Astronomers Solve Mystery of Vanishing Electrons in Earth's Outer Radiation Belt

UCLA researchers have explained the puzzling disappearing act of energetic electrons in Earth's outer radiation belt, using data collected from a fleet of orbiting spacecraft. (Credit: NASA Goddard Space Flight Center / Image by Reto Stöckli /Enhancements by Robert Simmon)

UCLA researchers have explained the puzzling disappearing act of energetic electrons in Earth's outer radiation belt, using data collected from a fleet of orbiting spacecraft.

In a paper published Jan. 29 in the advance online edition of the journalNature Physics, the team shows that the missing electrons are swept away from the planet by a tide of solar wind particles during periods of heightened solar activity.

"This is an important milestone in understanding Earth's space environment," said lead study author Drew Turner, an assistant researcher in the UCLA Department of Earth and Space Sciences and a member of UCLA's Institute for Geophysics and Planetary Physics (IGPP). "We are one step closer towards understanding and predicting space weather phenomena."

During powerful solar events such as coronal mass ejections, parts of the magnetized outer layers of sun's atmosphere crash onto Earth's magnetic field, triggering geomagnetic storms capable of damaging the electronics of orbiting spacecraft. These cosmic squalls have a peculiar effect on Earth's outer radiation belt, a doughnut-shaped region of space filled with electrons so energetic that they move at nearly the speed of light.

"During the onset of a geomagnetic storm, nearly all the electrons trapped within the radiation belt vanish, only to come back with a vengeance a few hours later," said Vassilis Angelopoulos, a UCLA professor of Earth and space sciences and IGPP researcher.

The missing electrons surprised scientists when the trend was first measured in the 1960s by instruments onboard the earliest spacecraft sent into orbit, said study co-author Yuri Shprits, a research geophysicist with the IGPP and the departments of Earth and space sciences, and atmospheric and oceanic sciences.

"It's a puzzling effect," he said. "Oceans on Earth do not suddenly lose most of their water, yet radiation belts filled with electrons can be rapidly depopulated."

Even stranger, the electrons go missing during the peak of a geomagnetic storm, a time when one might expect the radiation belt to be filled with energetic particles because of the extreme bombardment by the solar wind.

Where do the electrons go? This question has remained unresolved since the early 1960s. Some believed the electrons were lost to Earth's atmosphere, while others hypothesized that the electrons were not permanently lost at all but merely temporarily drained of energy so that they appeared absent.

"Our study in 2006 suggested that electrons may be, in fact, lost to the interplanetary medium and decelerated by moving outwards," Shprits said. "However, until recently, there was no definitive proof for this theory."

To resolve the mystery, Turner and his team used data from three networks of orbiting spacecraft positioned at different distances from Earth to catch the escaping electrons in the act. The data show that while a small amount of the missing energetic electrons did fall into the atmosphere, the vast majority were pushed away from the planet, stripped away from the radiation belt by the onslaught of solar wind particles during the heightened solar activity that generated the magnetic storm itself.

A greater understanding of Earth's radiation belts is vital for protecting the satellites we rely on for global positioning, communications and weather monitoring, Turner said. Earth's outer radiation belt is a harsh radiation environment for spacecraft and astronauts; the high-energy electrons can penetrate a spacecraft's shielding and wreak havoc on its delicate electronics. Geomagnetic storms triggered when the oncoming particles smash into Earth's magnetosphere can cause partial or total spacecraft failure.

"While most satellites are designed with some level of radiation protection in mind, spacecraft engineers must rely on approximations and statistics because they lack the data needed to model and predict the behavior of high-energy electrons in the outer radiation belt," Turner said.

During the 2003 "Halloween Storm," more than 30 satellites reported malfunctions, and one was a total loss, said Angelopoulos, a co-author of the current research. As the solar maximum approaches in 2013, marking the sun's peak activity over a roughly 11-year cycle, geomagnetic storms may occur as often as several times per month.

"High-energy electrons can cut down the lifetime of a spacecraft significantly," Turner said. "Satellites that spend a prolonged period within the active radiation belt might stop functioning years early."

While a mechanized spacecraft might include multiple redundant circuits to reduce the risk of total failure during a solar event, human explorers in orbit do not have the same luxury. High-energy electrons can punch through astronauts' spacesuits and pose serious health risks, Turner said.

"As a society, we've become incredibly dependent on space-based technology," he said. "Understanding this population of energetic electrons and their extreme variations will help create more accurate models to predict the effect of geomagnetic storms on the radiation belts."

Key observational data used in this study was collected by a network of NASA spacecraft known as THEMIS (Time History of Events and Macroscale Interactions during Substorms); Angelopoulos is the principal investigator of the THEMIS mission. Additional information was obtained from two groups of weather satellites called POES (Polar Operational Environmental Satellite) and GOES (Geostationary Operational Environmental Satellite).

A new collaboration between UCLA and Russia's Moscow State University promises to paint an even clearer picture of these vanishing electrons. Slated for launch in the spring of 2012, the Lomonosov spacecraft will fly in low Earth orbit to measure highly energetic particles with unprecedented accuracy, said Shprits, the principal investigator of the project. Several key instruments for the mission are being developed and assembled at UCLA.

Earth's radiation belts were discovered in 1958 by Explorer I, the first U.S. satellite that traveled to space.

"What we are studying was the first discovery of the space age," Shprits said. "People realized that launches of spacecraft didn't only make the news, they could also make scientific discoveries that were completely unexpected."

This project received federal funding from NASA and the National Science Foundation. Other co-authors include Michael Hartinger, a UCLA graduate student in Earth and space sciences.

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The above story is reprinted from materials provided by University of California - Los Angeles. The original article was written by Kim DeRose.

Note: Materials may be edited for content and length. For further information, please contact the source cited above.

---

Journal Reference:

1. Drew L. Turner, Yuri Shprits, Michael Hartinger, Vassilis Angelopoulos. Explaining sudden losses of outer radiation belt electrons during geomagnetic storms.Nature Physics, 2012; DOI: 10.1038/nphys2185

New Material to Remove Radioactive Gas from Spent Nuclear Fuel

This illustration of a metal-organic framework, or MOF, shows the metal center bound to organic molecules. Each MOF has a specific framework determined by the choice of metal and organic. Sandia chemists identified a MOF whose pore size and high surface area can separate and trap radioactive iodine molecules from a stream of spent nuclear fuel. (Credit: Image courtesy of Sandia National Laboratories)

Science Daily  — Research by a team of Sandia chemists could impact worldwide efforts to produce clean, safe nuclear energy and reduce radioactive waste.

The discovery could be applied to nuclear fuel reprocessing or to clean up nuclear reactor accidents. A characteristic of nuclear energy is that used fuel can be reprocessed to recover fissile materials and provide fresh fuel for nuclear power plants. Countries such as France, Russia and India are reprocessing spent fuel.The Sandia researchers have used metal-organic frameworks (MOFs) to capture and remove volatile radioactive gas from spent nuclear fuel. "This is one of the first attempts to use a MOF for iodine capture," said chemist Tina Nenoff of Sandia's Surface and Interface Sciences Department.

The process also reduces the volume of high-level wastes, a key concern of the Sandia researchers. "The goal is to find a methodology for highly selective separations that result in less waste being interred," Nenoff said.

Part of the challenge of reprocessing is to separate and isolate radioactive components that can't be burned as fuel. The Sandia team focused on removing iodine, whose isotopes have a half-life of 16 million years, from spent fuel.

They studied known materials, including silver-loaded zeolite, a crystalline, porous mineral with regular pore openings, high surface area and high mechanical, thermal and chemical stability. Various zeolite frameworks can trap and remove iodine from a stream of spent nuclear fuel, but need added silver to work well.

"Silver attracts iodine to form silver iodide," Nenoff said. "The zeolite holds the silver in its pores and then reacts with iodine to trap silver iodide."

But silver is expensive and poses environmental problems, so the team set out to engineer materials without silver that would work like zeolites but have higher capacity for the gas molecules. They explored why and how zeolite absorbs iodine, and used the critical components discovered to find the best MOF, named ZIF-8.

"We investigated the structural properties on how they work and translated that into new and improved materials," Nenoff said.

MOFs are crystalline, porous materials in which a metal center is bound to organic molecules by mild self-assembly chemical synthesis. The choice of metal and organic result in a very specific final framework.

The trick was to find a MOF highly selective for iodine. The Sandia researchers took the best elements of the zeolite Mordenite -- its pores, high surface area, stability and chemical absorption -- and identified a MOF that can separate one molecule, in this case iodine, from a stream of molecules. The MOF and pore-trapped iodine gas can then be incorporated into glass waste for long-term storage.

The Sandia team also fabricated MOFs, made of commercially available products, into durable pellets. The as-made MOF is a white powder with a tendency to blow around. The pellets provide a stable form to use without loss of surface area, Nenoff said.

Sandia has applied for a patent on the pellet technology, which could have commercial applications.

The Sandia researchers are part of the Off-Gas Sigma Team, which is led by Oak Ridge National Laboratory and studies waste-form capture of volatile gasses associated with nuclear fuel reprocessing. Other team members -- Pacific Northwest, Argonne and Idaho national laboratories -- are studying other volatile gases such as krypton, tritium and carbon.

The project began six years ago and the Sigma Team was formalized in 2009. It is funded by the U.S. Department of Energy Office of Nuclear Energy.

Sandia's iodine and MOFs research was featured in two recent articles in the Journal of the American Chemical Societyauthored by Nenoff and team members Dorina Sava, Mark Rodriguez, Jeffery Greathouse, Paul Crozier, Terry Garino, David Rademacher, Ben Cipiti, Haiqing Liu, Greg Halder, Peter Chupas, and Karena Chapman. Chupas, Halder and Chapman are from Argonne.

"The most important thing we did was introduce a new class of materials to nuclear waste remediation," said Sava, postdoctoral appointee on the project.

Nenoff said another recent paper in Industrial & Engineering Chemistry Research shows a one-step process that incorporates MOFs with iodine in a low-temperature, glass waste form. "We have a volatile off-gas capture using a MOF and we have a durable waste form," Nenoff said.

Nenoff and her colleagues are continuing their research into new and optimized MOFs for enhanced volatile gas separation and capture.

"We've shown that MOFs have the capacity to capture and, more importantly, retain many times more iodine than current materials technologies," said Argonne's Chapman.

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The above story is reprinted from materials provided by DOE/Sandia National Laboratories, via News wise.

Note: Materials may be edited for content and length. For further information, please contact the source cited above.

---

Journal References:

1. Karena W. Chapman, Dorina F. Sava, Gregory J. Halder, Peter J. Chupas, Tina M. Nenoff. Trapping Guests within a Nanoporous Metal–Organic Framework through Pressure-Induced Amorphization. Journal of the American Chemical Society, 2011; 133 (46): 18583 DOI:10.1021/ja2085096
2. Dorina F. Sava, Mark A. Rodriguez, Karena W. Chapman, Peter J. Chupas, Jeffery A. Greathouse, Paul S. Crozier, Tina M. Nenoff. Capture of Volatile Iodine, a Gaseous Fission Product, by Zeolitic Imidazolate Framework-8.Journal of the American Chemical Society, 2011; 133 (32): 12398 DOI: 10.1021/ja204757x

Fundamental discovery casts enzymes in new light

ScienceDaily (Nov. 9, 2011) — A tree outside Oak Ridge National Laboratory researcher Pratul Agarwal's office window provided the inspiration for a discovery that may ultimately lead to drugs with fewer side effects, less expensive biofuels and more.

Just as a breeze causes leaves, branches and ultimately the tree to move, enzymes moving at the molecular level perform hundreds of chemical processes that have a ripple effect necessary for life. Previously, protein complexes were viewed as static entities with biological function understood in terms of direct interactions, but that isn't the case. This finding, recently published in PLoS Biology, may have enormous implications.

"Our discovery is allowing us to perhaps find the knobs that we can use to improve the catalytic rate of enzymes and perform a host of functions more efficiently," said Agarwal, a member of the Department of Energy laboratory's Computer Science and Mathematics Division.

Making this discovery possible was ORNL's supercomputer, Jaguar, which allowed Agarwal and co-author Arvind Ramanathan to investigate a large number of enzymes at the atomistic scale.

The researchers found that enzymes have similar features that are entirely preserved from the smallest living organism -- bacteria -- to complex life forms, including humans.

"If something is important for function, then it will be present in the protein performing the same function across different species," Agarwal said. "For example, regardless of which company makes a car, they all have wheels and brakes."

Similarly, scientists have known for decades that certain structural features of the enzyme are also preserved because of their important function. Agarwal and Ramanathan believe the same is true for enzyme flexibility.

"The importance of the structure of enzymes has been known for more than 100 years, but only recently have we started to understand that the internal motions may be the missing piece of the puzzle to understand how enzymes work," Agarwal said. "If we think of the tree as the model, the protein move at the molecular level with the side-chain and residues being the leaves and the protein backbone being the entire stem."

This research builds on previous work in which Agarwal identified a network of protein vibrations in the enzyme Cyclphilin A, which is involved in many biological reactions, including AIDS-causing HIV-1.

While Agarwal sees this research perhaps leading to medicines able to target hard to cure diseases such as AIDS, he is also excited about its energy applications, specifically in the area of cellulosic ethanol. Highly efficient enzymes could bring down the cost of biofuels, making them a more attractive option.

Funding for this research was provided by ORNL's Laboratory Directed Research and Development program. Ramanathan was a graduate student at Carnegie Mellon University when this work began and now also works at ORNL. The paper is titled "Evolutionarily conserved linkage between enzyme fold, flexibility and catalysis."

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Journal Reference:

Arvind Ramanathan, Pratul K. Agarwal. Evolutionarily Conserved Linkage between Enzyme Fold, Flexibility, and Catalysis. PLoS Biology, 2011; 9 (11): e1001193 DOI: 10.1371/journal.pbio.1001193

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Giant flakes make graphene oxide gel: Discovery could boost metamaterials, high-strength fibers

ScienceDaily (Oct. 20, 2011) — Giant flakes of graphene oxide in water aggregate like a stack of pancakes, but infinitely thinner, and in the process gain characteristics that materials scientists may find delicious.

A new paper by scientists at Rice University and the University of Colorado details how slices of graphene, the single-atom form of carbon, in a solution arrange themselves to form a nematic liquid crystal in which particles are free-floating but aligned.

That much was already known. The new twist is that if the flakes -- in this case, graphene oxide -- are big enough and concentrated enough, they retain their alignment as they form a gel. That gel is a handy precursor for manufacturing metamaterials or fibers with unique mechanical and electronic properties.

The team reported its discovery online this week in the Royal Society of Chemistry journal Soft Matter. Rice authors include Matteo Pasquali, a professor of chemical and biomolecular engineering and of chemistry; James Tour, the T.T. and W.F. Chao Chair in Chemistry as well as a professor of mechanical engineering and materials science and of computer science; postdoctoral research associate Dmitry Kosynkin; and graduate students Budhadipta Dan and Natnael Behabtu. Ivan Smalyukh, an assistant professor of physics at the University of Colorado at Boulder, led research for his group, in which Dan served as a visiting scientist.

"Graphene materials and fluid phases are a great research area," Pasquali said. "From the fundamental point of view, fluid phases comprising flakes are relatively unexplored, and certainly so when the flakes have important electronic properties.

"From the application standpoint, graphene and graphene oxide can be important building blocks in such areas as flexible electronics and conductive and high-strength materials, and can serve as templates for ordering plasmonic structures," he said.

By "giant," the researchers referred to irregular flakes of graphene oxide up to 10,000 times as wide as they are high. (That's still impossibly small: on average, roughly 12 microns wide and less than a nanometer high.) Previous studies showed smaller bits of pristine graphene suspended in acid would form a liquid crystal and that graphene oxide would do likewise in other solutions, including water.

This time the team discovered that if the flakes are big enough and concentrated enough, the solution becomes semisolid. When they constrained the gel to a thin pipette and evaporated some of the water, the graphene oxide flakes got closer to each other and stacked up spontaneously, although imperfectly.

"The exciting part for me is the spontaneous ordering of graphene oxide into a liquid crystal, which nobody had observed before," said Behabtu, a member of Pasquali's lab. "It's still a liquid, but it's ordered. That's useful to make fibers, but it could also induce order on other particles like nanorods."

He said it would be a simple matter to heat the concentrated gel and extrude it into something like carbon fiber, with enhanced properties provided by "mix-ins."

Testing the possibilities, the researchers mixed gold microtriangles and glass microrods into the solution, and found both were effectively forced to line up with the pancaking flakes. Their inclusion also helped the team get visual confirmation of the flakes' orientation.

The process offers the possibility of the large-scale ordering and alignment of such plasmonic particles as gold, silver and palladium nanorods, important components in optoelectronic devices and metamaterials, they reported.

Behabtu added that heating the gel "crosslinks the flakes, and that's good for mechanical strength. You can even heat graphene oxide enough to reduce it, stripping out the oxygen and turning it back into graphite."

Co-authors of the paper are Angel Martinez and Julian Evans, graduate students of Smalyukh at the University of Colorado at Boulder.

The Institute for Complex Adaptive Matter, the Colorado Renewable and Sustainable Energy Initiative, the National Science Foundation, the Air Force Research Lab, the Air Force Office of Scientific Research, the Welch Foundation, the U.S. Army Corps of Engineers Environmental Quality and Installation Program and M-I Swaco supported the research.

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Journal Reference:

Budhadipta Dan, Natnael Behabtu, Angel Martinez, Julian S. Evans, Dmitry V. Kosynkin, James M. Tour, Matteo Pasquali, Ivan I. Smalyukh. Liquid crystals of aqueous, giant graphene oxide flakes. Soft Matter, 2011; DOI: 10.1039/C1SM06418E

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Giant flakes make graphene oxide gel: Discovery could boost metamaterials, high-strength fibers

ScienceDaily (Oct. 20, 2011) — Giant flakes of graphene oxide in water aggregate like a stack of pancakes, but infinitely thinner, and in the process gain characteristics that materials scientists may find delicious.

A new paper by scientists at Rice University and the University of Colorado details how slices of graphene, the single-atom form of carbon, in a solution arrange themselves to form a nematic liquid crystal in which particles are free-floating but aligned.

That much was already known. The new twist is that if the flakes -- in this case, graphene oxide -- are big enough and concentrated enough, they retain their alignment as they form a gel. That gel is a handy precursor for manufacturing metamaterials or fibers with unique mechanical and electronic properties.

The team reported its discovery online this week in the Royal Society of Chemistry journal Soft Matter. Rice authors include Matteo Pasquali, a professor of chemical and biomolecular engineering and of chemistry; James Tour, the T.T. and W.F. Chao Chair in Chemistry as well as a professor of mechanical engineering and materials science and of computer science; postdoctoral research associate Dmitry Kosynkin; and graduate students Budhadipta Dan and Natnael Behabtu. Ivan Smalyukh, an assistant professor of physics at the University of Colorado at Boulder, led research for his group, in which Dan served as a visiting scientist.

"Graphene materials and fluid phases are a great research area," Pasquali said. "From the fundamental point of view, fluid phases comprising flakes are relatively unexplored, and certainly so when the flakes have important electronic properties.

"From the application standpoint, graphene and graphene oxide can be important building blocks in such areas as flexible electronics and conductive and high-strength materials, and can serve as templates for ordering plasmonic structures," he said.

By "giant," the researchers referred to irregular flakes of graphene oxide up to 10,000 times as wide as they are high. (That's still impossibly small: on average, roughly 12 microns wide and less than a nanometer high.) Previous studies showed smaller bits of pristine graphene suspended in acid would form a liquid crystal and that graphene oxide would do likewise in other solutions, including water.

This time the team discovered that if the flakes are big enough and concentrated enough, the solution becomes semisolid. When they constrained the gel to a thin pipette and evaporated some of the water, the graphene oxide flakes got closer to each other and stacked up spontaneously, although imperfectly.

"The exciting part for me is the spontaneous ordering of graphene oxide into a liquid crystal, which nobody had observed before," said Behabtu, a member of Pasquali's lab. "It's still a liquid, but it's ordered. That's useful to make fibers, but it could also induce order on other particles like nanorods."

He said it would be a simple matter to heat the concentrated gel and extrude it into something like carbon fiber, with enhanced properties provided by "mix-ins."

Testing the possibilities, the researchers mixed gold microtriangles and glass microrods into the solution, and found both were effectively forced to line up with the pancaking flakes. Their inclusion also helped the team get visual confirmation of the flakes' orientation.

The process offers the possibility of the large-scale ordering and alignment of such plasmonic particles as gold, silver and palladium nanorods, important components in optoelectronic devices and metamaterials, they reported.

Behabtu added that heating the gel "crosslinks the flakes, and that's good for mechanical strength. You can even heat graphene oxide enough to reduce it, stripping out the oxygen and turning it back into graphite."

Co-authors of the paper are Angel Martinez and Julian Evans, graduate students of Smalyukh at the University of Colorado at Boulder.

The Institute for Complex Adaptive Matter, the Colorado Renewable and Sustainable Energy Initiative, the National Science Foundation, the Air Force Research Lab, the Air Force Office of Scientific Research, the Welch Foundation, the U.S. Army Corps of Engineers Environmental Quality and Installation Program and M-I Swaco supported the research.

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Journal Reference:

Budhadipta Dan, Natnael Behabtu, Angel Martinez, Julian S. Evans, Dmitry V. Kosynkin, James M. Tour, Matteo Pasquali, Ivan I. Smalyukh. Liquid crystals of aqueous, giant graphene oxide flakes. Soft Matter, 2011; DOI: 10.1039/C1SM06418E

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Disclaimer: Views expressed in this article do not necessarily reflect those of ScienceDaily or its staff.

View the original article here

Catalyst discovery potential has to revolutionize chemical industry

ScienceDaily (Sep. 27, 2011) — University of Alberta Chemistry Professor Steve Bergens and his graduate student Jeremy Johns have discovered a catalyst that has the potential to revolutionise the chemical industry by reducing its environmental footprint, improving efficiency and minimizing risks.

Their findings were published in a top international chemistry journal Angewandte Chemie this month and provide the chemical industry with a potential solution to issues surrounding economics, efficiency and environmental factors.

"Our findings are a game changer that people having been seeking an answer to for decades," said Bergens.

Bergen said researchers have been working for more than 50 years to find a "clean" and stable catalyst that produces little to no waste and also has a capacity to provide multiple turnovers. In February of this year his student Jeremy Johns created such a catalyst in his laboratory.

"After years of producing disappointing results I was thrilled to see the results that came out of this particular experiment," said Dr Bergens.

"The chemical industry is making huge efforts to reduce its environmental footprint and their economists and accountants are also looking to reduce the cost of not just transporting catalyst but improving its efficiency," said Dr Bergens.

He said the February 2011 discovery opens numerous doors to make these things happen for industries ranging from pharmaceuticals to agrochemicals.

"Catalysts are notoriously unstable and challenging to transport, and the waste products the reactions to produce chemicals produce are equally challenging," Bergens added.

John's catalyst only produces hydrogen as a waste, something that is easy to burn off or react to produce water.

Bergens says early indications are the catalyst is not just safe but also efficient. The researchers have pushed the experiment to produce 7000 turnovers for one unit of catalyst.

"We are hugely excited , and the challenge now is to identify exactly how this catalyst is made up and how we can produce it in amounts to further advance this discovery," said Bergens.

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The above story is reprinted (with editorial adaptations by ScienceDaily staff) from materials provided by University of Alberta, via EurekAlert!, a service of AAAS.

Journal Reference:

Jeremy M. John, Steven H. Bergens. Catalyst for the Hydrogenation of Amides to Alcohols and Amines. Angewandte Chemie International Edition, 2011; DOI: 10.1002/anie.201105348

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Disclaimer: Views expressed in this article do not necessarily reflect those of ScienceDaily or its staff.

View the original article here

Catalyst discovery potential has to revolutionize chemical industry

ScienceDaily (Sep. 27, 2011) — University of Alberta Chemistry Professor Steve Bergens and his graduate student Jeremy Johns have discovered a catalyst that has the potential to revolutionise the chemical industry by reducing its environmental footprint, improving efficiency and minimizing risks.

Their findings were published in a top international chemistry journal Angewandte Chemie this month and provide the chemical industry with a potential solution to issues surrounding economics, efficiency and environmental factors.

"Our findings are a game changer that people having been seeking an answer to for decades," said Bergens.

Bergen said researchers have been working for more than 50 years to find a "clean" and stable catalyst that produces little to no waste and also has a capacity to provide multiple turnovers. In February of this year his student Jeremy Johns created such a catalyst in his laboratory.

"After years of producing disappointing results I was thrilled to see the results that came out of this particular experiment," said Dr Bergens.

"The chemical industry is making huge efforts to reduce its environmental footprint and their economists and accountants are also looking to reduce the cost of not just transporting catalyst but improving its efficiency," said Dr Bergens.

He said the February 2011 discovery opens numerous doors to make these things happen for industries ranging from pharmaceuticals to agrochemicals.

"Catalysts are notoriously unstable and challenging to transport, and the waste products the reactions to produce chemicals produce are equally challenging," Bergens added.

John's catalyst only produces hydrogen as a waste, something that is easy to burn off or react to produce water.

Bergens says early indications are the catalyst is not just safe but also efficient. The researchers have pushed the experiment to produce 7000 turnovers for one unit of catalyst.

"We are hugely excited , and the challenge now is to identify exactly how this catalyst is made up and how we can produce it in amounts to further advance this discovery," said Bergens.

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and Google +1:

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Story Source:

The above story is reprinted (with editorial adaptations by ScienceDaily staff) from materials provided by University of Alberta, via EurekAlert!, a service of AAAS.

Journal Reference:

Jeremy M. John, Steven H. Bergens. Catalyst for the Hydrogenation of Amides to Alcohols and Amines. Angewandte Chemie International Edition, 2011; DOI: 10.1002/anie.201105348

Note: If no author is given, the source is cited instead.

Disclaimer: Views expressed in this article do not necessarily reflect those of ScienceDaily or its staff.

View the original article here

Doppler effect found even at molecular level -- 169 years after its discovery

ScienceDaily (May 11, 2011) — Whether they know it or not, anyone who's ever gotten a speeding ticket after zooming by a radar gun has experienced the Doppler effect -- a measurable shift in the frequency of radiation based on the motion of an object, which in this case is your car doing 45 miles an hour in a 30-mph zone.

But for the first time, scientists have experimentally shown a different version of the Doppler effect at a much, much smaller level -- the rotation of an individual molecule. Prior to this such an effect had been theorized, but it took a complex experiment with a synchrotron to prove it's for real.

"Some of us thought of this some time ago, but it's very difficult to show experimentally," said T. Darrah Thomas, a professor emeritus of chemistry at Oregon State University and part of an international research team that just announced its findings in Physical Review Letters, a professional journal.

Most illustrations of the Doppler effect are called "translational," meaning the change in frequency of light or sound when one object moves away from the other in a straight line, like a car passing a radar gun. The basic concept has been understood since an Austrian physicist named Christian Doppler first proposed it in 1842.

But a similar effect can be observed when something rotates as well, scientists say.

"There is plenty of evidence of the rotational Doppler effect in large bodies, such as a spinning planet or galaxy," Thomas said. "When a planet rotates, the light coming from it shifts to higher frequency on the side spinning toward you and a lower frequency on the side spinning away from you. But this same basic force is at work even on the molecular level."

In astrophysics, this rotational Doppler effect has been used to determine the rotational velocity of things such as planets. But in the new study, scientists from Japan, Sweden, France and the United States provided the first experimental proof that the same thing happens even with molecules.

At this tiny level, they found, the rotational Doppler effect can be even more important than the linear motion of the molecules, the study showed.

The findings are expected to have application in a better understanding of molecular spectroscopy, in which the radiation emitted from molecules is used to study their makeup and chemical properties. It is also relevant to the study of high energy electrons, Thomas said.

"There are some studies where a better understanding of this rotational Doppler effect will be important," Thomas said. "Mostly it's just interesting. We've known about the Doppler effect for a very long time but until now have never been able to see the rotational Doppler effect in molecules."

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The above story is reprinted (with editorial adaptations by ScienceDaily staff) from materials provided by Oregon State University, via EurekAlert!, a service of AAAS.

Journal Reference:

T. D. Thomas, E. Kukk, K. Ueda, T. Ouchi, K. Sakai, T. X. Carroll, C. Nicolas, O. Travnikova, and C. Miron. Experimental observation of rotational Doppler broadening in a molecular system. Physical Review Letters, Accepted Apr 12, 2011

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Disclaimer: Views expressed in this article do not necessarily reflect those of ScienceDaily or its staff.

View the original article here

Doppler effect found even at molecular level -- 169 years after its discovery

ScienceDaily (May 11, 2011) — Whether they know it or not, anyone who's ever gotten a speeding ticket after zooming by a radar gun has experienced the Doppler effect -- a measurable shift in the frequency of radiation based on the motion of an object, which in this case is your car doing 45 miles an hour in a 30-mph zone.

But for the first time, scientists have experimentally shown a different version of the Doppler effect at a much, much smaller level -- the rotation of an individual molecule. Prior to this such an effect had been theorized, but it took a complex experiment with a synchrotron to prove it's for real.

"Some of us thought of this some time ago, but it's very difficult to show experimentally," said T. Darrah Thomas, a professor emeritus of chemistry at Oregon State University and part of an international research team that just announced its findings in Physical Review Letters, a professional journal.

Most illustrations of the Doppler effect are called "translational," meaning the change in frequency of light or sound when one object moves away from the other in a straight line, like a car passing a radar gun. The basic concept has been understood since an Austrian physicist named Christian Doppler first proposed it in 1842.

But a similar effect can be observed when something rotates as well, scientists say.

"There is plenty of evidence of the rotational Doppler effect in large bodies, such as a spinning planet or galaxy," Thomas said. "When a planet rotates, the light coming from it shifts to higher frequency on the side spinning toward you and a lower frequency on the side spinning away from you. But this same basic force is at work even on the molecular level."

In astrophysics, this rotational Doppler effect has been used to determine the rotational velocity of things such as planets. But in the new study, scientists from Japan, Sweden, France and the United States provided the first experimental proof that the same thing happens even with molecules.

At this tiny level, they found, the rotational Doppler effect can be even more important than the linear motion of the molecules, the study showed.

The findings are expected to have application in a better understanding of molecular spectroscopy, in which the radiation emitted from molecules is used to study their makeup and chemical properties. It is also relevant to the study of high energy electrons, Thomas said.

"There are some studies where a better understanding of this rotational Doppler effect will be important," Thomas said. "Mostly it's just interesting. We've known about the Doppler effect for a very long time but until now have never been able to see the rotational Doppler effect in molecules."

Story Source:

The above story is reprinted (with editorial adaptations by ScienceDaily staff) from materials provided by Oregon State University, via EurekAlert!, a service of AAAS.

Journal Reference:

T. D. Thomas, E. Kukk, K. Ueda, T. Ouchi, K. Sakai, T. X. Carroll, C. Nicolas, O. Travnikova, and C. Miron. Experimental observation of rotational Doppler broadening in a molecular system. Physical Review Letters, Accepted Apr 12, 2011

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