Microbubbles Provide New Boost for Biofuel Production

A solution to the difficult issue of harvesting algae for use as a biofuel has been developed using microbubble technology pioneered at the University of Sheffield. The technique builds on previous research in which microbubbles were used to improve the way algae is cultivated.

Algae produce an oil which can be processed to create a useful biofuel. Biofuels, made from plant material, are considered an important alternative to fossil fuels and algae, in particular, has the potential to be a very efficient biofuel producer. Until now, however, there has been no cost-effective crmethod of harvesting and removing the water from the algae for it to be processed effectively.

Now, a team led by Professor Will Zimmerman in the Department of Chemical and Biological Engineering at the University of Sheffield, believe they have solved the problem. They have developed an inexpensive way of producing microbubbles that can float algae particles to the surface of the water, making harvesting easier, and saving biofuel-producing companies time and money.

The research is set to be published in Biotechnology and Bioengineering on 26 January 2012.

Professor Zimmerman and his team won the Moulton Medal, from the Institute of Chemical Engineers, for their earlier work which used the microbubble technology to improve algae production methods, allowing producers to grow crops more rapidly and more densely.

"We thought we had solved the major barrier to biofuel companies processing algae to use as fuel when we used microbubbles to grow the algae more densely," explains Professor Zimmerman.

"It turned out, however, that algae biofuels still couldn´t be produced economically, because of the difficulty in harvesting and dewatering the algae. We had to develop a solution to this problem and once again, microbubbles provided a solution."

Microbubbles have been used for flotation before: water purification companies use the process to float out impurities, but it hasn´t been done in this context, partly because previous methods have been very expensive.

The system developed by Professor Zimmerman´s team uses up to 1000 times less energy to produce the microbubbles and, in addition, the cost of installing the Sheffield microbubble system is predicted to be much less than existing flotation systems.

The next step in the project is to develop a pilot plant to test the system at an industrial scale. Professor Zimmerman is already working with Tata Steel at their site in Scunthorpe using CO2 from their flue-gas stacks and plans to continue this partnership to test the new system.

Dr. Bruce Adderley, Manager Climate Change Breakthrough Technology, said, "Professor Zimmerman´s microbubble-based technologies are exactly the kind of step-change innovations that we are seeking as a means to address our emissions in the longer term, and we are delighted to have the opportunity to extend our relationship with Will and his team in the next phase of this pioneering research."

The research was supported by the University of Sheffield´s Knowledge Transfer Account, funded by the Engineering and Physical Sciences Research Council. It was also supported by the Royal Society Innovation Award 2010, and the Concept Fund of Yorkshire Forward

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Journal Reference:

1. James Hanotu, HC Hemaka Bandulasena, William B Zimmerman. Microflotation performance for algal separation. Biotechnology and Bioengineering, 2012; DOI:10.1002/bit.24449

New Material to Remove Radioactive Gas from Spent Nuclear Fuel

This illustration of a metal-organic framework, or MOF, shows the metal center bound to organic molecules. Each MOF has a specific framework determined by the choice of metal and organic. Sandia chemists identified a MOF whose pore size and high surface area can separate and trap radioactive iodine molecules from a stream of spent nuclear fuel. (Credit: Image courtesy of Sandia National Laboratories)

Science Daily  — Research by a team of Sandia chemists could impact worldwide efforts to produce clean, safe nuclear energy and reduce radioactive waste.

The discovery could be applied to nuclear fuel reprocessing or to clean up nuclear reactor accidents. A characteristic of nuclear energy is that used fuel can be reprocessed to recover fissile materials and provide fresh fuel for nuclear power plants. Countries such as France, Russia and India are reprocessing spent fuel.The Sandia researchers have used metal-organic frameworks (MOFs) to capture and remove volatile radioactive gas from spent nuclear fuel. "This is one of the first attempts to use a MOF for iodine capture," said chemist Tina Nenoff of Sandia's Surface and Interface Sciences Department.

The process also reduces the volume of high-level wastes, a key concern of the Sandia researchers. "The goal is to find a methodology for highly selective separations that result in less waste being interred," Nenoff said.

Part of the challenge of reprocessing is to separate and isolate radioactive components that can't be burned as fuel. The Sandia team focused on removing iodine, whose isotopes have a half-life of 16 million years, from spent fuel.

They studied known materials, including silver-loaded zeolite, a crystalline, porous mineral with regular pore openings, high surface area and high mechanical, thermal and chemical stability. Various zeolite frameworks can trap and remove iodine from a stream of spent nuclear fuel, but need added silver to work well.

"Silver attracts iodine to form silver iodide," Nenoff said. "The zeolite holds the silver in its pores and then reacts with iodine to trap silver iodide."

But silver is expensive and poses environmental problems, so the team set out to engineer materials without silver that would work like zeolites but have higher capacity for the gas molecules. They explored why and how zeolite absorbs iodine, and used the critical components discovered to find the best MOF, named ZIF-8.

"We investigated the structural properties on how they work and translated that into new and improved materials," Nenoff said.

MOFs are crystalline, porous materials in which a metal center is bound to organic molecules by mild self-assembly chemical synthesis. The choice of metal and organic result in a very specific final framework.

The trick was to find a MOF highly selective for iodine. The Sandia researchers took the best elements of the zeolite Mordenite -- its pores, high surface area, stability and chemical absorption -- and identified a MOF that can separate one molecule, in this case iodine, from a stream of molecules. The MOF and pore-trapped iodine gas can then be incorporated into glass waste for long-term storage.

The Sandia team also fabricated MOFs, made of commercially available products, into durable pellets. The as-made MOF is a white powder with a tendency to blow around. The pellets provide a stable form to use without loss of surface area, Nenoff said.

Sandia has applied for a patent on the pellet technology, which could have commercial applications.

The Sandia researchers are part of the Off-Gas Sigma Team, which is led by Oak Ridge National Laboratory and studies waste-form capture of volatile gasses associated with nuclear fuel reprocessing. Other team members -- Pacific Northwest, Argonne and Idaho national laboratories -- are studying other volatile gases such as krypton, tritium and carbon.

The project began six years ago and the Sigma Team was formalized in 2009. It is funded by the U.S. Department of Energy Office of Nuclear Energy.

Sandia's iodine and MOFs research was featured in two recent articles in the Journal of the American Chemical Societyauthored by Nenoff and team members Dorina Sava, Mark Rodriguez, Jeffery Greathouse, Paul Crozier, Terry Garino, David Rademacher, Ben Cipiti, Haiqing Liu, Greg Halder, Peter Chupas, and Karena Chapman. Chupas, Halder and Chapman are from Argonne.

"The most important thing we did was introduce a new class of materials to nuclear waste remediation," said Sava, postdoctoral appointee on the project.

Nenoff said another recent paper in Industrial & Engineering Chemistry Research shows a one-step process that incorporates MOFs with iodine in a low-temperature, glass waste form. "We have a volatile off-gas capture using a MOF and we have a durable waste form," Nenoff said.

Nenoff and her colleagues are continuing their research into new and optimized MOFs for enhanced volatile gas separation and capture.

"We've shown that MOFs have the capacity to capture and, more importantly, retain many times more iodine than current materials technologies," said Argonne's Chapman.

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The above story is reprinted from materials provided by DOE/Sandia National Laboratories, via News wise.

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Journal References:

1. Karena W. Chapman, Dorina F. Sava, Gregory J. Halder, Peter J. Chupas, Tina M. Nenoff. Trapping Guests within a Nanoporous Metal–Organic Framework through Pressure-Induced Amorphization. Journal of the American Chemical Society, 2011; 133 (46): 18583 DOI:10.1021/ja2085096
2. Dorina F. Sava, Mark A. Rodriguez, Karena W. Chapman, Peter J. Chupas, Jeffery A. Greathouse, Paul S. Crozier, Tina M. Nenoff. Capture of Volatile Iodine, a Gaseous Fission Product, by Zeolitic Imidazolate Framework-8.Journal of the American Chemical Society, 2011; 133 (32): 12398 DOI: 10.1021/ja204757x

Incredible shrinking material: Engineers reveal how scandium trifluoride contracts with heat

ScienceDaily (Nov. 7, 2011) — They shrink when you heat 'em. Most materials expand when heated, but a few contract. Now engineers at the California Institute of Technology (Caltech) have figured out how one of these curious materials, scandium trifluoride (ScF3), does the trick -- a finding, they say, that will lead to a deeper understanding of all kinds of materials.

The researchers, led by graduate student Chen Li, published their results in the November 4 issue of Physical Review Letters (PRL).

Materials that don't expand under heat aren't just an oddity. They're useful in a variety of applications -- in mechanical machines such as clocks, for example, that have to be extremely precise. Materials that contract could counteract the expansion of more conventional ones, helping devices remain stable even when the heat is on.

"When you heat a solid, most of the heat goes into the vibrations of the atoms," explains Brent Fultz, professor of materials science and applied physics and a coauthor of the paper. In normal materials, this vibration causes atoms to move apart and the material to expand. A few of the known shrinking materials, however, have unique crystal structures that cause them to contract when heated, a property called negative thermal expansion. But because these crystal structures are complicated, scientists have not been able to clearly see how heat -- in the form of atomic vibrations -- could lead to contraction.

But in 2010 researchers discovered negative thermal expansion in ScF3, a powdery substance with a relatively simple crystal structure. To figure out how its atoms vibrated under heat, Li, Fultz, and their colleagues used a computer to simulate each atom's quantum behavior. The team also probed the material's properties by blasting it with neutrons at the Spallation Neutron Source at Oak Ridge National Laboratory (ORNL) in Tennessee; by measuring the angles and speeds with which the neutrons scattered off the atoms in the crystal lattice, the team could study the atoms' vibrations. The more the material is heated the more it contracts, so by doing this scattering experiment at increasing temperatures, the team learned how the vibrations changed as the material shrank.

The results paint a clear picture of how the material shrinks, the researchers say. You can imagine the bound scandium and fluorine atoms as balls attached to one another with springs. The lighter fluorine atom is linked to two heavier scandium atoms on opposite sides. As the temperature is cranked up, all the atoms jiggle in many directions. But because of the linear arrangement of the fluorine and two scandiums, the fluorine vibrates more in directions perpendicular to the springs. With every shake, the fluorine pulls the scandium atoms toward each other. Since this happens throughout the material, the entire structure shrinks.

The surprise, the researchers say, was that in the large fluorine vibrations, the energy in the springs is proportional to the atom's displacement -- how far the atom moves while shaking -- raised to the fourth power, a behavior known as a quartic oscillation. Most materials are dominated by quadratic (or harmonic) oscillations -- characteristic of the typical back-and-forth motion of springs and pendulums -- in which the stored energy is proportional to the square of the displacement.

"A nearly pure quantum quartic oscillator has never been seen in atom vibrations in crystals," Fultz says. Many materials have a little bit of quartic behavior, he explains, but their quartic tendencies are pretty small. In the case of ScF3, however, the team observed the quartic behavior very clearly. "A pure quartic oscillator is a lot of fun," he says. "Now that we've found a case that's very pure, I think we know where to look for it in many other materials." Understanding quartic oscillator behavior will help engineers design materials with unusual thermal properties. "In my opinion," Fultz says, "that will be the biggest long-term impact of this work."

The other authors of the PRL paper, "The structural relationship between negative thermal expansion and quartic anharmonicity of cubic ScF3," are former Caltech postdoctoral scholars Xiaoli Tang and J. Brandon Keith; Caltech graduate students Jorge Muñoz and Sally Tracy; and Doug Abernathy of ORNL. The research was supported by the Department of Energy.

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NASA develops super-black material that absorbs light across multiple wavelength bands

ScienceDaily (Nov. 8, 2011) — NASA engineers have produced a material that absorbs on average more than 99 percent of the ultraviolet, visible, infrared, and far-infrared light that hits it -- a development that promises to open new frontiers in space technology.

The team of engineers at NASA's Goddard Space Flight Center in Greenbelt, Md., reported their findings recently at the SPIE Optics and Photonics conference, the largest interdisciplinary technical meeting in this discipline. The team has since reconfirmed the material's absorption capabilities in additional testing, said John Hagopian, who is leading the effort involving 10 Goddard technologists.

"The reflectance tests showed that our team had extended by 50 times the range of the material's absorption capabilities. Though other researchers are reporting near-perfect absorption levels mainly in the ultraviolet and visible, our material is darn near perfect across multiple wavelength bands, from the ultraviolet to the far infrared," Hagopian said. "No one else has achieved this milestone yet."

The nanotech-based coating is a thin layer of multi-walled carbon nanotubes, tiny hollow tubes made of pure carbon about 10,000 times thinner than a strand of human hair. They are positioned vertically on various substrate materials much like a shag rug. The team has grown the nanotubes on silicon, silicon nitride, titanium, and stainless steel, materials commonly used in space-based scientific instruments. (To grow carbon nanotubes, Goddard technologist Stephanie Getty applies a catalyst layer of iron to an underlayer on silicon, titanium, and other materials. She then heats the material in an oven to about 1,382 degrees Fahrenheit. While heating, the material is bathed in carbon-containing feedstock gas.)

The tests indicate that the nanotube material is especially useful for a variety of spaceflight applications where observing in multiple wavelength bands is important to scientific discovery. One such application is stray-light suppression. The tiny gaps between the tubes collect and trap background light to prevent it from reflecting off surfaces and interfering with the light that scientists actually want to measure. Because only a small fraction of light reflects off the coating, the human eye and sensitive detectors see the material as black.

In particular, the team found that the material absorbs 99.5 percent of the light in the ultraviolet and visible, dipping to 98 percent in the longer or far-infrared bands. "The advantage over other materials is that our material is from 10 to 100 times more absorbent, depending on the specific wavelength band," Hagopian said.

"We were a little surprised by the results," said Goddard engineer Manuel Quijada, who co-authored the SPIE paper and carried out the reflectance tests. "We knew it was absorbent. We just didn't think it would be this absorbent from the ultraviolet to the far infrared."

If used in detectors and other instrument components, the technology would allow scientists to gather hard-to-obtain measurements of objects so distant in the universe that astronomers no longer can see them in visible light or those in high-contrast areas, including planets in orbit around other stars, Hagopian said. Earth scientists studying the oceans and atmosphere also would benefit. More than 90 percent of the light Earth-monitoring instruments gather comes from the atmosphere, overwhelming the faint signal they are trying to retrieve.

Currently, instrument developers apply black paint to baffles and other components to help prevent stray light from ricocheting off surfaces. However, black paints absorb only 90 percent of the light that strikes it. The effect of multiple bounces makes the coating's overall advantage even larger, potentially resulting in hundreds of times less stray light.

In addition, black paints do not remain black when exposed to cryogenic temperatures. They take on a shiny, slightly silver quality, said Goddard scientist Ed Wollack, who is evaluating the carbon-nanotube material for use as a calibrator on far-infrared-sensing instruments that must operate in super-cold conditions to gather faint far-infrared signals emanating from objects in the very distant universe. If these instruments are not cold, thermal heat generated by the instrument and observatory, will swamp the faint infrared they are designed to collect.

Black materials also serve another important function on spacecraft instruments, particularly infrared-sensing instruments, added Goddard engineer Jim Tuttle. The blacker the material, the more heat it radiates away. In other words, super-black materials, like the carbon nanotube coating, can be used on devices that remove heat from instruments and radiate it away to deep space. This cools the instruments to lower temperatures, where they are more sensitive to faint signals.

To prevent the black paints from losing their absorption and radiative properties at long wavelengths, instrument developers currently use epoxies loaded with conductive metals to create a black coating. However, the mixture adds weight, always a concern for instrument developers. With the carbon-nanotube coating, however, the material is less dense and remains black without additives, and therefore is effective at absorbing light and removing heat. "This is a very promising material," Wollack said. "It's robust, lightweight, and extremely black. It is better than black paint by a long shot."

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Key property of potential 'spintronic' material measured

ScienceDaily (Oct. 19, 2011) — An advanced material that could help bring about next-generation "spintronic" computers has revealed one of its fundamental secrets to a team of scientists from Argonne National Laboratory (ANL) and the National Institute of Standards and Technology (NIST).

The material, constructed of two different compounds, might one day allow computers to use the magnetic spin of electrons, in addition to their charge, for computation. A host of innovations could result, including fast memory devices that use considerably less power than conventional systems and still retain data when the power is off. The team's effort not only demonstrates that the custom-made material's properties can be engineered precisely, but in creating a virtually perfect sample of the material, the team also has revealed a fundamental characteristic of devices that can be made from it.

Team members from ANL began by doing something that had never been done before -- engineering a highly ordered version of a magnetic oxide compound that naturally has two randomly distributed elements: lanthanum and strontium. Stronger magnetic properties are found in those places in the lattice where extra lanthanum atoms are added. Precise placement of the strontium and lanthanum within the lattice can enable understanding of what is needed to harness the interaction of the magnetic forces among the layers for memory storage applications, but such control has been elusive up to this point.

"These oxides are physically messy to work with, and until very recently, it was not possible to control the local atomic structure so precisely," says Brian Kirby, a physicist at the NIST Center for Neutron Research (NCNR). "Doing so gives us access to important fundamental properties, which are critical to understand if you really want to make optimal use of a material."

The team members from ANL have mastered a technique for laying down the oxides one atomic layer at a time, allowing them to construct an exceptionally organized lattice in which each layer contains only strontium or lanthanum, so that the interface between the two components could be studied. The NIST team members then used the NCNR's polarized neutron reflectometer to analyze how the magnetic properties within this oxide lattice changed as a consequence of the near-perfect placement of atoms.

They found that the influence of electrons near the additional lanthanum layers was spread out across three magnetic layers in either direction, but fell off sharply further away than that. Tiffany Santos, lead scientist on the study from ANL, says that the measurement will be important for the emerging field of oxide spintronics, as it reveals a fundamental size unit for electronic and magnetic effects in memory devices made from the material.

"For electrons to share spin information -- something required in a memory system -- they will need to be physically close enough to influence each other," Kirby says. "By ordering this material in such a precise way, we were able to see just how big that range of influence is."

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Journal Reference:

T. Santos, B. Kirby, S. Kumar, S. May, J. Borchers, B. Maranville, J. Zarestky, S. te Velthuis, J. van den Brink, A. Bhattacharya. Delta Doping of Ferromagnetism in Antiferromagnetic Manganite Superlattices. Physical Review Letters, 2011; 107 (16) DOI: 10.1103/PhysRevLett.107.167202

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Key property of potential 'spintronic' material measured

ScienceDaily (Oct. 19, 2011) — An advanced material that could help bring about next-generation "spintronic" computers has revealed one of its fundamental secrets to a team of scientists from Argonne National Laboratory (ANL) and the National Institute of Standards and Technology (NIST).

The material, constructed of two different compounds, might one day allow computers to use the magnetic spin of electrons, in addition to their charge, for computation. A host of innovations could result, including fast memory devices that use considerably less power than conventional systems and still retain data when the power is off. The team's effort not only demonstrates that the custom-made material's properties can be engineered precisely, but in creating a virtually perfect sample of the material, the team also has revealed a fundamental characteristic of devices that can be made from it.

Team members from ANL began by doing something that had never been done before -- engineering a highly ordered version of a magnetic oxide compound that naturally has two randomly distributed elements: lanthanum and strontium. Stronger magnetic properties are found in those places in the lattice where extra lanthanum atoms are added. Precise placement of the strontium and lanthanum within the lattice can enable understanding of what is needed to harness the interaction of the magnetic forces among the layers for memory storage applications, but such control has been elusive up to this point.

"These oxides are physically messy to work with, and until very recently, it was not possible to control the local atomic structure so precisely," says Brian Kirby, a physicist at the NIST Center for Neutron Research (NCNR). "Doing so gives us access to important fundamental properties, which are critical to understand if you really want to make optimal use of a material."

The team members from ANL have mastered a technique for laying down the oxides one atomic layer at a time, allowing them to construct an exceptionally organized lattice in which each layer contains only strontium or lanthanum, so that the interface between the two components could be studied. The NIST team members then used the NCNR's polarized neutron reflectometer to analyze how the magnetic properties within this oxide lattice changed as a consequence of the near-perfect placement of atoms.

They found that the influence of electrons near the additional lanthanum layers was spread out across three magnetic layers in either direction, but fell off sharply further away than that. Tiffany Santos, lead scientist on the study from ANL, says that the measurement will be important for the emerging field of oxide spintronics, as it reveals a fundamental size unit for electronic and magnetic effects in memory devices made from the material.

"For electrons to share spin information -- something required in a memory system -- they will need to be physically close enough to influence each other," Kirby says. "By ordering this material in such a precise way, we were able to see just how big that range of influence is."

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Journal Reference:

T. Santos, B. Kirby, S. Kumar, S. May, J. Borchers, B. Maranville, J. Zarestky, S. te Velthuis, J. van den Brink, A. Bhattacharya. Delta Doping of Ferromagnetism in Antiferromagnetic Manganite Superlattices. Physical Review Letters, 2011; 107 (16) DOI: 10.1103/PhysRevLett.107.167202

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Researchers discover material with graphene-like properties

ScienceDaily (Oct. 14, 2011) — After the Nobel Prize in Physics was awarded to two scientists in 2010 who had studied the material graphene, this substance has received a lot of attention. Together with colleagues from Korea, Dr. Frederik Wolff-Fabris from the Helmholtz-Zentrum Dresden-Rossendorf (HZDR) has now developed and analyzed a material which possesses physical properties similar to graphene. Its structure also resembles iron pnictides, i.e. high temperature superconductors, and it definitely has a promising future: Due to the position of the individual components in the Periodic Table of Elements, some of the atoms can simply be replaced by foreign atoms.

This creates new materials which can be superconductive, magnetic, or behave like topological insulators.

Earlier this year, Dr. Jun Sung Kim came from South Korea to use HZDR's Dresden High Magnetic Field Laboratory to analyze a number of material samples in high magnetic fields. For the first time ever, he and his colleague from Dresden, Dr. Frederik Wolff-Fabris, studied the metal SrMnBi2 and observed something amazing: The material consisting of the three elements strontium, manganese, and bismuth behaves physically similar to the "magical material" graphene.

Due to its composition and the position of its elements in the Periodic Table, SrMnBi2 permits simple and uncomplicated doping with foreign atoms. Inserting small amounts of foreign atoms alters the physical properties of a material. This might result in the creation of new magnets or superconductors.

SrMnBi2 is currently also in the focus of other research groups; but only the use of ultra-high magnetic fields, such as those generated in the Dresden High Magnetic Field Laboratory, permitted these precise results and, thus, a publication in the scientific journal Physical Review Letters. Later this year, Dr. Jun Sung Kim will return to Dresden to conduct additional experiments on SrMnBi2 with Dr. Wolff-Fabris.

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Journal Reference:

Joonbum Park, G. Lee, F. Wolff-Fabris, Y. Koh, M. Eom, Y. Kim, M. Farhan, Y. Jo, C. Kim, J. Shim, J. Kim. Anisotropic Dirac Fermions in a Bi Square Net of SrMnBi2. Physical Review Letters, 2011; 107 (12) DOI: 10.1103/PhysRevLett.107.126402

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New insights on an old material will enable design of better polymer batteries, water purification

ScienceDaily (June 19, 2011) — Designing new materials depends upon understanding the properties of today's materials. One such material, Nafion ©, is a polymer that efficiently conducts ions (a polymer electrolyte) and water through its nanostructure, making it important for many energy-related industrial applications, including in fuel cells, organic batteries, and reverse-osmosis water purification. But since Nafion was invented 50 years ago, scientists have only been able to speculate about how to build new materials because they have not been able to see details on how the molecules come together and work within Nafion.

Now, two Virginia Tech research groups have combined forces to devise a way to measure Nafion's internal structure and, in the process, have discovered how to manipulate this structure to enhance the material's applications.

The research is published in the June 19 issue of Nature Materials in the Letters article, "Linear coupling of alignment with transport in a polymer electrolyte membrane," by Jing Li, Jong Keun Park, Robert B. Moore, and Louis A. Madsen, all with the chemistry department in the College of Science and the Macromolecules and Interfaces Institute at Virginia Tech.

Nafion is made up of molecules that combine the non-stick and tough nature of Teflon with the conductive properties of an acid, such as battery acid. A network of tiny channels, nanometers in size, carries water or ions quickly through the polymer. "But, due to the irregular structure of Nafion, scientists have not been able to get reliable information about its properties using most standard analysis tools, such as transmission electron microscopy," said Madsen, assistant professor of physical, polymer, and materials chemistry.

Madsen and Moore, professor of physical and polymer chemistry; Madsen's post-doctoral associate Jing Li; and Moore's Ph.D. student Jong Keun Park, of Korea, were able to use nuclear magnetic resonance (NMR)to measure molecular motion, and a combination of NMR and X-ray scattering to measure molecular alignment within Nafion. "We were looking at water molecules inside Nafion as internal reporters of structure and efficiency of conduction," said Madsen. "The new feature we discovered is the locally aligned aggregates of polymer molecules in the material. The molecules align like strands of dry spaghetti lined up in a box. We can measure the speed (diffusion) of the water molecules and the direction they travel within those structures, which relates strongly to the alignment of the polymer molecule strands."

The researchers observed that the alignment of the channels influenced the speed and preferential direction of water motion. And a startlingly clear picture presented itself when the scientists stretched the Nafion and measured its structure and water motion.

"Stretching drastically influences the degree of alignment," said Madsen. "So the molecules move faster along the direction of the stretch, and in a very predictable way. These materials actually share some properties with liquid crystals -- molecules that line up with each other and are used in every LCD television, projector, and screen."

These relationships have not been previously recognized in a polymer electrolyte, Madsen said.

The ability to observe motion and direction, and understand what is happening within Nafion, has implications for using the material in new ways, and for designing new materials, the researchers write in the Nature Materials article. Ion-based applications could include actuator devices such as artificial muscles, organic batteries, and more energy efficient fuel cells. A water-based application would be improved reverse osmosis membranes for water purification.

Madsen and Moore started this collaborative project shortly after they arrived at Virginia Tech (Madsen in 2006, Moore in 2007), and they are furthering their work together by investigating new polymeric materials using their unique combination of analysis techniques.

"Alignment provides for a better flow of the molecules through the polymer," Madsen said.

The research is supported by Madsen's National Science Foundation Faculty Early Career Development (CAREER) Award. His research focuses on improving advanced polymers for fuel cells and reverse-osmosis water purification by combining detailed analysis of these materials with theoretical understanding. The research is also supported by the US Army Research Office under Ionic Liquids in Electro-Active Devices (ILEAD) Multidisciplinary University Research Initiative (MURI) grant.

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Journal Reference:

Jing Li, Jong Keun Park, Robert B. Moore and Louis A. Madsen. Linear coupling of alignment with transport in a polymer electrolyte membrane. Nature Materials, June 19 2011 DOI: 10.1038/NMAT3048

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Material turns hard or soft at the touch of a button

ScienceDaily (June 6, 2011) — A world premiere: a material which changes its strength, virtually at the touch of a button. This transformation can be achieved in a matter of seconds through changes in the electron structure of a material; thus hard and brittle matter, for example, can become soft and malleable. What makes this development revolutionary, is that the transformation can be controlled by electric signals.

This world-first has its origins in Hamburg. Jörg Weißmüller, a materials scientist at both the Technical University of Hamburg and the Helmholtz Center Geesthacht, has carried out research on this groundbreaking development, working in cooperation with colleagues from the Institute for Metal Research in Shenyang, China.

The 51-year-old researcher from the Saarland referred to his fundamental research, which opens the door to a multitude of diverse applications, as "a breakthrough in the material sciences." The new metallic high-performance material is described by Prof. Dr. Jörg Weißmüller and the Chinese research scientist Hai-Jun Jin in the latest issue of the scientific journal Science. Their research findings could, for example, make future intelligent materials with the ability of self healing, smoothing out flaws autonomously.

The firmness of a boiled egg can be adjusted at will through the cooking time. Some decisions are, however, irrevocable -- a hard-boiled egg can never be reconverted into a soft-boiled one. There would be less annoyance at the breakfast table if we could simply switch back and forth between the different degrees of firmness of the egg.

Similar issues arise in the making of structural materials such as metals and alloys. The materials properties are set once and for all during production. This forces engineers to make compromises in the selection of the mechanical properties of a material. Greater strength is inevitably accompanied by increased brittleness and a reduction of the damage tolerance.

Professor Weißmüller, head of the Institute of Materials Physics and Technology at the Technical University of Hamburg and also of the department for Hybrid Material Systems at the Helmholtz Center Geesthacht, stated: "This is a point where significant progress is being made. For the first time we have succeeded in producing a material which, while in service, can switch back and forth between a state of strong and brittle behavior and one of soft and malleable. We are still at the fundamental research stage but our discovery may bring significant progress in the development of so-called smart materials."

A Marriage of Metal and Water

In order to produce this innovative material, material scientists employ a comparatively simple process: corrosion. The metals, typically precious metals such as gold or platinum, are placed in an acidic solution. As a consequence of the onset of the corrosion process, minute ducts and holes are formed in the metal. The emerging nanostructured material is pervaded by a network of pore channels.

The pores are impregnated with a conductive liquid, for example a simple saline solution or a diluted acid, and a true hybrid material of metal and liquid is thus created. It is the unusual "marriage," as Weißmüller calls this union of metal and water which, when triggered by an electric signal, enables the properties of the material to change at the touch of a button.

As ions are dissolved in the liquid, the surfaces of the metal can be electrically charged. In other words, the mechanical properties of the metallic partner are changed by the application of an electric potential in the liquid partner. The effect can be traced back to a strengthening or weakening of the atomic bonding in the surface of the metal when extra electrons are added to or withdrawn from the surface atoms. The strength of the material can be as much as doubled when required. Alternatively, the material can be switched to a state which is weaker, but more damage tolerant, energy-absorbing and malleable.

Specific applications are still a matter for the future. However, researchers are already thinking ahead. In principle, the material can create electric signals spontaneously and selectively, so as to strengthen the matter in regions of local stress concentration. Damage, for instance in the form of cracks, could thereby be prevented or even healed. This has brought scientists a great step closer to their objective of 'intelligent' high performance materials.

Story Source:

The above story is reprinted (with editorial adaptations by ScienceDaily staff) from materials provided by Helmholtz Association of German Research Centres.

Journal Reference:

H.-J. Jin, J. Weissmuller. A Material with Electrically Tunable Strength and Flow Stress. Science, 2011; 332 (6034): 1179 DOI: 10.1126/science.1202190

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Novel artificial material could facilitate wireless power

ScienceDaily (May 24, 2011) — Electrical engineers at Duke University have determined that unique artificial materials should theoretically make it possible to improve the power transfer to small devices, such as laptops or cell phones, or ultimately to larger ones, such as cars or elevators, without wires.

This advance is made possible by the recent ability to fabricate exotic composite materials known as metamaterials, which are not so much a single substance, but an entire human-made structure that can be engineered to exhibit properties not readily found in nature. In fact, the metamaterial used in earlier Duke studies, and which would likely be used in future wireless power transmission systems, resembles a miniature set of tan Venetian blinds.

Theoretically, this metamaterial can improve the efficiency of "recharging" devices without wires. As power passes from the transmitting device to the receiving device, most if not all of it scatters and dissipates unless the two devices are extremely close together. However, the metamaterial postulated by the Duke researchers, which would be situated between the energy source and the "recipient" device, greatly refocuses the energy transmitted and permits the energy to traverse the open space between with minimal loss of power.

"We currently have the ability to transmit small amounts of power over short distances, such as in radio frequency identification (RFID) devices," said Yaroslav Urzhumov, assistant research professor in electrical and computer engineering at Duke's Pratt School of Engineering. "However, larger amounts of energy, such as that seen in lasers or microwaves, would burn up anything in its path.

"Based on our calculations, it should be possible to use these novel metamaterials to increase the amount of power transmitted without the negative effects," Urzhumov said.

The results of the Duke research were published online in the journal Physical Review B. Urzhumov works in the laboratory of David R. Smith, William Bevan Professor of electrical and computer engineering at Pratt School of Engineering. Smith's team was the first demonstrate that similar metamaterials could act as a cloaking device in 2006.

Just as the metamaterial in the cloaking device appeared to make a volume of space "disappear," in the latest work, the metamaterial would make it seem as if there was no space between the transmitter and the recipient, Urzhumov said. Therefore, he said, the loss of power should be minimal.

Urzhumov's research is an offshoot of "superlens" research conducted in Smith's laboratory. Traditional lenses get their focusing power by controlling rays as they pass through the two outside surfaces of the lens. On the other hand, the superlens, which is in fact a metamaterial, directs waves within the bulk of the lens between the outside surfaces, giving researchers a much greater control over whatever passes through it.

The metamaterial used in wireless power transmission would likely be made of hundreds to thousands -- depending on the application -- of individual thin conducting loops arranged into an array. Each piece is made from the same copper-on-fiberglass substrate used in printed circuit boards, with excess copper etched away. These pieces can then be arranged in an almost infinite variety of configurations.

"The system would need to be tailored to the specific recipient device, in essence the source and target would need to be 'tuned' to each other," Urzhumov said. "This new understanding of how matematerials can be fabricated and arranged should help make the design of wireless power transmission systems more focused."

The analysis performed at Duke was inspired by recent studies at Mitsubishi Electric Research Labs (MERL), an industrial partner of the Duke Center for Metamaterials and Integrated Plasmonics. MERL is currently investigating metamaterials for wireless power transfer. The Duke researchers said that with these new insights into the effects of metamaterials, developing actual devices can be more targeted and efficient.

The Duke University research was supported by a Multidisciplinary University Research Initiative (MURI) grant through the Air Force Office of Scientific Research and the U.S. Army Research Office.

Story Source:

The above story is reprinted (with editorial adaptations by ScienceDaily staff) from materials provided by Duke University, via EurekAlert!, a service of AAAS.

Journal Reference:

Yaroslav Urzhumov, David Smith. Metamaterial-enhanced coupling between magnetic dipoles for efficient wireless power transfer. Physical Review B, 2011; 83 (20) DOI: 10.1103/PhysRevB.83.205114

Note: If no author is given, the source is cited instead.

Disclaimer: Views expressed in this article do not necessarily reflect those of ScienceDaily or its staff.

View the original article here

Novel artificial material could facilitate wireless power

ScienceDaily (May 24, 2011) — Electrical engineers at Duke University have determined that unique artificial materials should theoretically make it possible to improve the power transfer to small devices, such as laptops or cell phones, or ultimately to larger ones, such as cars or elevators, without wires.

This advance is made possible by the recent ability to fabricate exotic composite materials known as metamaterials, which are not so much a single substance, but an entire human-made structure that can be engineered to exhibit properties not readily found in nature. In fact, the metamaterial used in earlier Duke studies, and which would likely be used in future wireless power transmission systems, resembles a miniature set of tan Venetian blinds.

Theoretically, this metamaterial can improve the efficiency of "recharging" devices without wires. As power passes from the transmitting device to the receiving device, most if not all of it scatters and dissipates unless the two devices are extremely close together. However, the metamaterial postulated by the Duke researchers, which would be situated between the energy source and the "recipient" device, greatly refocuses the energy transmitted and permits the energy to traverse the open space between with minimal loss of power.

"We currently have the ability to transmit small amounts of power over short distances, such as in radio frequency identification (RFID) devices," said Yaroslav Urzhumov, assistant research professor in electrical and computer engineering at Duke's Pratt School of Engineering. "However, larger amounts of energy, such as that seen in lasers or microwaves, would burn up anything in its path.

"Based on our calculations, it should be possible to use these novel metamaterials to increase the amount of power transmitted without the negative effects," Urzhumov said.

The results of the Duke research were published online in the journal Physical Review B. Urzhumov works in the laboratory of David R. Smith, William Bevan Professor of electrical and computer engineering at Pratt School of Engineering. Smith's team was the first demonstrate that similar metamaterials could act as a cloaking device in 2006.

Just as the metamaterial in the cloaking device appeared to make a volume of space "disappear," in the latest work, the metamaterial would make it seem as if there was no space between the transmitter and the recipient, Urzhumov said. Therefore, he said, the loss of power should be minimal.

Urzhumov's research is an offshoot of "superlens" research conducted in Smith's laboratory. Traditional lenses get their focusing power by controlling rays as they pass through the two outside surfaces of the lens. On the other hand, the superlens, which is in fact a metamaterial, directs waves within the bulk of the lens between the outside surfaces, giving researchers a much greater control over whatever passes through it.

The metamaterial used in wireless power transmission would likely be made of hundreds to thousands -- depending on the application -- of individual thin conducting loops arranged into an array. Each piece is made from the same copper-on-fiberglass substrate used in printed circuit boards, with excess copper etched away. These pieces can then be arranged in an almost infinite variety of configurations.

"The system would need to be tailored to the specific recipient device, in essence the source and target would need to be 'tuned' to each other," Urzhumov said. "This new understanding of how matematerials can be fabricated and arranged should help make the design of wireless power transmission systems more focused."

The analysis performed at Duke was inspired by recent studies at Mitsubishi Electric Research Labs (MERL), an industrial partner of the Duke Center for Metamaterials and Integrated Plasmonics. MERL is currently investigating metamaterials for wireless power transfer. The Duke researchers said that with these new insights into the effects of metamaterials, developing actual devices can be more targeted and efficient.

The Duke University research was supported by a Multidisciplinary University Research Initiative (MURI) grant through the Air Force Office of Scientific Research and the U.S. Army Research Office.

Story Source:

The above story is reprinted (with editorial adaptations by ScienceDaily staff) from materials provided by Duke University, via EurekAlert!, a service of AAAS.

Journal Reference:

Yaroslav Urzhumov, David Smith. Metamaterial-enhanced coupling between magnetic dipoles for efficient wireless power transfer. Physical Review B, 2011; 83 (20) DOI: 10.1103/PhysRevB.83.205114

Note: If no author is given, the source is cited instead.

Disclaimer: Views expressed in this article do not necessarily reflect those of ScienceDaily or its staff.

View the original article here

New material could improve safety for first responders to chemical hazards

ScienceDaily (May 2, 2011) — A new kind of sensor could warn emergency workers when carbon filters in the respirators they wear to avoid inhaling toxic fumes have become dangerously saturated.

In a recent issue of the journal Advanced Materials, a team of researchers from the University of California, San Diego and Tyco Electronics describe how they made the carbon nanostructures and demonstrate their potential use as microsensors for volatile organic compounds.

First responders protect themselves from such vapors, whose composition is often unknown, by breathing through a canister filled with activated charcoal -- a gas mask. Airborne toxins stick to the carbon in the filter, trapping the dangerous materials.

As the filters become saturated, chemicals will begin to pass through. The respirator can then do more harm than good by providing an illusion of safety. But there is no easy way to determine when the filter is spent. Current safety protocols base the timing of filter changes on how long the user has worn the mask.

"The new sensors would provide a more accurate reading of how much material the carbon in the filters has actually absorbed," said team leader Michael Sailor, professor of chemistry and biochemistry and bioengineering at UC San Diego. "Because these carbon nanofibers have the same chemical properties as the activated charcoal used in respirators, they have a similar ability to absorb organic pollutants."

Sailor's team assembled the nanofibers into repeating structures called photonic crystals that reflect specific wavelengths, or colors, of light. The wing scales of the Morpho butterfly, which give the insect its brilliant iridescent coloration, are natural examples of this kind of structure.

The sensors are an iridescent color too, rather than black like ordinary carbon. That color changes when the fibers absorb toxins -- a visible indication of their capacity for absorbing additional chemicals.

The agency that certifies respirators in the U.S., the National Institute of Occupational Safety and Health, has long sought such a sensor but the design requirements for a tiny, sensitive, inexpensive device that requires little power, have proved difficult to meet.

The materials that the team fabricated are very thin -- less than half the width of a human hair. Sailor's group has previously placed similar photonic sensors on the tips of optical fibers less than a millimeter across and shown that they can be inserted into respirator cartridges. And the crystals are sensitive enough to detect chemicals such as toluene at concentrations as low as one part per million.

Ting Gao, a senior researcher at the Polymers, Ceramics, and Technical Services Laboratories of Tyco Electronics in Menlo Park, California and Timothy L. Kelly, a NSERC post-doctoral fellow at UC San Diego co-authored the paper. The National Science Foundation, the Department of Homeland Security, the Natural Sciences and Engineering Research Council of Canada, and TYCO Electronics provided funding for the work.

Story Source:

The above story is reprinted (with editorial adaptations by ScienceDaily staff) from materials provided by University of California - San Diego. The original article was written by Susan Brown.

Journal Reference:

Timothy L. Kelly, Ting Gao, Michael J. Sailor. Carbon Nanofiber Photonic Crystals: Carbon and Carbon/Silicon Composites Templated in Rugate Filters for the Adsorption and Detection of Organic Vapors (Adv. Mater. 15/2011). Advanced Materials, 2011; 23 (15): 1688 DOI: 10.1002/adma.201190052

Note: If no author is given, the source is cited instead.

Disclaimer: Views expressed in this article do not necessarily reflect those of ScienceDaily or its staff.

View the original article here