings with molecular dynamics modeling as well as classical theoretical modeling.

"We found that van der Waals forces are not disrupted by graphene. This effect is an artifact of the extreme thinness of graphene -- which is only about 0.3 nanometers thick," Koratkar said. "Nothing can rival the thinness of graphene. Because of this, graphene is the ideal material for wetting angle transparency."

"Moreover, graphene is strong and flexible, and it does not easily crack or break apart," he said. "Additionally, it is easy to coat a surface with graphene using chemical vapor deposition, and it is relatively uncomplicated to deposit uniform and homogeneous graphene coatings over large areas. Finally, graphene is chemically inert, which means a graphene coating will not oxidize away. No single material system can provide all of the above attributes that graphene is able to offer."

A practical application of this new discovery is to coat copper surfaces used in dehumidifiers. Because of its exposure to water, copper in dehumidifier systems oxidizes, which in turn decreases its ability to transfer heat and makes the entire device less efficient. Coating the copper with graphene prevents oxidation, the researchers said, and the operation of the device is unaffected because graphene does not change the way water interacts with copper. This same concept may be applied to improve the ability of heat pipes to dissipate heat from computer chips, Koratkar said.

"It's an interesting idea. The graphene doesn't cause any significant change to the wettability of copper, and at the same time it passivates the copper surface and prevents it from oxidizing," he said.

Along with Koratkar and Ajayan, co-authors of the paper are Yunfeng Shi, assistant professor in the Department of Materials Science and Engineering at Rensselaer; Rensselaer mechanical engineering graduate students Javad Rafiee, Abhay Thomas, and Fazel Yavari; Rensselaer physics graduate student Xi Mi; and Rice mechanical and materials engineering graduate student Hemtej Gullapalli.

This research was supported in part by the Advanced Energy Consortium (AEC); the National Science Foundation (NSF); and the Office of Naval Research (ONR) graphene Multidisciplinary University Research Initiative (MURI).

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Journal Reference:

1. Javad Rafiee, Xi Mi, Hemtej Gullapalli, Abhay V. Thomas, Fazel Yavari, Yunfeng Shi, Pulickel M. Ajayan, Nikhil A. Koratkar. Wetting transparency of graphene. Nature Materials, 2012; DOI: 10.1038/NMAT3228

Secrets of tunneling through energy barriers: How massless electrons tunnel through energy barriers in a carbon sheet called graphene

ScienceDaily (Nov. 7, 2011) — Electrons moving in graphene behave in an unusual way, as demonstrated by 2010 Nobel Prize laureates for physics Andre Geim and Konstantin Novoselov, who performed transport experiments on this one-carbon-atom-thick material. A review article, just published in The European Physical Journal B, explores the theoretical and experimental results to date of electrons tunneling through energy barriers in graphene.

As good an electrical conductor at room temperature as copper graphene is, it also outperforms all other known materials as a heat conductor. It is both very dense due to its honeycomb lattice structure and almost completely transparent, making it suitable, among other applications, for touch screens and light panels.

What could partly explain graphene's properties is that electrons travelling inside the material behave as if they were massless. Their behavior is described by the so-called massless Dirac equation that is normally used for high-energy particles such as neutrinos nearing the speed of light. However, electrons in graphene move at a constant speed 300 times smaller than that of light.

In this review, P.E. Allain and J.N. Fuchs, both from the Université Paris-Sud, focus on the tunneling effect occurring when Dirac electrons found in graphene are transmitted through different types of energy barriers. Contrary to the laws of classical mechanics, which govern larger scale particles that cannot cross energy barriers, electron tunneling is possible in quantum mechanics -- though only under restricted conditions, depending on the width and energy height of the barrier.

However, the Dirac electrons found in graphene can tunnel through energy barriers regardless of their width and energy height; a phenomenon called Klein tunneling, described theoretically for 3D massive Dirac electrons by the Swedish physicist Oskar Klein in 1929. Graphene was the first material in which Klein tunneling was observed experimentally, as massive Dirac electrons required energy barriers too large to be observed.

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P. E. Allain, J. N. Fuchs. Klein tunneling in graphene: optics with massless electrons. The European Physical Journal B, 2011; 83 (3): 301 DOI: 10.1140/epjb/e2011-20351-3

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Secrets of tunneling through energy barriers: How massless electrons tunnel through energy barriers in a carbon sheet called graphene

ScienceDaily (Nov. 7, 2011) — Electrons moving in graphene behave in an unusual way, as demonstrated by 2010 Nobel Prize laureates for physics Andre Geim and Konstantin Novoselov, who performed transport experiments on this one-carbon-atom-thick material. A review article, just published in The European Physical Journal B, explores the theoretical and experimental results to date of electrons tunneling through energy barriers in graphene.

As good an electrical conductor at room temperature as copper graphene is, it also outperforms all other known materials as a heat conductor. It is both very dense due to its honeycomb lattice structure and almost completely transparent, making it suitable, among other applications, for touch screens and light panels.

What could partly explain graphene's properties is that electrons travelling inside the material behave as if they were massless. Their behavior is described by the so-called massless Dirac equation that is normally used for high-energy particles such as neutrinos nearing the speed of light. However, electrons in graphene move at a constant speed 300 times smaller than that of light.

In this review, P.E. Allain and J.N. Fuchs, both from the Université Paris-Sud, focus on the tunneling effect occurring when Dirac electrons found in graphene are transmitted through different types of energy barriers. Contrary to the laws of classical mechanics, which govern larger scale particles that cannot cross energy barriers, electron tunneling is possible in quantum mechanics -- though only under restricted conditions, depending on the width and energy height of the barrier.

However, the Dirac electrons found in graphene can tunnel through energy barriers regardless of their width and energy height; a phenomenon called Klein tunneling, described theoretically for 3D massive Dirac electrons by the Swedish physicist Oskar Klein in 1929. Graphene was the first material in which Klein tunneling was observed experimentally, as massive Dirac electrons required energy barriers too large to be observed.

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Journal Reference:

P. E. Allain, J. N. Fuchs. Klein tunneling in graphene: optics with massless electrons. The European Physical Journal B, 2011; 83 (3): 301 DOI: 10.1140/epjb/e2011-20351-3

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Graphene grows better on certain copper crystals

ScienceDaily (Oct. 27, 2011) — New observations could improve industrial production of high-quality graphene, hastening the era of graphene-based consumer electronics, thanks to University of Illinois engineers.

By combining data from several imaging techniques, the team found that the quality of graphene depends on the crystal structure of the copper substrate it grows on. Led by electrical and computer engineering professors Joseph Lyding and Eric Pop, the researchers published their findings in the journal Nano Letters.

"Graphene is a very important material," Lyding said. "The future of electronics may depend on it. The quality of its production is one of the key unsolved problems in nanotechnology. This is a step in the direction of solving that problem."

To produce large sheets of graphene, methane gas is piped into a furnace containing a sheet of copper foil. When the methane strikes the copper, the carbon-hydrogen bonds crack. Hydrogen escapes as gas, while the carbon sticks to the copper surface. The carbon atoms move around until they find each other and bond to make graphene. Copper is an appealing substrate because it is relatively cheap and promotes single-layer graphene growth, which is important for electronics applications.

"It's a very cost-effective, straightforward way to make graphene on a large scale," said Joshua Wood, a graduate student and the lead author of the paper.

"However, this does not take into consideration the subtleties of growing graphene," he said. "Understanding these subtleties is important for making high-quality, high-performance electronics."

While graphene grown on copper tends to be better than graphene grown on other substrates, it remains riddled with defects and multi-layer sections, precluding high-performance applications. Researchers have speculated that the roughness of the copper surface may affect graphene growth, but the Illinois group found that the copper's crystal structure is more important.

Copper foils are a patchwork of different crystal structures. As the methane falls onto the foil surface, the shapes of the copper crystals it encounters affect how well the carbon atoms form graphene.

Different crystal shapes are assigned index numbers. Using several advanced imaging techniques, the Illinois team found that patches of copper with higher index numbers tend to have lower-quality graphene growth. They also found that two common crystal structures, numbered (100) and (111), have the worst and the best growth, respectively. The (100) crystals have a cubic shape, with wide gaps between atoms. Meanwhile, (111) has a densely packed hexagonal structure.

"In the (100) configuration the carbon atoms are more likely to stick in the holes in the copper on the atomic level, and then they stack vertically rather than diffusing out and growing laterally," Wood said. "The (111) surface is hexagonal, and graphene is also hexagonal. It's not to say there's a perfect match, but that there's a preferred match between the surfaces."

Researchers now are faced with balancing the cost of all (111) copper and the value of high-quality, defect-free graphene. It is possible to produce single-crystal copper, but it is difficult and prohibitively expensive.

The U. of I. team speculates that it may be possible to improve copper foil manufacturing so that it has a higher percentage of (111) crystals. Graphene grown on such foil would not be ideal, but may be "good enough" for most applications.

"The question is, how do you optimize it while still maintaining cost effectiveness for technological applications?" said Pop, a co-author of the paper. "As a community, we're still writing the cookbook for graphene. We're constantly refining our techniques, trying out new recipes. As with any technology in its infancy, we are still exploring what works and what doesn't."

Next, the researchers hope to use their methodology to study the growth of other two-dimensional materials, including insulators to improve graphene device performance. They also plan to follow up on their observations by growing graphene on single-crystal copper.

"There's a lot of confusion in the graphene business right now," Lyding said. "The fact that there is a clear observational difference between these different growth indices helps steer the research and will probably lead to more quantitative experiments as well as better modeling. This paper is funneling things in that direction."

Lyding and Pop are affiliated with the Beckman Institute for Advanced Science and Technology at the U. of I. The Office of Naval Research, the Air Force Office of Scientific Research, and the Army Research Office supported this research.

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Journal Reference:

Joshua D. Wood, Scott W. Schmucker, Austin S. Lyons, Eric Pop, Joseph W. Lyding. Effects of Polycrystalline Cu Substrate on Graphene Growth by Chemical Vapor Deposition. Nano Letters, 2011; : 111004083339002 DOI: 10.1021/nl201566c

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Giant flakes make graphene oxide gel: Discovery could boost metamaterials, high-strength fibers

ScienceDaily (Oct. 20, 2011) — Giant flakes of graphene oxide in water aggregate like a stack of pancakes, but infinitely thinner, and in the process gain characteristics that materials scientists may find delicious.

A new paper by scientists at Rice University and the University of Colorado details how slices of graphene, the single-atom form of carbon, in a solution arrange themselves to form a nematic liquid crystal in which particles are free-floating but aligned.

That much was already known. The new twist is that if the flakes -- in this case, graphene oxide -- are big enough and concentrated enough, they retain their alignment as they form a gel. That gel is a handy precursor for manufacturing metamaterials or fibers with unique mechanical and electronic properties.

The team reported its discovery online this week in the Royal Society of Chemistry journal Soft Matter. Rice authors include Matteo Pasquali, a professor of chemical and biomolecular engineering and of chemistry; James Tour, the T.T. and W.F. Chao Chair in Chemistry as well as a professor of mechanical engineering and materials science and of computer science; postdoctoral research associate Dmitry Kosynkin; and graduate students Budhadipta Dan and Natnael Behabtu. Ivan Smalyukh, an assistant professor of physics at the University of Colorado at Boulder, led research for his group, in which Dan served as a visiting scientist.

"Graphene materials and fluid phases are a great research area," Pasquali said. "From the fundamental point of view, fluid phases comprising flakes are relatively unexplored, and certainly so when the flakes have important electronic properties.

"From the application standpoint, graphene and graphene oxide can be important building blocks in such areas as flexible electronics and conductive and high-strength materials, and can serve as templates for ordering plasmonic structures," he said.

By "giant," the researchers referred to irregular flakes of graphene oxide up to 10,000 times as wide as they are high. (That's still impossibly small: on average, roughly 12 microns wide and less than a nanometer high.) Previous studies showed smaller bits of pristine graphene suspended in acid would form a liquid crystal and that graphene oxide would do likewise in other solutions, including water.

This time the team discovered that if the flakes are big enough and concentrated enough, the solution becomes semisolid. When they constrained the gel to a thin pipette and evaporated some of the water, the graphene oxide flakes got closer to each other and stacked up spontaneously, although imperfectly.

"The exciting part for me is the spontaneous ordering of graphene oxide into a liquid crystal, which nobody had observed before," said Behabtu, a member of Pasquali's lab. "It's still a liquid, but it's ordered. That's useful to make fibers, but it could also induce order on other particles like nanorods."

He said it would be a simple matter to heat the concentrated gel and extrude it into something like carbon fiber, with enhanced properties provided by "mix-ins."

Testing the possibilities, the researchers mixed gold microtriangles and glass microrods into the solution, and found both were effectively forced to line up with the pancaking flakes. Their inclusion also helped the team get visual confirmation of the flakes' orientation.

The process offers the possibility of the large-scale ordering and alignment of such plasmonic particles as gold, silver and palladium nanorods, important components in optoelectronic devices and metamaterials, they reported.

Behabtu added that heating the gel "crosslinks the flakes, and that's good for mechanical strength. You can even heat graphene oxide enough to reduce it, stripping out the oxygen and turning it back into graphite."

Co-authors of the paper are Angel Martinez and Julian Evans, graduate students of Smalyukh at the University of Colorado at Boulder.

The Institute for Complex Adaptive Matter, the Colorado Renewable and Sustainable Energy Initiative, the National Science Foundation, the Air Force Research Lab, the Air Force Office of Scientific Research, the Welch Foundation, the U.S. Army Corps of Engineers Environmental Quality and Installation Program and M-I Swaco supported the research.

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Budhadipta Dan, Natnael Behabtu, Angel Martinez, Julian S. Evans, Dmitry V. Kosynkin, James M. Tour, Matteo Pasquali, Ivan I. Smalyukh. Liquid crystals of aqueous, giant graphene oxide flakes. Soft Matter, 2011; DOI: 10.1039/C1SM06418E

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Giant flakes make graphene oxide gel: Discovery could boost metamaterials, high-strength fibers

ScienceDaily (Oct. 20, 2011) — Giant flakes of graphene oxide in water aggregate like a stack of pancakes, but infinitely thinner, and in the process gain characteristics that materials scientists may find delicious.

A new paper by scientists at Rice University and the University of Colorado details how slices of graphene, the single-atom form of carbon, in a solution arrange themselves to form a nematic liquid crystal in which particles are free-floating but aligned.

That much was already known. The new twist is that if the flakes -- in this case, graphene oxide -- are big enough and concentrated enough, they retain their alignment as they form a gel. That gel is a handy precursor for manufacturing metamaterials or fibers with unique mechanical and electronic properties.

The team reported its discovery online this week in the Royal Society of Chemistry journal Soft Matter. Rice authors include Matteo Pasquali, a professor of chemical and biomolecular engineering and of chemistry; James Tour, the T.T. and W.F. Chao Chair in Chemistry as well as a professor of mechanical engineering and materials science and of computer science; postdoctoral research associate Dmitry Kosynkin; and graduate students Budhadipta Dan and Natnael Behabtu. Ivan Smalyukh, an assistant professor of physics at the University of Colorado at Boulder, led research for his group, in which Dan served as a visiting scientist.

"Graphene materials and fluid phases are a great research area," Pasquali said. "From the fundamental point of view, fluid phases comprising flakes are relatively unexplored, and certainly so when the flakes have important electronic properties.

"From the application standpoint, graphene and graphene oxide can be important building blocks in such areas as flexible electronics and conductive and high-strength materials, and can serve as templates for ordering plasmonic structures," he said.

By "giant," the researchers referred to irregular flakes of graphene oxide up to 10,000 times as wide as they are high. (That's still impossibly small: on average, roughly 12 microns wide and less than a nanometer high.) Previous studies showed smaller bits of pristine graphene suspended in acid would form a liquid crystal and that graphene oxide would do likewise in other solutions, including water.

This time the team discovered that if the flakes are big enough and concentrated enough, the solution becomes semisolid. When they constrained the gel to a thin pipette and evaporated some of the water, the graphene oxide flakes got closer to each other and stacked up spontaneously, although imperfectly.

"The exciting part for me is the spontaneous ordering of graphene oxide into a liquid crystal, which nobody had observed before," said Behabtu, a member of Pasquali's lab. "It's still a liquid, but it's ordered. That's useful to make fibers, but it could also induce order on other particles like nanorods."

He said it would be a simple matter to heat the concentrated gel and extrude it into something like carbon fiber, with enhanced properties provided by "mix-ins."

Testing the possibilities, the researchers mixed gold microtriangles and glass microrods into the solution, and found both were effectively forced to line up with the pancaking flakes. Their inclusion also helped the team get visual confirmation of the flakes' orientation.

The process offers the possibility of the large-scale ordering and alignment of such plasmonic particles as gold, silver and palladium nanorods, important components in optoelectronic devices and metamaterials, they reported.

Behabtu added that heating the gel "crosslinks the flakes, and that's good for mechanical strength. You can even heat graphene oxide enough to reduce it, stripping out the oxygen and turning it back into graphite."

Co-authors of the paper are Angel Martinez and Julian Evans, graduate students of Smalyukh at the University of Colorado at Boulder.

The Institute for Complex Adaptive Matter, the Colorado Renewable and Sustainable Energy Initiative, the National Science Foundation, the Air Force Research Lab, the Air Force Office of Scientific Research, the Welch Foundation, the U.S. Army Corps of Engineers Environmental Quality and Installation Program and M-I Swaco supported the research.

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The above story is reprinted from materials provided by Rice University.

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Journal Reference:

Budhadipta Dan, Natnael Behabtu, Angel Martinez, Julian S. Evans, Dmitry V. Kosynkin, James M. Tour, Matteo Pasquali, Ivan I. Smalyukh. Liquid crystals of aqueous, giant graphene oxide flakes. Soft Matter, 2011; DOI: 10.1039/C1SM06418E

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Frustration inspires new form of graphene

ScienceDaily (Oct. 14, 2011) — They're the building block of graphite -- ultra-thin sheets of carbon, just one atom thick, whose discovery was lauded in 2010 with a Nobel Prize in Physics.

The seemingly simple material is graphene, and many researchers believe it has great potential for many applications, from electronic devices to high-performance composite materials. Graphene is extremely strong, an excellent conductor, and with no internal structure at all, it offers an abundance of surface area -- much like a sheet of paper.

When it comes to producing and utilizing graphene on a large scale, however, researchers have come upon a major problem: the material's tendency to aggregate. Like paper, graphene sheets easily stack into piles, significantly reducing their surface area and making them unprocessable.

Researchers at Northwestern University have now developed a new form of graphene that does not stack. The new material -- inspired by a trash can full of crumpled-up papers -- is made by crumpling the graphene sheets into balls.

A paper describing the findings was published Oct. 13 in the journal ACS Nano.

Graphene-based materials are very easily aggregated due to the strong interaction between the sheets, called "Van der Waals attraction." Therefore, common steps in materials processing, such as heating, solvent washing, compression, and mixing with other materials, can affect how the sheets are stacked. When the paper-like sheets band together -- picture a deck of cards -- their surface area is lost; with just a fraction of its original surface area available, the material becomes less effective. Stacked graphene sheets also become rigid and lose their processability.

Some scientists have tried to physically keep the sheets apart by inserting non-carbon "spacers" between them, but that changes the chemical composition of the material. When graphene is crumpled into balls, however, its surface area remains available and the material remains pure.

"If you imagine a trash can filled with paper crumples, you really get the idea," says Jiaxing Huang, Morris E. Fine Junior Professor in Materials and Manufacturing, the lead researcher of the study. "The balls can stack up into a tight structure. You can crumple them as hard as you want, but their surface area won't be eliminated, unlike face-to-face stacking."

"Crumpled paper balls usually express an emotion of frustration, a quite common experience in research," Huang says, "However, here 'frustration' quite appropriately describes why these particles are resistant to aggregation -- because their uneven surface frustrates or prevents tight face-to-face packing no matter how you process them."

To make crumpled graphene balls, Huang and his team created freely suspended water droplets containing graphene-based sheets, then used a carrier gas to blow the aerosol droplets through a furnace. As the water quickly evaporated, the thin sheets were compressed by capillary force into near-spherical particles.

The resulting crumpled graphene particles have the same electrical properties as the flat sheets but are more useful for applications that require large amounts of the material. The ridges formed in the crumpling process render the particles a strain-hardening property; the harder you compress them, the stronger they become. Therefore, the crumpled graphene balls are remarkably stable against mechanical deformation, Huang said. "We expect this to serve as a new graphene platform to investigate application in energy storage and energy conversion," Huang said.

Other authors of the paper were Jiayan Luo, Hee Dong Jang, Tao Sun, Li Xiao, Zhen He, Alexandros P. Katsoulidis, Mercouri G. Kanatzidis, and J. Murray Gibson.

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The above story is reprinted (with editorial adaptations by ScienceDaily staff) from materials provided by Northwestern University.

Journal Reference:

Jiayan Luo, Hee Dong Jang, Tao Sun, Li Xiao, Zhen He, Alexandros P. Katsoulidis, Mercouri G. Kanatzidis, J. Murray Gibson, Jiaxing Huang. Compression and Aggregation-resistant Particles of Crumpled Soft Sheets. ACS Nano, 2011; 111013144955004 DOI: 10.1021/nn203115u

Note: If no author is given, the source is cited instead.

Disclaimer: Views expressed in this article do not necessarily reflect those of ScienceDaily or its staff.

View the original article here

Frustration inspires new form of graphene

ScienceDaily (Oct. 14, 2011) — They're the building block of graphite -- ultra-thin sheets of carbon, just one atom thick, whose discovery was lauded in 2010 with a Nobel Prize in Physics.

The seemingly simple material is graphene, and many researchers believe it has great potential for many applications, from electronic devices to high-performance composite materials. Graphene is extremely strong, an excellent conductor, and with no internal structure at all, it offers an abundance of surface area -- much like a sheet of paper.

When it comes to producing and utilizing graphene on a large scale, however, researchers have come upon a major problem: the material's tendency to aggregate. Like paper, graphene sheets easily stack into piles, significantly reducing their surface area and making them unprocessable.

Researchers at Northwestern University have now developed a new form of graphene that does not stack. The new material -- inspired by a trash can full of crumpled-up papers -- is made by crumpling the graphene sheets into balls.

A paper describing the findings was published Oct. 13 in the journal ACS Nano.

Graphene-based materials are very easily aggregated due to the strong interaction between the sheets, called "Van der Waals attraction." Therefore, common steps in materials processing, such as heating, solvent washing, compression, and mixing with other materials, can affect how the sheets are stacked. When the paper-like sheets band together -- picture a deck of cards -- their surface area is lost; with just a fraction of its original surface area available, the material becomes less effective. Stacked graphene sheets also become rigid and lose their processability.

Some scientists have tried to physically keep the sheets apart by inserting non-carbon "spacers" between them, but that changes the chemical composition of the material. When graphene is crumpled into balls, however, its surface area remains available and the material remains pure.

"If you imagine a trash can filled with paper crumples, you really get the idea," says Jiaxing Huang, Morris E. Fine Junior Professor in Materials and Manufacturing, the lead researcher of the study. "The balls can stack up into a tight structure. You can crumple them as hard as you want, but their surface area won't be eliminated, unlike face-to-face stacking."

"Crumpled paper balls usually express an emotion of frustration, a quite common experience in research," Huang says, "However, here 'frustration' quite appropriately describes why these particles are resistant to aggregation -- because their uneven surface frustrates or prevents tight face-to-face packing no matter how you process them."

To make crumpled graphene balls, Huang and his team created freely suspended water droplets containing graphene-based sheets, then used a carrier gas to blow the aerosol droplets through a furnace. As the water quickly evaporated, the thin sheets were compressed by capillary force into near-spherical particles.

The resulting crumpled graphene particles have the same electrical properties as the flat sheets but are more useful for applications that require large amounts of the material. The ridges formed in the crumpling process render the particles a strain-hardening property; the harder you compress them, the stronger they become. Therefore, the crumpled graphene balls are remarkably stable against mechanical deformation, Huang said. "We expect this to serve as a new graphene platform to investigate application in energy storage and energy conversion," Huang said.

Other authors of the paper were Jiayan Luo, Hee Dong Jang, Tao Sun, Li Xiao, Zhen He, Alexandros P. Katsoulidis, Mercouri G. Kanatzidis, and J. Murray Gibson.

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Story Source:

The above story is reprinted (with editorial adaptations by ScienceDaily staff) from materials provided by Northwestern University.

Journal Reference:

Jiayan Luo, Hee Dong Jang, Tao Sun, Li Xiao, Zhen He, Alexandros P. Katsoulidis, Mercouri G. Kanatzidis, J. Murray Gibson, Jiaxing Huang. Compression and Aggregation-resistant Particles of Crumpled Soft Sheets. ACS Nano, 2011; 111013144955004 DOI: 10.1021/nn203115u

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Disclaimer: Views expressed in this article do not necessarily reflect those of ScienceDaily or its staff.

View the original article here

Controlling silicon evaporation allows scientists to boost graphene quality

ScienceDaily (Sep. 22, 2011) — Scientists from the Georgia Institute of Technology have for the first time provided details of their "confinement controlled sublimation" technique for growing high-quality layers of epitaxial graphene on silicon carbide wafers. The technique relies on controlling the vapor pressure of gas-phase silicon in the high-temperature furnace used for fabricating the material.

The basic principle for growing thin layers of graphene on silicon carbide requires heating the material to about 1,500 degrees Celsius under high vacuum. The heat drives off the silicon, leaving behind one or more layers of graphene. But uncontrolled evaporation of silicon can produce poor quality material useless to designers of electronic devices.

"For growing high-quality graphene on silicon carbide, controlling the evaporation of silicon at just the right temperature is essential," said Walt de Heer, a professor who pioneered the technique in the Georgia Tech School of Physics. "By precisely controlling the rate at which silicon comes off the wafer, we can control the rate at which graphene is produced. That allows us to produce very nice layers of epitaxial graphene."

De Heer and his team begin by placing a silicon carbide wafer into an enclosure made of graphite. A small hole in the container controls the escape of silicon atoms as the one-square-centimeter wafer is heated, maintaining the rate of silicon evaporation and condensation near its thermal equilibrium. The growth of epitaxial graphene can be done in a vacuum or in the presence of an inert gas such as argon, and can be used to produce both single layers and multiple layers of the material.

"This technique seems to be completely in line with what people might one day do in fabrication facilities," de Heer said. "We believe this is quite significant in allowing us to rationally and reproducibly grow graphene on silicon carbide. We feel we now understand the process, and believe it could be scaled up for electronics manufacturing."

The technique for growing large-area layers of epitaxial graphene was described this week in the Early Edition of the journal Proceedings of the National Academy of Sciences. The research has been supported by the National Science Foundation through the Georgia Tech Materials Research Science and Engineering Center (MRSEC), the Air Force Office of Scientific Research, and the W.M. Keck Foundation.

The paper also describes a technique for growing narrow graphene ribbons, a process de Heer's group has called "templated growth." That technique, which could be useful for making graphene interconnects, was first described in October 2010 in the journal Nature Nanotechnology.

The templated growth technique involves etching patterns into silicon carbide surfaces using conventional nanolithography processes. The patterns serve as templates directing the growth of graphene structures on portions of the patterned surfaces. The technique forms nanoribbons of specific widths without the use of electron beams or other destructive cutting techniques. Graphene nanoribbons produced with these templates have smooth edges that avoid problems with electron scattering.

Together, the two techniques provide researchers with the flexibility to produce graphene in forms appropriate to different needs, de Heer noted. Large-area sheets of graphene may be grown on both the carbon-terminated and silicon-terminated sides of a silicon carbide wafer, while the narrow ribbons may be grown on the silicon-terminated side. Because of different processing techniques, only one side of a particular wafer can be used.

The Georgia Tech research team -- which includes Claire Berger, Ming Ruan, Mike Sprinkle, Xuebin Li, Yike Hu, Baiqian Zhang, John Hankinson and Edward Conrad -- has so far fabricated structures as narrow as 10 nanometers using the templated growth technique. These nanowires exhibit interesting quantum transport properties.

"We can make very good quantum wires using the templated growth technique," de Heer said. "We can make large structures and devices that demonstrate the Quantum Hall Effect, which is important for many applications. We have demonstrated that templated growth can go all the way down to the nanoscale, and that the properties get even better there."

Development of the sublimation technique arose from efforts to protect the growing graphene from oxygen and other contaminants in the furnace. To address the quality concerns, the research team tried enclosing the wafer in a graphite container from which some silicon gas was permitted to leak out.

"We soon realized that graphene grown in the container was much better than what we had been producing," de Heer recalled. "Originally, we thought it was because we were protecting it from contaminants. Later, we realized it was because we were controlling the evaporation of silicon."

Epitaxial graphene may be the basis for a new generation of high-performance devices that will take advantage of the material's unique properties in applications where higher costs can be justified. Silicon, today's electronic material of choice, will continue to be used in applications where high-performance is not required, de Heer said.

Though researchers are still struggling to design nanometer-scale epitaxial graphene devices that take advantage of the material's unique properties, de Heer is confident that will ultimately be done.

"These techniques allow us to make accurate nanostructures and seem to be very promising for making the nanoscale devices that we need," he said. "While there are serious challenges ahead for using graphene in electronics, we have overcome roadblocks before."

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Story Source:

The above story is reprinted (with editorial adaptations by ScienceDaily staff) from materials provided by Georgia Institute of Technology Research News. The original article was written by John Toon.

Note: If no author is given, the source is cited instead.

Disclaimer: Views expressed in this article do not necessarily reflect those of ScienceDaily or its staff.

View the original article here

Controlling silicon evaporation allows scientists to boost graphene quality

ScienceDaily (Sep. 22, 2011) — Scientists from the Georgia Institute of Technology have for the first time provided details of their "confinement controlled sublimation" technique for growing high-quality layers of epitaxial graphene on silicon carbide wafers. The technique relies on controlling the vapor pressure of gas-phase silicon in the high-temperature furnace used for fabricating the material.

The basic principle for growing thin layers of graphene on silicon carbide requires heating the material to about 1,500 degrees Celsius under high vacuum. The heat drives off the silicon, leaving behind one or more layers of graphene. But uncontrolled evaporation of silicon can produce poor quality material useless to designers of electronic devices.

"For growing high-quality graphene on silicon carbide, controlling the evaporation of silicon at just the right temperature is essential," said Walt de Heer, a professor who pioneered the technique in the Georgia Tech School of Physics. "By precisely controlling the rate at which silicon comes off the wafer, we can control the rate at which graphene is produced. That allows us to produce very nice layers of epitaxial graphene."

De Heer and his team begin by placing a silicon carbide wafer into an enclosure made of graphite. A small hole in the container controls the escape of silicon atoms as the one-square-centimeter wafer is heated, maintaining the rate of silicon evaporation and condensation near its thermal equilibrium. The growth of epitaxial graphene can be done in a vacuum or in the presence of an inert gas such as argon, and can be used to produce both single layers and multiple layers of the material.

"This technique seems to be completely in line with what people might one day do in fabrication facilities," de Heer said. "We believe this is quite significant in allowing us to rationally and reproducibly grow graphene on silicon carbide. We feel we now understand the process, and believe it could be scaled up for electronics manufacturing."

The technique for growing large-area layers of epitaxial graphene was described this week in the Early Edition of the journal Proceedings of the National Academy of Sciences. The research has been supported by the National Science Foundation through the Georgia Tech Materials Research Science and Engineering Center (MRSEC), the Air Force Office of Scientific Research, and the W.M. Keck Foundation.

The paper also describes a technique for growing narrow graphene ribbons, a process de Heer's group has called "templated growth." That technique, which could be useful for making graphene interconnects, was first described in October 2010 in the journal Nature Nanotechnology.

The templated growth technique involves etching patterns into silicon carbide surfaces using conventional nanolithography processes. The patterns serve as templates directing the growth of graphene structures on portions of the patterned surfaces. The technique forms nanoribbons of specific widths without the use of electron beams or other destructive cutting techniques. Graphene nanoribbons produced with these templates have smooth edges that avoid problems with electron scattering.

Together, the two techniques provide researchers with the flexibility to produce graphene in forms appropriate to different needs, de Heer noted. Large-area sheets of graphene may be grown on both the carbon-terminated and silicon-terminated sides of a silicon carbide wafer, while the narrow ribbons may be grown on the silicon-terminated side. Because of different processing techniques, only one side of a particular wafer can be used.

The Georgia Tech research team -- which includes Claire Berger, Ming Ruan, Mike Sprinkle, Xuebin Li, Yike Hu, Baiqian Zhang, John Hankinson and Edward Conrad -- has so far fabricated structures as narrow as 10 nanometers using the templated growth technique. These nanowires exhibit interesting quantum transport properties.

"We can make very good quantum wires using the templated growth technique," de Heer said. "We can make large structures and devices that demonstrate the Quantum Hall Effect, which is important for many applications. We have demonstrated that templated growth can go all the way down to the nanoscale, and that the properties get even better there."

Development of the sublimation technique arose from efforts to protect the growing graphene from oxygen and other contaminants in the furnace. To address the quality concerns, the research team tried enclosing the wafer in a graphite container from which some silicon gas was permitted to leak out.

"We soon realized that graphene grown in the container was much better than what we had been producing," de Heer recalled. "Originally, we thought it was because we were protecting it from contaminants. Later, we realized it was because we were controlling the evaporation of silicon."

Epitaxial graphene may be the basis for a new generation of high-performance devices that will take advantage of the material's unique properties in applications where higher costs can be justified. Silicon, today's electronic material of choice, will continue to be used in applications where high-performance is not required, de Heer said.

Though researchers are still struggling to design nanometer-scale epitaxial graphene devices that take advantage of the material's unique properties, de Heer is confident that will ultimately be done.

"These techniques allow us to make accurate nanostructures and seem to be very promising for making the nanoscale devices that we need," he said. "While there are serious challenges ahead for using graphene in electronics, we have overcome roadblocks before."

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Story Source:

The above story is reprinted (with editorial adaptations by ScienceDaily staff) from materials provided by Georgia Institute of Technology Research News. The original article was written by John Toon.

Note: If no author is given, the source is cited instead.

Disclaimer: Views expressed in this article do not necessarily reflect those of ScienceDaily or its staff.

View the original article here

Team reports scalable fabrication of self-aligned graphene transistors, circuits

ScienceDaily (June 16, 2011) — Graphene, a one-atom-thick layer of graphitic carbon, has the potential to make consumer electronic devices faster and smaller. But its unique properties, and the shrinking scale of electronics, also make graphene difficult to fabricate and to produce on a large scale.

In September 2010, a UCLA research team reported that they had overcome some of these difficulties and were able to fabricate graphene transistors with unparalleled speed. These transistors used a nanowire as the self-aligned gate -- the element that switches the transistor between various states. But the scalability of this approach remained an open question.

Now the researchers, using equipment from the Nanoelectronics Research Facility and the Center for High Frequency Electronics at UCLA, report that they have developed a scalable approach to fabricating these high-speed graphene transistors.

The team used a dielectrophoresis assembly approach to precisely place nanowire gate arrays on large-area chemical vapor deposition-growth graphene -- as opposed to mechanically peeled graphene flakes -- to enable the rational fabrication of high-speed transistor arrays. They were able to do this on a glass substrate, minimizing parasitic delay and enabling graphene transistors with extrinsic cut-off frequencies exceeding 50 GHz. Typical high-speed graphene transistors are fabricated on silicon or semi-insulating silicon carbide substrates that tend to bleed off electric charge, leading to extrinsic cut-off frequencies of around 10 GHz or less.

Taking an additional step, the UCLA team was able to use these graphene transistors to construct radio-frequency circuits functioning up to 10 GHz, a substantial improvement from previous reports of 20 MHz.

The research opens a rational pathway to scalable fabrication of high-speed, self-aligned graphene transistors and functional circuits and it demonstrates for the first time a graphene transistor with a practical (extrinsic) cutoff frequency beyond 50 GHz.

This represents a significant advance toward graphene-based, radio-frequency circuits that could be used in a variety of devices, including radios, computers and mobile phones. The technology might also be used in wireless communication, imaging and radar technologies.

The UCLA research team included Xiangfeng Duan, professor of chemistry and biochemistry; Yu Huang, assistant professor of materials science and engineering at the Henry Samueli School of Engineering and Applied Science; Lei Liao; Jingwei Bai; Rui Cheng; Hailong Zhou; Lixin Liu; and Yuan Liu.

Duan and Huang are also researchers at the California NanoSystems Institute at UCLA.

The work was funded by grants from National Science Foundation and the National Institutes of Health.

The research was recently published in the peer-reviewed journal Nano Letters.

Story Source:

The above story is reprinted (with editorial adaptations by ScienceDaily staff) from materials provided by University of California - Los Angeles. The original article was written by Mike Rodewald.

Journal Reference:

Lei Liao, Jingwei Bai, Rui Cheng, Hailong Zhou, Lixin Liu, Yuan Liu, Yu Huang, Xiangfeng Duan. Scalable fabrication of self-aligned graphene transistors and circuits on glass. Nano Letters, 2011; 110607115253088 DOI: 10.1021/nl201922c

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Disclaimer: Views expressed in this article do not necessarily reflect those of ScienceDaily or its staff.

View the original article here

Nanotechnology circuits for wireless devices: First wafer-scale graphene integrated circuit smaller than a pinhead

ScienceDaily (June 11, 2011) — IBM Research scientists have announced that they have achieved a milestone in creating a building block for the future of wireless devices. In a paper published in the journal Science, IBM researchers announced the first integrated circuit fabricated from wafer-size graphene, and demonstrated a broadband frequency mixer operating at frequencies up to 10 gigahertz (10 billion cycles/second).

Designed for wireless communications, this graphene-based analog integrated circuit could improve today's wireless devices and points to the potential for a new set of applications. At today's conventional frequencies, cell phone and transceiver signals could be improved, potentially allowing phones to work where they can't today while, at much higher frequencies, military and medical personnel could see concealed weapons or conduct medical imaging without the same radiation dangers of X-rays.

Graphene, the thinnest electronic material consisting of a single layer of carbon atoms packed in a honeycomb structure, possesses outstanding electrical, optical, mechanical and thermal properties that could make it less expensive and use less energy inside portable electronics like smart phones.

Despite significant scientific progress in the understanding of this novel material and the demonstration of high-performance graphene-based devices, the challenge of integrating graphene transistors with other components on a single chip had not been realized until now, mostly due to poor adhesion of graphene with metals and oxides and the lack of reliable fabrication schemes to yield reproducible devices and circuits.

This new integrated circuit, consisting of a graphene transistor and a pair of inductors compactly integrated on a silicon carbide (SiC) wafer, overcomes these design hurdles by developing wafer-scale fabrication procedures that maintain the quality of graphene and, at the same time, allow for its integration to other components in a complex circuitry.

How it Works

In this demonstration, graphene is synthesized by thermal annealing of SiC wafers to form uniform graphene layers on the surface of SiC. The fabrication of graphene circuits involves four layers of metal and two layers of oxide to form top-gated graphene transistor, on-chip inductors and interconnects.

The circuit operates as a broadband frequency mixer, which produces output signals with mixed frequencies (sum and difference) of the input signals. Mixers are fundamental components of many electronic communication systems. Frequency mixing up to 10 GHz and excellent thermal stability up to 125°C has been demonstrated with the graphene integrated circuit.

The fabrication scheme developed can also be applied to other types of graphene materials, including chemical vapor deposited (CVD) graphene films synthesized on metal films, and are also compatible with optical lithography for reduced cost and throughput.

Previously, the team has demonstrated standalone graphene transistors with a cut-off frequency as high as 100 GHz and 155 GHz for epitaxial and CVD graphene, for a gate length of 240 and 40 nm, respectively.

Story Source:

The above story is reprinted (with editorial adaptations by ScienceDaily staff) from materials provided by IBM Research.

Journal Reference:

Y.-M. Lin, A. Valdes-Garcia, S.-J. Han, D. B. Farmer, I. Meric, Y. Sun, Y. Wu, C. Dimitrakopoulos, A. Grill, P. Avouris, K. A. Jenkins. Wafer-Scale Graphene Integrated Circuit. Science, 2011; 332 (6035): 1294 DOI: 10.1126/science.1204428

Note: If no author is given, the source is cited instead.

Disclaimer: Views expressed in this article do not necessarily reflect those of ScienceDaily or its staff.

View the original article here

Graphene may gain an on-off switch, adding semiconductor to long list of material's achievements

ScienceDaily (June 17, 2011) — A team of researchers has proposed a way to turn the material graphene into a semiconductor, enabling it to control the flow of electrons with a laser "on-off switch."

Graphene is thinnest and strongest material ever discovered. It's a layer of carbon atoms only one-atom thick, but 200 times stronger than steel. It also conducts electricity extremely well and heat better than any other known material. It is almost completely transparent, yet so dense that not even atoms of helium can penetrate it. In spite of the impressive list of promising prospects, however, graphene appears to lack a critical property -- it doesn't have a "band gap."

A band gap is the basic property of semiconductors, enabling materials to control the flow of electrons. This on-off property is the foundation of computers, encoding the 0s and 1s of computer languages.

Now, a team of researchers at the National University of Córdoba and CONICET in Argentina; the Institut Catala de Nanotecnologia in Barcelona, Spain; and RWTH Aachen University, Germany; suggest that illuminating graphene with a mid-infrared laser could be a key to switch off conduction, thereby improving the possibilities for novel optoelectronic devices.

In an article featured in Applied Physics Letters, the researchers report on the first atomistic simulations of electrical conduction through a micrometer-sized graphene sample illuminated by a laser field. Their simulations show that a laser in the mid-infrared can open an observable band gap in this otherwise gapless material.

"Imagine that by turning on the light, graphene conduction is turned off, or vice versa. This would allow the transduction of optical into electrical signals," says Luis Foa Torres, the researcher leading this collaboration. "The problem of graphene interacting with radiation is also of current interest for the understanding of more exotic states of matter such as the topological insulators."

Story Source:

The above story is reprinted (with editorial adaptations by ScienceDaily staff) from materials provided by American Institute of Physics, via EurekAlert!, a service of AAAS.

Journal Reference:

Herna´n L. Calvo, Horacio M. Pastawski, Stephan Roche, Luis E. F. Foa Torres. Tuning laser-induced band gaps in graphene. Applied Physics Letters, 2011; 98 (23): 232103 DOI: 10.1063/1.3597412

Note: If no author is given, the source is cited instead.

Disclaimer: Views expressed in this article do not necessarily reflect those of ScienceDaily or its staff.

View the original article here

Nanotechnology circuits for wireless devices: First wafer-scale graphene integrated circuit smaller than a pinhead

ScienceDaily (June 11, 2011) — IBM Research scientists have announced that they have achieved a milestone in creating a building block for the future of wireless devices. In a paper published in the journal Science, IBM researchers announced the first integrated circuit fabricated from wafer-size graphene, and demonstrated a broadband frequency mixer operating at frequencies up to 10 gigahertz (10 billion cycles/second).

Designed for wireless communications, this graphene-based analog integrated circuit could improve today's wireless devices and points to the potential for a new set of applications. At today's conventional frequencies, cell phone and transceiver signals could be improved, potentially allowing phones to work where they can't today while, at much higher frequencies, military and medical personnel could see concealed weapons or conduct medical imaging without the same radiation dangers of X-rays.

Graphene, the thinnest electronic material consisting of a single layer of carbon atoms packed in a honeycomb structure, possesses outstanding electrical, optical, mechanical and thermal properties that could make it less expensive and use less energy inside portable electronics like smart phones.

Despite significant scientific progress in the understanding of this novel material and the demonstration of high-performance graphene-based devices, the challenge of integrating graphene transistors with other components on a single chip had not been realized until now, mostly due to poor adhesion of graphene with metals and oxides and the lack of reliable fabrication schemes to yield reproducible devices and circuits.

This new integrated circuit, consisting of a graphene transistor and a pair of inductors compactly integrated on a silicon carbide (SiC) wafer, overcomes these design hurdles by developing wafer-scale fabrication procedures that maintain the quality of graphene and, at the same time, allow for its integration to other components in a complex circuitry.

How it Works

In this demonstration, graphene is synthesized by thermal annealing of SiC wafers to form uniform graphene layers on the surface of SiC. The fabrication of graphene circuits involves four layers of metal and two layers of oxide to form top-gated graphene transistor, on-chip inductors and interconnects.

The circuit operates as a broadband frequency mixer, which produces output signals with mixed frequencies (sum and difference) of the input signals. Mixers are fundamental components of many electronic communication systems. Frequency mixing up to 10 GHz and excellent thermal stability up to 125°C has been demonstrated with the graphene integrated circuit.

The fabrication scheme developed can also be applied to other types of graphene materials, including chemical vapor deposited (CVD) graphene films synthesized on metal films, and are also compatible with optical lithography for reduced cost and throughput.

Previously, the team has demonstrated standalone graphene transistors with a cut-off frequency as high as 100 GHz and 155 GHz for epitaxial and CVD graphene, for a gate length of 240 and 40 nm, respectively.

Story Source:

The above story is reprinted (with editorial adaptations by ScienceDaily staff) from materials provided by IBM Research.

Journal Reference:

Y.-M. Lin, A. Valdes-Garcia, S.-J. Han, D. B. Farmer, I. Meric, Y. Sun, Y. Wu, C. Dimitrakopoulos, A. Grill, P. Avouris, K. A. Jenkins. Wafer-Scale Graphene Integrated Circuit. Science, 2011; 332 (6035): 1294 DOI: 10.1126/science.1204428

Note: If no author is given, the source is cited instead.

Disclaimer: Views expressed in this article do not necessarily reflect those of ScienceDaily or its staff.

View the original article here

Graphene may gain an on-off switch, adding semiconductor to long list of material's achievements

ScienceDaily (June 17, 2011) — A team of researchers has proposed a way to turn the material graphene into a semiconductor, enabling it to control the flow of electrons with a laser "on-off switch."

Graphene is thinnest and strongest material ever discovered. It's a layer of carbon atoms only one-atom thick, but 200 times stronger than steel. It also conducts electricity extremely well and heat better than any other known material. It is almost completely transparent, yet so dense that not even atoms of helium can penetrate it. In spite of the impressive list of promising prospects, however, graphene appears to lack a critical property -- it doesn't have a "band gap."

A band gap is the basic property of semiconductors, enabling materials to control the flow of electrons. This on-off property is the foundation of computers, encoding the 0s and 1s of computer languages.

Now, a team of researchers at the National University of Córdoba and CONICET in Argentina; the Institut Catala de Nanotecnologia in Barcelona, Spain; and RWTH Aachen University, Germany; suggest that illuminating graphene with a mid-infrared laser could be a key to switch off conduction, thereby improving the possibilities for novel optoelectronic devices.

In an article featured in Applied Physics Letters, the researchers report on the first atomistic simulations of electrical conduction through a micrometer-sized graphene sample illuminated by a laser field. Their simulations show that a laser in the mid-infrared can open an observable band gap in this otherwise gapless material.

"Imagine that by turning on the light, graphene conduction is turned off, or vice versa. This would allow the transduction of optical into electrical signals," says Luis Foa Torres, the researcher leading this collaboration. "The problem of graphene interacting with radiation is also of current interest for the understanding of more exotic states of matter such as the topological insulators."

Story Source:

The above story is reprinted (with editorial adaptations by ScienceDaily staff) from materials provided by American Institute of Physics, via EurekAlert!, a service of AAAS.

Journal Reference:

Herna´n L. Calvo, Horacio M. Pastawski, Stephan Roche, Luis E. F. Foa Torres. Tuning laser-induced band gaps in graphene. Applied Physics Letters, 2011; 98 (23): 232103 DOI: 10.1063/1.3597412

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