Scorpions Inspire Scientists in Making Tougher Surfaces for Machinery

Yellow fattail scorpion (Androctonus australis). 
(Credit: © Fyle / Fotolia)

Taking inspiration from the yellow fattail scorpion, which uses a bionic shield to protect itself against scratches from desert sandstorms, scientists have developed a new way to protect the moving parts of machinery from wear and tear.

A report on the research appears in ACS' journal Langmuir.

Zhiwu Han, Junqiu Zhang, Wen Li and colleagues explain that "solid particle erosion" is one of the important reasons for material damage or equipment failure. It causes millions of dollars of damage each year to helicopter rotors, rocket motor nozzles, turbine blades, pipes and other mechanical parts. The damage occurs when particles of dirt, grit and other hard material in the air, water or other fluids strike the surfaces of those parts. Filters can help remove the particles but must be replaced or cleaned, while harder, erosion-resistant materials cost more to develop and make. In an effort to develop better erosion-resistant surfaces, Han and Li's group sought the secrets of the yellow fattail scorpion for the first time. The scorpion evolved to survive the abrasive power of harsh sandstorms.

They studied the bumps and grooves on the scorpions' backs, scanning the creatures with a 3-D laser device and developing a computer program that modeled the flow of sand-laden air over the scorpions. The team used the model in computer simulations to develop actual patterned surfaces to test which patterns perform best. At the same time, the erosion tests were conducted in the simple erosion wind tunnel for groove surface bionic samples at various impact conditions. Their results showed that a series of small grooves at a 30-degree angle to the flowing gas or liquid give steel surfaces the best protection from erosion.

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Journal Reference:

1. Han Zhiwu, Zhang Junqiu, Ge Chao, Wen Li, Luquan Ren.Erosion Resistance of Bionic Functional Surfaces Inspired from Desert Scorpions. Langmuir, 2012; 120120101148000 DOI: 10.1021/la203942r

Scientists Create First Atomic X-Ray Laser

A powerful X-ray laser pulse from SLAC National Accelerator Laboratory's Linac Coherent Light Source comes up from the lower-left corner (shown as green) and hits a neon atom (center). This intense incoming light energizes an electron from an inner orbit (or shell) closest to the neon nucleus (center, brown), knocking it totally out of the atom (upper-left, foreground). In some cases, an outer electron will drop down into the vacated inner orbit (orange starburst near the nucleus) and release a short-wavelength, high-energy (i.e. "hard") X-ray photon of a specific wavelength (energy/color) (shown as yellow light heading out from the atom to the upper right along with the larger, green LCLS light). (Credit: Illustration by Gregory M. Stewart, SLAC National Accelerator Laboratory)

Scientists working at the U.S. Department of Energy's (DOE) SLAC National Accelerator Laboratory have created the shortest, purest X-ray laser pulses ever achieved, fulfilling a 45-year-old prediction and opening the door to a new range of scientific discovery.

The researchers, reporting in Nature, aimed SLAC's Linac Coherent Light Source (LCLS) at a capsule of neon gas, setting off an avalanche of X-ray emissions to create the world's first "atomic X-ray laser."

"X-rays give us a penetrating view into the world of atoms and molecules," said physicist Nina Rohringer, who led the research. A group leader at the Max Planck Society's Advanced Study Group in Hamburg, Germany, Rohringer collaborated with researchers from SLAC, DOE's Lawrence Livermore National Laboratory and Colorado State University.

"We envision researchers using this new type of laser for all sorts of interesting things, such as teasing out the details of chemical reactions or watching biological molecules at work," she added. "The shorter the pulses, the faster the changes we can capture. And the purer the light, the sharper the details we can see."

The new atomic X-ray laser fulfills a 1967 prediction that X-ray lasers could be made in the same manner as many visible-light lasers -- by inducing electrons to fall from higher to lower energy levels within atoms, releasing a single color of light in the process. But until 2009, when LCLS turned on, no X-ray source was powerful enough to create this type of laser.

To make the atom laser, LCLS's powerful X-ray pulses -- each a billion times brighter than any available before -- knocked electrons out of the inner shells of many of the neon atoms in the capsule. When other electrons fell in to fill the holes, about one in 50 atoms responded by emitting a photon in the X-ray range, which has a very short wavelength. Those X-rays then stimulated neighboring neon atoms to emit more X-rays, creating a domino effect that amplified the laser light 200 million times.

Although LCLS and the neon capsule are both lasers, they create light in different ways and emit light with different attributes. The LCLS passes high-energy electrons through alternating magnetic fields to trigger production of X-rays; its X-ray pulses are brighter and much more powerful. The atomic laser's pulses are only one-eighth as long and their color is much more pure, qualities that will enable it to illuminate and distinguish details of ultrafast reactions that had been impossible to see before.

"This achievement opens the door for a new realm of X-ray capabilities," said John Bozek, LCLS instrument scientist. "Scientists will surely want new facilities to take advantage of this new type of laser."

For example, researchers envision using both LCLS and atomic laser pulses in a synchronized one-two punch: The first laser triggers a change in a sample under study, and the second records with atomic-scale precision any changes that occurred within a few quadrillionths of a second.

In future experiments, Rohringer says she will try to create even shorter-pulsed, higher-energy atomic X-ray lasers using oxygen, nitrogen or sulfur gas.

Additional authors included Richard London, Felicie Albert, James Dunn, Randal Hill and Stefan P. Hau-Riege from Lawrence Livermore National Laboratory (LLNL); Duncan Ryan, Michael Purvis and Jorge J. Rocca from Colorado State University; and Christoph Bostedt from SLAC.

The work was supported by Lawrence Livermore National Laboratory's Laboratory Directed Research and Development Program. Authors Roca, Purvis and Ryan were supported by the DOE Office of Science. LCLS is a national scientific user facility operated by SLAC and supported by DOE's Office of Science.

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Journal Reference:

1. Nina Rohringer, Duncan Ryan, Richard A. London, Michael Purvis, Felicie Albert, James Dunn, John D. Bozek, Christoph Bostedt, Alexander Graf, Randal Hill, Stefan P. Hau-Riege, Jorge J. Rocca. Atomic inner-shell X-ray laser at 1.46 nanometres pumped by an X-ray free-electron laser. Nature, 2012; 481 (7382): 488 DOI:10.1038/nature10721

Scientists Produce World's First Magnetic Soap

The liquid crystal progression of each surfactant was investigated by the solvent penetration method (i.e. phase cut). A small amount of surfactant was placed on a microscope slide under a coverslip. The slide was mounted on the cover slide and heated until the sample was fluid and completely isotropic. After slow cooling (1.0 °C min-1) to 25 °C, a drop of water was added to the edge of the coverslip. As the water penetrated the surfactant, a concentration gradient was established, from water at one side to pure surfactant at the other, enabling the entire range of mesophases to be observed in the field of view. (Credit: Image courtesy of Institut Laue-Langevin (ILL))


ScienceDaily (Jan. 23, 2012) — Scientists from Bristol University have developed a soap, composed of iron rich salts dissolved in water, that responds to a magnetic field when placed in solution. The soap’s magnetic properties were shown with neutrons at the Institut Laue-Langevin to result from tiny iron-rich clumps that sit within the watery solution. The generation of this property in a fully functional soap could calm concerns over the use of soaps in oil-spill clean ups and revolutionise industrial cleaning products.


Scientists have long been searching for a way to control soaps (or surfactants as they are known in industry) once they are in solution to increase their ability to dissolve oils in water and then remove them from a system. The team at Bristol University have previously worked on soaps sensitive to light, carbon dioxide or changes in pH, temperature or pressure. Their latest breakthrough, reported inAngewandte Chemie, is the world’s first soap sensitive to a magnetic field.

Ionic liquid surfactants, composed mostly of water with some transition metal complexes (heavy metals like iron bound to halides such as bromine or chlorine) have been suggested as potentially controllable by magnets for some time, but it had always been assumed that their metallic centres were too isolated within the solution, preventing the long-range interactions required to be magnetically active.

The team at Bristol, lead by Professor Julian Eastoe produced their magnetic soap by dissolving iron in a range of inert surfactant materials composed of chloride and bromide ions, very similar to those found in everyday mouthwash or fabric conditioner. The addition of the iron creates metallic centres within the soap particles.

To test its properties, the team introduced a magnet to a test tube containing their new soap lying beneath a less dense organic solution. When the magnet was introduced the iron-rich soap overcame both gravity and surface tension between the water and oil, to levitate through the organic solvent and reach the source of the magnetic energy, proving its magnetic properties.

Once the surfactant was developed and shown to be magnetic, Prof Eastoe’s team took it to the Institut Laue-Langevin, the world’s flagship centre for neutron science, and home to the world’s most intense neutron source, to investigate the science behind its remarkable property.

When surfactants are added to water they are known to form tiny clumps (particles called micelles). Scientists at ILL used a technique called “small angle neutron scattering (SANS)” to confirm that it was this clumping of the iron-rich surfactant that brought about its magnetic properties.

Dr Isabelle Grillo, responsible of the Chemistry Laboratories at ILL: “The particles of surfactant in solution are small and thus difficult to see using light but are easily revealed by SANS which we use to investigate the structure and behaviour of all types of materials with typical sizes ranging from the nanometer to the tenth of micrometer.”

The potential applications of magnetic surfactants are huge. Their responsiveness to external stimuli allows a range of properties, such as their electrical conductivity, melting point, the size and shape of aggregates and how readily its dissolves in water to be altered by a simple magnetic on and off switch. Traditionally these factors, which are key to the effective application of soaps in a variety of industrial settings, could only be controlled by adding an electric charge or changing the pH, temperature or pressure of the system, all changes that irreversibly alter the system composition and cost money to remediate.

Its magnetic properties also makes it easier to round up and remove from a system once it has been added, suggesting further applications in environmental clean ups and water treatment. Scientific experiments which require precise control of liquid droplets could also be made easier with the addition of this surfactant and a magnetic field.

Professor Julian Eastoe, University of Bristol: “As most magnets are metals, from a purely scientific point of view these ionic liquid surfactants are highly unusual, making them a particularly interesting discovery. From a commercial point of view, though these exact liquids aren’t yet ready to appear in any household product, by proving that magnetic soaps can be developed, future work can reproduce the same phenomenon in more commercially viable liquids for a range of applications from water treatment to industrial cleaning products.”

Peter Dowding an industrial chemist, not involved in the research: “Any systems which act only when responding to an outside stimulus that has no effect on its composition is a major breakthrough as you can create products which only work when they are needed to. Also the ability to remove the surfactant after it has been added widens the potential applications to environmentally sensitive areas like oil spill clean ups where in the past concerns have been raised.”

Scientists study 'galaxy zoo' using Google Maps and thousands of volunteers

ScienceDaily (Nov. 3, 2011) — The reddest galaxies with the largest central bulb show the largest bars -- gigantic central columns of stars and dark matter -- according to a scientific study that used Google Maps to observe the sky. A group of volunteers of more than 200,000 participants of the galaxy classification project Galaxy Zoo contributed to this research.

More than two thirds of spiral galaxies, including our own Milky Way, display a central bar that can extend for thousands of light years. These colossal elongated structures are made up of collections of stars and dark matter which are held together by gravity.

Now a team of researchers from Europe and the USA have measured the bar length of some 5000 galaxies with the help of amateur astronomers. The most precise results (those obtained for 3150 galaxies) have been published in the Monthly Notices of the Royal Astronomical Society.

The study comes under the Galaxy Zoo project, a citizen science initiative in which more than 200,000 volunteers assisted in classifying a million galaxies through images provided by the Sloan Digital Sky Survey astronomical catalogue. As for the bars, 150 amateur astronomers have recorded their observations on a webpage specifically created for this purpose. The page is currently still active despite being closed to any further data entry.

Ben Hoyle, researcher at the Institute of Cosmos Sciences (University of Barcelona, Spain) and coordinator of the study, stresses that "this webpage combines Galaxy Zoo classifications with Google Maps technology." More precisely, the team has used the Google Maps Sky interface which allows to see the sky, especially the galaxies, as seen from Earth's surface.

The redness of bars

"In this way we have compiled some 16,000 measurements of the bars of 5000 galaxies, which is a sample a hundred times greater than previous ones. We have also come to many different conclusions, such as the fact that redder galaxies, which are stopping star formation, have longer bars," says Hoyle.

In the electromagnetic spectrum, the colour red comes from older, cooler stars whereas the colour blue is linked to hotter and younger stars. The study also reveals that the bars tend to be redder than the rest of the galaxy, which indicates that they have an older stellar population.

Other conclusions indicate that those galaxies with a larger bulb (a central agglomeration of stars) have longer bars. In addition, barred galaxies are more likely to display spiral arms than unbarred galaxies.

The images provide examples of barred galaxies with spiral arms. In the first row, the arms are connected to the ring around the bar. In the second row, the arms are connected at the end of the bar and the third row shows a mixture of the two. Image: Ben Hoyle et al./Galaxy Zoo.

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Journal Reference:

Ben Hoyle, Karen. L. Masters, Robert C. Nichol, Edward M. Edmondson, Arfon M. Smith, Chris Lintott, Ryan Scranton, Steven Bamford, Kevin Schawinski, Daniel Thomas. Galaxy Zoo: bar lengths in local disc galaxies. Monthly Notices of the Royal Astronomical Society, 2011; 415 (4): 3627 DOI: 10.1111/j.1365-2966.2011.18979.x

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Structure, not scientists to blame for Los Alamos failings, article says

ScienceDaily (Nov. 1, 2011) — Policy decisions and poor management have substantially undermined the US Los Alamos National Laboratory -- and, consequently, national security, according to an article available November 1 in the current issue of the Bulletin of the Atomic Scientists, published by SAGE. The article calls into question media and government stereotypes that have blamed Los Alamos's scientists for the decline.

According to George Mason University professor of anthropology and sociology Hugh Gusterson, who has studied America's nuclear weapons scientists since the 1980s, morale at Los Alamos is the worst it has ever been in the lab's seven-decade history. Its ability to function as an institution and to superintend the nuclear stockpile has been substantially eroded, he writes. Driven by a mistaken belief that Los Alamos's organizational culture is characterized by arrogance and carelessness, congressmen and government officials are to blame for framing Los Alamos as an institution in need of reform and for implementing deleterious management practices, which have reduced effectiveness, Gusterson writes.

Gusterson is an expert on nuclear culture, international security, and the anthropology of science. His article, "The assault on Los Alamos National Laboratory: A drama in three acts," highlights the decline of Los Alamos, the famous nuclear laboratory originally established by J. Robert Oppenheimer in the high desert of New Mexico during World War II.

The first phase began with a media circus when Chinese-American scientist Wen Ho Lee's downloaded secret computer codes in 1999. Lee was arrested and charged on 59 counts of mishandling national security information, 58 of which were dropped.

The media reinforced the perception that Lee's behavior was symptomatic of a culture of laxness at Los Alamos. Security was tightened, yet additional disks were misplaced. FBI agents descended on Los Alamos, administering polygraphs to weapons scientists, commandeering their offices, and dragging some from their beds at night for interrogations. The National Nuclear Security Administration was created to superintend weapons labs and General Eugene Habiger was put in charge of security at Los Alamos and the nation's other weapons lab, Lawrence Livermore.

The 2003 appointment of Pete Nanos as director of Los Alamos marked the next phase of decline. After more disks apparently went missing and a student was hit in the eye by a laser beam, Nanos called for swift and extreme action. Calling lab employees "cowboys and buttheads" who thought they were above the rules -- and describing "a culture of arrogance" and "suicidal denial" at a news conference -- he suspended lab operations for up to seven months, forcing employees to retrain and reflect on security practices.

The shutdown cost $370 million. Both Nanos and his actions were deeply unpopular with lab staff. Nanos abruptly resigned in 2005. It turned out the disks had not gone missing, but had in fact never existed. It was an inventory management error. Extreme and destructive acts of cultural reengineering had cost the Los Alamos National Laboratory and, presumably, national security dearly.

Next, instead of renewing the University of California's management contract, the federal government put the contract out to bid. Los Alamos National Security (LANS), a consortium headed by the Bechtel Corporation with the University of California as a junior partner, won the contract in 2005. A year later, it also won the contract to run the lab at Livermore.

To boost profits, Bechtel increased the management fee tenfold, rewarding its senior LANS officials. The budget was static but costs increased, resulting in heavy job losses at the Livermore Laboratory. New managers did not establish the same rapport with scientists as previous managers who had risen through the ranks. Peer reviewed publication output by scientists dropped sharply. But the number and quality of articles published, papers given, and experiments conducted by lab scientists was now irrelevant to the government's evaluation of managerial effectiveness. Scientists were discouraged from raising concerns, which could impact management bonuses.

Gusterson concludes that misattribution of Los Alamos's problems to a pathological organizational culture involved at least two misreadings of the situation: The actions of a rogue individual (Lee) were confused with the informal norms of an entire organization, and the organizational dysfunction at Los Alamos has been misdiagnosed as a problem of culture when it is more likely a problem of structure.

"Having survived the antinuclear protests of the 1980s and the end of the Cold War a few years later, American nuclear weapons scientists are now finding that the main threat to their craft comes from an unexpected source: politicians and administrators who are supposed to be on their side," says Gusterson. "As so often seems to be the case, well-meaning attempts to make the country more secure are having the opposite effect."

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H. Gusterson. The assault on Los Alamos National Laboratory: A drama in three acts. Bulletin of the Atomic Scientists, 2011; 67 (6): 9 DOI: 10.1177/0096340211426631

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Shaken, not stirred: Scientists spy molecular maneuvers

ScienceDaily (Oct. 27, 2011) — Stir this clear liquid in a glass vial and nothing happens. Shake this liquid, and free-floating sheets of protein-like structures emerge, ready to detect molecules or catalyze a reaction. This isn't the latest gadget from James Bond's arsenal -- rather, the latest research from the U. S. Department of Energy (DOE)'s Lawrence Berkeley National Laboratory (Berkeley Lab) scientists unveiling how slim sheets of protein-like structures self-assemble. This "shaken, not stirred" mechanism provides a way to scale up production of these two-dimensional nanosheets for a wide range of applications, such as platforms for sensing, filtration and templating growth of other nanostructures.

"Our findings tell us how to engineer two-dimensional, biomimetic materials with atomic precision in water," said Ron Zuckermann, Director of the Biological Nanostructures Facility at the Molecular Foundry, a DOE nanoscience user facility at Berkeley Lab. "What's more, we can produce these materials for specific applications, such as a platform for sensing molecules or a membrane for filtration."

Zuckermann, who is also a senior scientist at Berkeley Lab, is a pioneer in the development of peptoids, synthetic polymers that behave like naturally occurring proteins without degrading. His group previously discovered peptoids capable of self-assembling into nanoscale ropes, sheets and jaws, accelerating mineral growth and serving as a platform for detecting misfolded proteins.

In this latest study, the team employed a Langmuir-Blodgett trough -- a bath of water with Teflon-coated paddles at either end -- to study how peptoid nanosheets assemble at the surface of the bath, called the air-water interface. By compressing a single layer of peptoid molecules on the surface of water with these paddles, said Babak Sanii, a post-doctoral researcher working with Zuckermann, "we can squeeze this layer to a critical pressure and watch it collapse into a sheet."

"Knowing the mechanism of sheet formation gives us a set of design rules for making these nanomaterials on a much larger scale," added Sanii.

To study how shaking affected sheet formation, the team developed a new device called the SheetRocker to gently rock a vial of peptoids from upright to horizontal and back again. This carefully controlled motion allowed the team to precisely control the process of compression on the air-water interface.

"During shaking, the monolayer of peptoids essentially compresses, pushing chains of peptoids together and squeezing them out into a nanosheet. The air-water interface essentially acts as a catalyst for producing nanosheets in 95% yield," added Zuckermann. "What's more, this process may be general for a wide variety of two-dimensional nanomaterials."

This research is reported in a paper titled, "Shaken, not stirred: Collapsing a peptoid monolayer to produce free-floating, stable nanosheets," appearing in the Journal of the American Chemical Society (JACS) and available in JACS online. Co-authoring the paper with Zuckermann and Sanii were Romas Kudirka, Andrew Cho, Neeraja Venkateswaran, Gloria Olivier, Alexander Olson, Helen Tran, Marika Harada and Li Tan.

This work at the Molecular Foundry was supported by DOE's Office of Science and the Defense Threat Reduction Agency.

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Babak Sanii, Romas Kudirka, Andrew Cho, Neeraja Venkateswaran, Gloria K. Olivier, Alexander M. Olson, Helen Tran, R. Marika Harada, Li Tan, Ronald N. Zuckermann. Shaken, Not Stirred: Collapsing a Peptoid Monolayer To Produce Free-Floating, Stable Nanosheets. Journal of the American Chemical Society, 2011; : 111012114427004 DOI: 10.1021/ja206199d

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Shaken, not stirred: Scientists spy molecular maneuvers

ScienceDaily (Oct. 27, 2011) — Stir this clear liquid in a glass vial and nothing happens. Shake this liquid, and free-floating sheets of protein-like structures emerge, ready to detect molecules or catalyze a reaction. This isn't the latest gadget from James Bond's arsenal -- rather, the latest research from the U. S. Department of Energy (DOE)'s Lawrence Berkeley National Laboratory (Berkeley Lab) scientists unveiling how slim sheets of protein-like structures self-assemble. This "shaken, not stirred" mechanism provides a way to scale up production of these two-dimensional nanosheets for a wide range of applications, such as platforms for sensing, filtration and templating growth of other nanostructures.

"Our findings tell us how to engineer two-dimensional, biomimetic materials with atomic precision in water," said Ron Zuckermann, Director of the Biological Nanostructures Facility at the Molecular Foundry, a DOE nanoscience user facility at Berkeley Lab. "What's more, we can produce these materials for specific applications, such as a platform for sensing molecules or a membrane for filtration."

Zuckermann, who is also a senior scientist at Berkeley Lab, is a pioneer in the development of peptoids, synthetic polymers that behave like naturally occurring proteins without degrading. His group previously discovered peptoids capable of self-assembling into nanoscale ropes, sheets and jaws, accelerating mineral growth and serving as a platform for detecting misfolded proteins.

In this latest study, the team employed a Langmuir-Blodgett trough -- a bath of water with Teflon-coated paddles at either end -- to study how peptoid nanosheets assemble at the surface of the bath, called the air-water interface. By compressing a single layer of peptoid molecules on the surface of water with these paddles, said Babak Sanii, a post-doctoral researcher working with Zuckermann, "we can squeeze this layer to a critical pressure and watch it collapse into a sheet."

"Knowing the mechanism of sheet formation gives us a set of design rules for making these nanomaterials on a much larger scale," added Sanii.

To study how shaking affected sheet formation, the team developed a new device called the SheetRocker to gently rock a vial of peptoids from upright to horizontal and back again. This carefully controlled motion allowed the team to precisely control the process of compression on the air-water interface.

"During shaking, the monolayer of peptoids essentially compresses, pushing chains of peptoids together and squeezing them out into a nanosheet. The air-water interface essentially acts as a catalyst for producing nanosheets in 95% yield," added Zuckermann. "What's more, this process may be general for a wide variety of two-dimensional nanomaterials."

This research is reported in a paper titled, "Shaken, not stirred: Collapsing a peptoid monolayer to produce free-floating, stable nanosheets," appearing in the Journal of the American Chemical Society (JACS) and available in JACS online. Co-authoring the paper with Zuckermann and Sanii were Romas Kudirka, Andrew Cho, Neeraja Venkateswaran, Gloria Olivier, Alexander Olson, Helen Tran, Marika Harada and Li Tan.

This work at the Molecular Foundry was supported by DOE's Office of Science and the Defense Threat Reduction Agency.

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Journal Reference:

Babak Sanii, Romas Kudirka, Andrew Cho, Neeraja Venkateswaran, Gloria K. Olivier, Alexander M. Olson, Helen Tran, R. Marika Harada, Li Tan, Ronald N. Zuckermann. Shaken, Not Stirred: Collapsing a Peptoid Monolayer To Produce Free-Floating, Stable Nanosheets. Journal of the American Chemical Society, 2011; : 111012114427004 DOI: 10.1021/ja206199d

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Electron accelerator scientists report breakthroughs

ScienceDaily (Oct. 25, 2011) — Cornell scientists have surpassed two major scientific milestones toward proving the technology of a novel, exceedingly powerful X-ray source.

For more than a decade, Cornell scientists have been conducting research and development for an Energy Recovery Linac (ERL) electron accelerator that would produce X-ray beams 1,000 times brighter than any in existence.

The university ultimately hopes to use ERL technology to upgrade the Cornell High Energy Synchrotron Source (CHESS), one of five U.S. national facilities for hard X-ray synchrotron radiation research.

The National Science Foundation provided $50 million for 2006-14 to build instrumentation for prototyping and testing ERL concepts proposed by the Cornell team of faculty, students and collaborators. Specifically, the program goals are to prove that electron beams of unmatched quality could be created and accelerated to continuously produce X-ray beams with the laserlike property of coherence. No such X-ray source presently exists.

Cornell's ERL team is now reporting that its prototype electron injector is producing beams with a so-called emittance of 0.8 micrometers -- the smallest ever recorded from an electron source of this type. The injector is the key component needed to make an ERL work by creating electron beams that are tightly packed and traveling at nearly the speed of light. The emittance is a measure of how tightly packed the electron beams are.

This small emittance, say the scientists, proves that the ERL could produce X-ray beams focused down to exceedingly small volumes, allowing investigation of materials with unprecedented precision and speed.

In another breakthrough for the ERL project, the scientists have built and tested a prototype seven-cell superconducting radio frequency (SRF) cavity. SRF cavities are needed to accelerate the electrons from the injector to very high energies in order to produce the X-rays. The SRF cavities are operated at -456 F (-271 C), just 2 degrees above absolute zero temperature.

The Cornell researchers' SRF cavity has met the first performance specifications necessary to continuously power a high intensity ERL. It has been tested in a vertical cryostat at the required temperature and electric field gradients -- a significant milestone because it proves the cavities can perform at high power while within the scientific and cost parameters of the project.

The team must now demonstrate the efficacy of their cavities in horizontal tests, which will take place in 2012.

"These developments go a long way toward proving that an ERL X-ray source will work as predicted by simulations and theory," said Sol Gruner, director of CHESS.

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Electron accelerator scientists report breakthroughs

ScienceDaily (Oct. 25, 2011) — Cornell scientists have surpassed two major scientific milestones toward proving the technology of a novel, exceedingly powerful X-ray source.

For more than a decade, Cornell scientists have been conducting research and development for an Energy Recovery Linac (ERL) electron accelerator that would produce X-ray beams 1,000 times brighter than any in existence.

The university ultimately hopes to use ERL technology to upgrade the Cornell High Energy Synchrotron Source (CHESS), one of five U.S. national facilities for hard X-ray synchrotron radiation research.

The National Science Foundation provided $50 million for 2006-14 to build instrumentation for prototyping and testing ERL concepts proposed by the Cornell team of faculty, students and collaborators. Specifically, the program goals are to prove that electron beams of unmatched quality could be created and accelerated to continuously produce X-ray beams with the laserlike property of coherence. No such X-ray source presently exists.

Cornell's ERL team is now reporting that its prototype electron injector is producing beams with a so-called emittance of 0.8 micrometers -- the smallest ever recorded from an electron source of this type. The injector is the key component needed to make an ERL work by creating electron beams that are tightly packed and traveling at nearly the speed of light. The emittance is a measure of how tightly packed the electron beams are.

This small emittance, say the scientists, proves that the ERL could produce X-ray beams focused down to exceedingly small volumes, allowing investigation of materials with unprecedented precision and speed.

In another breakthrough for the ERL project, the scientists have built and tested a prototype seven-cell superconducting radio frequency (SRF) cavity. SRF cavities are needed to accelerate the electrons from the injector to very high energies in order to produce the X-rays. The SRF cavities are operated at -456 F (-271 C), just 2 degrees above absolute zero temperature.

The Cornell researchers' SRF cavity has met the first performance specifications necessary to continuously power a high intensity ERL. It has been tested in a vertical cryostat at the required temperature and electric field gradients -- a significant milestone because it proves the cavities can perform at high power while within the scientific and cost parameters of the project.

The team must now demonstrate the efficacy of their cavities in horizontal tests, which will take place in 2012.

"These developments go a long way toward proving that an ERL X-ray source will work as predicted by simulations and theory," said Sol Gruner, director of CHESS.

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Scientists discover way to determine when water was present on Mars and Earth

ScienceDaily (Oct. 20, 2011) — The discovery of the mineral jarosite in rocks analyzed by the Mars Rover, Opportunity, on the Martian surface had special meaning for a team of Syracuse University scientists who study the mineral here on Earth. Jarosite can only form in the presence of water. Its presence on Mars means that water had to exist at some point in the past. The trick is in figuring out if jarosite can be used as a proxy for determining when, and under what conditions, water was present on the planet.

The SU scientists have done just that. In a recent study published in an October issue issue of Earth and Planetary Science Letters, Suzanne Baldwin, professor of Earth Sciences in SU's College of Arts and Sciences; and Joseph Kula, research associate and corresponding author for the study, established the "diffusion parameters" for argon in jarosite. In simpler terms, they discovered a way to use the noble gas argon, which accumulates in jarosite over time, to determine the age of the mineral and the surface conditions under which it formed.

The new study is the first in a series of experiments designed to provide a roadmap of sorts for scientists who may someday study Martian samples brought back to Earth. "Our experiments indicate that over billion-year timescales and at surface temperatures of 20 degrees Celsius (68 degrees Fahrenheit) or colder, jarosite will preserve the amount of argon that has accumulated since the crystal formed," Kula says, "which simply means that jarosite is a good marker for measuring the amount of time that has passed since water was present on Mars."

Moreover, since the development of life requires water, knowing when and for how long water was present on the Martian surface has implications for the search for potential habitats harboring life, the scientists say. "Jarosite requires water for its formation, but dry conditions for its preservation," Baldwin says. "We'd like to know when water formed on the surface of Mars and how long it was there. Studying jarosite may help answer some of these questions."

Jarosite is a byproduct of the weathering of rocks exposed at the surface of a planet (such as Earth and Mars). The mineral forms when the right mixture of oxygen, iron, sulfur, potassium and water is present. Once formed, the crystals begin to accumulate argon, which is produced when certain potassium isotopes in the crystals decay. Potassium decay is a radioactive process that occurs at a known rate. By measuring the isotopes of argon trapped within the crystals, scientists can determine the age of the crystals.

However, because argon is a gas, it can potentially escape rapidly from the crystals under hot conditions or slowly over long durations at cold conditions. In order to determine the reliability of the "argon clock" in jarosite, the scientists had to determine the temperature limits to which the crystals could be subjected and still retain the argon. Using a combination of experiments and computer modeling, the team found that argon remains trapped inside the crystals for long periods of time over a range of planetary surface temperatures.

"Our results suggest that 4 billion-year-old jarosite will preserve its argon and, along with it, a record of the climate conditions that existed at the time it formed," Baldwin says. The scientists are in the process of conducting further studies on jarosite that formed less than 50 million years ago in the Big Horn Basin in Wyoming, which they hope will reveal when the minerals formed and how fast environmental conditions changed from water-saturated to dry. The results can be used as a context for interpreting findings on other planets.

Baldwin and Kula are members of the NASA-funded New York Center for Astrobiology at Rensselaer Polytechnic Institute in Troy, N.Y. The center is one of 10 such centers nationally that are part of the NASA Astrobiology Institute, located at NASA's Ames Research Center at Moffett Field, Calif. Their jarosite research is funded by NASA.

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Journal Reference:

Joseph Kula, Suzanne L. Baldwin. Jarosite, argon diffusion, and dating aqueous mineralization on Earth and Mars. Earth and Planetary Science Letters, 2011; 310 (3-4): 314 DOI: 10.1016/j.epsl.2011.08.006

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Scientists release most accurate simulation of the universe to date

ScienceDaily (Sep. 30, 2011) — The Bolshoi supercomputer simulation, the most accurate and detailed large cosmological simulation run to date, gives physicists and astronomers a powerful new tool for understanding such cosmic mysteries as galaxy formation, dark matter, and dark energy.

The simulation traces the evolution of the large-scale structure of the universe, including the evolution and distribution of the dark matter halos in which galaxies coalesced and grew. Initial studies show good agreement between the simulation's predictions and astronomers' observations.

"In one sense, you might think the initial results are a little boring, because they basically show that our standard cosmological model works," said Joel Primack, distinguished professor of physics at the University of California, Santa Cruz. "What's exciting is that we now have this highly accurate simulation that will provide the basis for lots of important new studies in the months and years to come."

Primack and Anatoly Klypin, professor of astronomy at New Mexico State University, lead the team that produced the Bolshoi simulation. Klypin wrote the computer code for the simulation, which was run on the Pleiades supercomputer at NASA Ames Research Center. "These huge cosmological simulations are essential for interpreting the results of ongoing astronomical observations and for planning the new large surveys of the universe that are expected to help determine the nature of the mysterious dark energy," Klypin said.

Primack, who directs the University of California High-Performance Astrocomputing Center (UC-HIPACC), said the initial release of data from the Bolshoi simulation began in early September. "We've released a lot of the data so that other astrophysicists can start to use it," he said. "So far it's less than one percent of the actual output, because the total output is so huge, but there will be additional releases in the future."

The previous benchmark for large-scale cosmological simulations, known as the Millennium Run, has been the basis for some 400 papers since 2005. But the fundamental parameters used as the input for the Millennium Run are now known to be inaccurate. Produced by the Virgo Consortium of mostly European scientists, the Millennium simulation used cosmological parameters based on the first release of data from NASA's Wilkinson Microwave Anisotropy Probe (WMAP). WMAP provided a detailed map of subtle variations in the cosmic microwave background radiation, the primordial radiation left over from the Big Bang. But the initial WMAP1 parameters have been superseded by subsequent releases: WMAP5 (five-year results released in 2008) and WMAP7 (seven-year results released in 2010).

The Bolshoi simulation is based on WMAP5 parameters, which are consistent with the later WMAP7 results. "The WMAP1 cosmological parameters on which the Millennium simulation is based are now known to be wrong," Primack said. "Moreover, advances in supercomputer technology allow us to do a much better simulation with higher resolution by almost an order of magnitude. So I expect the Bolshoi simulation will have a big impact on the field."

The standard explanation for how the universe evolved after the Big Bang is known as the Lambda Cold Dark Matter model, and it is the theoretical basis for the Bolshoi simulation. According to this model, gravity acted initially on slight density fluctuations present shortly after the Big Bang to pull together the first clumps of dark matter. These grew into larger and larger clumps through the hierarchical merging of smaller progenitors. Although the nature of dark matter remains a mystery, it accounts for about 82 percent of the matter in the universe. As a result, the evolution of structure in the universe has been driven by the gravitational interactions of dark matter. The ordinary matter that forms stars and planets has fallen into the "gravitational wells" created by clumps of dark matter, giving rise to galaxies in the centers of dark matter halos.

A principal purpose of the Bolshoi simulation is to compute and model the evolution of dark matter halos. The characteristics of the halos and subhalos in the Bolshoi simulation are presented in a paper that has been accepted for publication in the Astrophysical Journal and is now available online. The authors are Klypin, NMSU graduate student Sebastian Trujillo-Gomez, and Primack.

A second paper, also accepted for publication in the Astrophysical Journal and available online, presents the abundance and properties of galaxies predicted by the Bolshoi simulation of dark matter. The authors are Klypin, Trujillo-Gomez, Primack, and UCSC postdoctoral researcher Aaron Romanowsky. A comparison of the Bolshoi predictions with galaxy observations from the Sloan Digital Sky Survey showed very good agreement, according to Primack.

The Bolshoi simulation focused on a representative section of the universe, computing the evolution of a cubic volume measuring about one billion light-years on a side and following the interactions of 8.6 billion particles of dark matter. It took 6 million CPU-hours to run the full computation on the Pleiades supercomputer, recently ranked as the seventh fastest supercomputer in the world.

A variant of the Bolshoi simulation, known as BigBolshoi or MultiDark, was run on the same supercomputer with the same number of particles, but this time in a volume 64 times larger. BigBolshoi was run to predict the properties and distribution of galaxy clusters and other very large structures in the universe, as well as to help with dark energy projects such as the Baryon Oscillation Spectroscopic Survey (BOSS).

Another variant, called MiniBolshoi, is currently being run on the Pleiades supercomputer. MiniBolshoi focuses on a smaller portion of the universe and provides even higher resolution than Bolshoi. The Bolshoi simulation and its two variants will be made publicly available to astrophysical researchers worldwide in phases via the MultiDark Database, hosted by the Potsdam Astrophysics Institute in Germany and supported by grants from Spain and Germany.

Primack, Klypin, and their collaborators are continuing to analyze the results of the Bolshoi simulation and submit papers for publication. Among their findings are results showing that the simulation correctly predicts the number of galaxies as bright as the Milky Way that have satellite galaxies as bright as the Milky Way's major satellites, the Large and Small Magellanic Clouds.

"A lot more papers are on the way," Primack said.

This research was funded by grants from NASA and the National Science Foundation.

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Scientists observe how superconducting nanowires lose resistance-free state

ScienceDaily (Sep. 22, 2011) — Even with today's invisibility cloaks, people can't walk through walls. But, when paired together, millions of electrons can. The electrons perform this trick, called macroscopic quantum tunneling, when they pair up and move into a region of space that is normally off-limits under the laws of classical mechanics. The problem is that as millions of electrons collectively move through a superconducting nanowire, they use energy and give off heat.

The heat can build, transforming sections of the wire into a non-superconducting state. The process, called a phase slip, adds resistance to an electrical system and has implications for designing new nano-scale superconductors.

Now, scientists have observed individual phase slips in aluminum nanowires and characterized the nature and temperature at which they occur. This information could help scientists remove phase slips from nano-scale systems, which could lead to more reliable nanowires and more efficient nano-electronics, said Duke physicist Albert Chang.

The results appeared online Sept. 21 in Physical Review Letters.

The macroscopic quantum tunneling effect was first observed in a system called a Josephson junction. This device has a thin insulating layer connecting two superconductors, which are several nanometers wide and have a three-dimensional shape.

To study the tunneling and phase slips in a simpler system, however, Chang and his colleagues used individual, one-dimensional nanowires made of aluminum. The new observations are "arguably the first convincing demonstration of tunneling of millions of electrons in one-dimensional superconducting nanowires," said Chang, who led the study.

In the experiment, the wires ranged in length from 1.5 to 10 micrometers, with widths from five to 10 nanometers. Chang cooled the wires to a temperature close to absolute zero, roughly 1 degree Kelvin or -458 degrees Fahrenheit.

At this temperature, a metal's crystal lattice vibrates in a way that allows electrons to overcome their negative repulsion of one other. The electrons make pairs and electric current flows essentially resistance-free, forming a superconductor.

The electron pairs move together in a path in a quantum-mechanical space, which resembles the curled cord of an old phone. On their way around the path, all of the electrons have to scale a barrier or a wall. Moving past this wall collectively keeps the electrons paired and the superconducting current stable.

But, the collective effort takes energy and gives off heat. With successive scaling attempts, the heat builds, causing a section of the wire to experience a phase slip from a superconducting to a non-superconducting state.

To pinpoint precisely how phase slips happen, Chang varied the temperatures and amount of current run through the aluminum nanowires.

The experiments show that at higher temperatures, roughly 1.5 degrees Kelvin and close to the critical temperature where the wires naturally become non-superconducting, the electrons have enough energy to move over the wall that keeps the electrons paired and the superconducting current stable.

In contrast, the electrons in the nanowires cooled to less than 1 degree Kelvin do not have the energy to scale the wall. Instead, the electrons tunnel, or go through the wall together, all at once, said Duke physicist Gleb Finkelstein, one of Chang's collaborators.

The experiments also show that at the relatively higher temperatures, individual jumps over the wall don't create enough heat to cause a breakdown in superconductivity. But multiple jumps do.

At the lowest temperatures, however, the paired electrons only need to experience one successful attempt at the wall, either over or through it, to create enough heat to slip in phase and break the superconducting state.

Studying the electrons' behavior at specific temperatures provides scientists with information to build ultra-thin superconducting wires that might not have phase slips. Chang said the improved wires could soon play a role in ultra-miniaturized electrical components for ultra-miniaturized electronics, such as the quantum bit, used in a quantum computer.

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Journal Reference:

Peng Li, Phillip Wu, Yuriy Bomze, Ivan Borzenets, Gleb Finkelstein, A. Chang. Switching Currents Limited by Single Phase Slips in One-Dimensional Superconducting Al Nanowires. Physical Review Letters, 2011; 107 (13) DOI: 10.1103/PhysRevLett.107.137004

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Scientists release most accurate simulation of the universe to date

ScienceDaily (Sep. 30, 2011) — The Bolshoi supercomputer simulation, the most accurate and detailed large cosmological simulation run to date, gives physicists and astronomers a powerful new tool for understanding such cosmic mysteries as galaxy formation, dark matter, and dark energy.

The simulation traces the evolution of the large-scale structure of the universe, including the evolution and distribution of the dark matter halos in which galaxies coalesced and grew. Initial studies show good agreement between the simulation's predictions and astronomers' observations.

"In one sense, you might think the initial results are a little boring, because they basically show that our standard cosmological model works," said Joel Primack, distinguished professor of physics at the University of California, Santa Cruz. "What's exciting is that we now have this highly accurate simulation that will provide the basis for lots of important new studies in the months and years to come."

Primack and Anatoly Klypin, professor of astronomy at New Mexico State University, lead the team that produced the Bolshoi simulation. Klypin wrote the computer code for the simulation, which was run on the Pleiades supercomputer at NASA Ames Research Center. "These huge cosmological simulations are essential for interpreting the results of ongoing astronomical observations and for planning the new large surveys of the universe that are expected to help determine the nature of the mysterious dark energy," Klypin said.

Primack, who directs the University of California High-Performance Astrocomputing Center (UC-HIPACC), said the initial release of data from the Bolshoi simulation began in early September. "We've released a lot of the data so that other astrophysicists can start to use it," he said. "So far it's less than one percent of the actual output, because the total output is so huge, but there will be additional releases in the future."

The previous benchmark for large-scale cosmological simulations, known as the Millennium Run, has been the basis for some 400 papers since 2005. But the fundamental parameters used as the input for the Millennium Run are now known to be inaccurate. Produced by the Virgo Consortium of mostly European scientists, the Millennium simulation used cosmological parameters based on the first release of data from NASA's Wilkinson Microwave Anisotropy Probe (WMAP). WMAP provided a detailed map of subtle variations in the cosmic microwave background radiation, the primordial radiation left over from the Big Bang. But the initial WMAP1 parameters have been superseded by subsequent releases: WMAP5 (five-year results released in 2008) and WMAP7 (seven-year results released in 2010).

The Bolshoi simulation is based on WMAP5 parameters, which are consistent with the later WMAP7 results. "The WMAP1 cosmological parameters on which the Millennium simulation is based are now known to be wrong," Primack said. "Moreover, advances in supercomputer technology allow us to do a much better simulation with higher resolution by almost an order of magnitude. So I expect the Bolshoi simulation will have a big impact on the field."

The standard explanation for how the universe evolved after the Big Bang is known as the Lambda Cold Dark Matter model, and it is the theoretical basis for the Bolshoi simulation. According to this model, gravity acted initially on slight density fluctuations present shortly after the Big Bang to pull together the first clumps of dark matter. These grew into larger and larger clumps through the hierarchical merging of smaller progenitors. Although the nature of dark matter remains a mystery, it accounts for about 82 percent of the matter in the universe. As a result, the evolution of structure in the universe has been driven by the gravitational interactions of dark matter. The ordinary matter that forms stars and planets has fallen into the "gravitational wells" created by clumps of dark matter, giving rise to galaxies in the centers of dark matter halos.

A principal purpose of the Bolshoi simulation is to compute and model the evolution of dark matter halos. The characteristics of the halos and subhalos in the Bolshoi simulation are presented in a paper that has been accepted for publication in the Astrophysical Journal and is now available online. The authors are Klypin, NMSU graduate student Sebastian Trujillo-Gomez, and Primack.

A second paper, also accepted for publication in the Astrophysical Journal and available online, presents the abundance and properties of galaxies predicted by the Bolshoi simulation of dark matter. The authors are Klypin, Trujillo-Gomez, Primack, and UCSC postdoctoral researcher Aaron Romanowsky. A comparison of the Bolshoi predictions with galaxy observations from the Sloan Digital Sky Survey showed very good agreement, according to Primack.

The Bolshoi simulation focused on a representative section of the universe, computing the evolution of a cubic volume measuring about one billion light-years on a side and following the interactions of 8.6 billion particles of dark matter. It took 6 million CPU-hours to run the full computation on the Pleiades supercomputer, recently ranked as the seventh fastest supercomputer in the world.

A variant of the Bolshoi simulation, known as BigBolshoi or MultiDark, was run on the same supercomputer with the same number of particles, but this time in a volume 64 times larger. BigBolshoi was run to predict the properties and distribution of galaxy clusters and other very large structures in the universe, as well as to help with dark energy projects such as the Baryon Oscillation Spectroscopic Survey (BOSS).

Another variant, called MiniBolshoi, is currently being run on the Pleiades supercomputer. MiniBolshoi focuses on a smaller portion of the universe and provides even higher resolution than Bolshoi. The Bolshoi simulation and its two variants will be made publicly available to astrophysical researchers worldwide in phases via the MultiDark Database, hosted by the Potsdam Astrophysics Institute in Germany and supported by grants from Spain and Germany.

Primack, Klypin, and their collaborators are continuing to analyze the results of the Bolshoi simulation and submit papers for publication. Among their findings are results showing that the simulation correctly predicts the number of galaxies as bright as the Milky Way that have satellite galaxies as bright as the Milky Way's major satellites, the Large and Small Magellanic Clouds.

"A lot more papers are on the way," Primack said.

This research was funded by grants from NASA and the National Science Foundation.

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Scientists play ping-pong with single electrons

ScienceDaily (Sep. 22, 2011) — Scientists at Cambridge University have shown an amazing degree of control over the most fundamental aspect of an electronic circuit, how electrons move from one place to another.

Researchers from the University's Cavendish Laboratory have moved an individual electron along a wire, batting it back and forth over sixty times, rather like the ball in a game of ping-pong. The research findings, published September 22 in the journal Nature, may have applications in quantum computing, transferring a quantum 'bit' between processor and memory, for example.

Imagine you are at a party and you want to get to the other side of a crowded room to talk to someone. As you walk you have to weave around people who are walking, dancing or just standing in the way. You may also have to stop and greet friends along the way and by the time you reach the person you wanted to talk to you have forgotten what you were going to say. Wouldn't it be nice to be lifted up above the crowd, and pushed directly to your destination?

In a similar way, electrons carrying a current along a wire do not go directly from one end to the other but instead follow a complicated zigzag path. This is a problem if the electron is carrying information, as it tends to 'forget' it, or, more scientifically, the quantum state loses coherence.

In this work, a single electron can be trapped in a small well (called a quantum dot), just inside the surface of a piece of Gallium Arsenide (GaAs). A channel leads to another, empty, dot 4 microns (millionths of a metre) away. The channel is higher in energy than the surrounding electrons. A very short burst of sound (just a few billionths of a second long) is then sent along the surface, past the dot. The accompanying wave of electrical potential picks up the electron, which then surfs along the channel to the other dot, where it is captured. A burst of sound sent from the other direction returns the electron to the starting dot where the process can be repeated. The electron goes back and forth like a ping-pong ball. Rallies of up to 60 shots have been achieved before anything goes wrong.

"The movement of electrons by our 'surface acoustic wave' can also be likened to peristalsis in the esophagus, where food is propelled from the mouth to the stomach by a wave of muscle contraction," explains Rob McNeil, the PhD student who did most of the work, helped by postdoc Masaya Kataoka, both at the University of Cambridge's Department of Physics, the Cavendish Laboratory.

"This is an enabling technology for quantum computers," Chris Ford, team leader of the research from the Semiconductor Physics Group in the Cavendish, says. "There is a lot of work going on worldwide to make this new type of computer, which may solve certain complex problems much faster than classical computers. However, little effort has yet been put into connecting up different components, such as processor and memory. Although our experiments do not yet show that electrons 'remember' their quantum state, this is likely to be the case. This would make the method of transfer a candidate for moving quantum bits of information (qubits) around a quantum circuit, in a quantum computer. Indeed, our theorist, Crispin Barnes, proposed using this mechanism to make a whole quantum computer a long time ago, and this is an important step towards that goal."

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The above story is reprinted (with editorial adaptations by ScienceDaily staff) from materials provided by University of Cambridge. The original story is licensed under a Creative Commons license.

Journal Reference:

R. P. G. McNeil, M. Kataoka, C. J. B. Ford, C. H. W. Barnes, D. Anderson, G. A. C. Jones, I. Farrer, D. A. Ritchie. On-demand single-electron transfer between distant quantum dots. Nature, 2011; 477 (7365): 439 DOI: 10.1038/nature10444

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Controlling silicon evaporation allows scientists to boost graphene quality

ScienceDaily (Sep. 22, 2011) — Scientists from the Georgia Institute of Technology have for the first time provided details of their "confinement controlled sublimation" technique for growing high-quality layers of epitaxial graphene on silicon carbide wafers. The technique relies on controlling the vapor pressure of gas-phase silicon in the high-temperature furnace used for fabricating the material.

The basic principle for growing thin layers of graphene on silicon carbide requires heating the material to about 1,500 degrees Celsius under high vacuum. The heat drives off the silicon, leaving behind one or more layers of graphene. But uncontrolled evaporation of silicon can produce poor quality material useless to designers of electronic devices.

"For growing high-quality graphene on silicon carbide, controlling the evaporation of silicon at just the right temperature is essential," said Walt de Heer, a professor who pioneered the technique in the Georgia Tech School of Physics. "By precisely controlling the rate at which silicon comes off the wafer, we can control the rate at which graphene is produced. That allows us to produce very nice layers of epitaxial graphene."

De Heer and his team begin by placing a silicon carbide wafer into an enclosure made of graphite. A small hole in the container controls the escape of silicon atoms as the one-square-centimeter wafer is heated, maintaining the rate of silicon evaporation and condensation near its thermal equilibrium. The growth of epitaxial graphene can be done in a vacuum or in the presence of an inert gas such as argon, and can be used to produce both single layers and multiple layers of the material.

"This technique seems to be completely in line with what people might one day do in fabrication facilities," de Heer said. "We believe this is quite significant in allowing us to rationally and reproducibly grow graphene on silicon carbide. We feel we now understand the process, and believe it could be scaled up for electronics manufacturing."

The technique for growing large-area layers of epitaxial graphene was described this week in the Early Edition of the journal Proceedings of the National Academy of Sciences. The research has been supported by the National Science Foundation through the Georgia Tech Materials Research Science and Engineering Center (MRSEC), the Air Force Office of Scientific Research, and the W.M. Keck Foundation.

The paper also describes a technique for growing narrow graphene ribbons, a process de Heer's group has called "templated growth." That technique, which could be useful for making graphene interconnects, was first described in October 2010 in the journal Nature Nanotechnology.

The templated growth technique involves etching patterns into silicon carbide surfaces using conventional nanolithography processes. The patterns serve as templates directing the growth of graphene structures on portions of the patterned surfaces. The technique forms nanoribbons of specific widths without the use of electron beams or other destructive cutting techniques. Graphene nanoribbons produced with these templates have smooth edges that avoid problems with electron scattering.

Together, the two techniques provide researchers with the flexibility to produce graphene in forms appropriate to different needs, de Heer noted. Large-area sheets of graphene may be grown on both the carbon-terminated and silicon-terminated sides of a silicon carbide wafer, while the narrow ribbons may be grown on the silicon-terminated side. Because of different processing techniques, only one side of a particular wafer can be used.

The Georgia Tech research team -- which includes Claire Berger, Ming Ruan, Mike Sprinkle, Xuebin Li, Yike Hu, Baiqian Zhang, John Hankinson and Edward Conrad -- has so far fabricated structures as narrow as 10 nanometers using the templated growth technique. These nanowires exhibit interesting quantum transport properties.

"We can make very good quantum wires using the templated growth technique," de Heer said. "We can make large structures and devices that demonstrate the Quantum Hall Effect, which is important for many applications. We have demonstrated that templated growth can go all the way down to the nanoscale, and that the properties get even better there."

Development of the sublimation technique arose from efforts to protect the growing graphene from oxygen and other contaminants in the furnace. To address the quality concerns, the research team tried enclosing the wafer in a graphite container from which some silicon gas was permitted to leak out.

"We soon realized that graphene grown in the container was much better than what we had been producing," de Heer recalled. "Originally, we thought it was because we were protecting it from contaminants. Later, we realized it was because we were controlling the evaporation of silicon."

Epitaxial graphene may be the basis for a new generation of high-performance devices that will take advantage of the material's unique properties in applications where higher costs can be justified. Silicon, today's electronic material of choice, will continue to be used in applications where high-performance is not required, de Heer said.

Though researchers are still struggling to design nanometer-scale epitaxial graphene devices that take advantage of the material's unique properties, de Heer is confident that will ultimately be done.

"These techniques allow us to make accurate nanostructures and seem to be very promising for making the nanoscale devices that we need," he said. "While there are serious challenges ahead for using graphene in electronics, we have overcome roadblocks before."

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The above story is reprinted (with editorial adaptations by ScienceDaily staff) from materials provided by Georgia Institute of Technology Research News. The original article was written by John Toon.

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Scientists and engineers create the 'perfect plastic'

ScienceDaily (Sep. 30, 2011) — Researchers at the University of Leeds and Durham University have solved a long-standing problem that could revolutionize the way new plastics are developed. The breakthrough will allow experts to create the 'perfect plastic' with specific uses and properties by using a high-tech 'recipe book.' It will also increase our ability to recycle plastics. The research paper is published in the journal Science on September 29.

The paper's authors form part of the Microscale Polymer Processing project, a collaboration between academics and industry experts which has spent 10 years exploring how to better build giant 'macromolecules.' These long tangled molecules are the basic components of plastics and dictate their properties during the melting, flowing and forming processes in plastics production.

Low-density polyethylenes (LDPEs) are used in trays and containers, lightweight car parts, recyclable packaging and electrical goods. Up until now, industry developed a plastic then found a use for it, or tried hundreds of different "recipes" to see which worked. This method could save the manufacturing industry time, energy and money.

The mathematical models used put together two pieces of computer code. The first predicts how polymers will flow based on the connections between the string-like molecules they are made from. A second piece of code predicts the shapes that these molecules will take when they are created at a chemical level. These models were enhanced by experiments on carefully synthesised 'perfect polymers' created in labs of the Microscale Polymer Processing project.

Dr. Daniel Read, from the School of Mathematics, University of Leeds, who led the research, said, "Plastics are used by everybody, every day, but until now their production has been effectively guesswork. This breakthrough means that new plastics can be created more efficiently and with a specific use in mind, with benefits to industry and the environment."

Professor Tom McLeish, formerly of the University of Leeds, now Pro-Vice Chancellor for Research at Durham University leads the Microscale Polymer Processing project. He said, "After years of trying different chemical recipes and finding only a very few provide useable products, this new science provides industry with a toolkit to bring new materials to market faster and more efficiently."

Professor McLeish added that as plastics production moves from oil-based materials to sustainable and renewable materials, the "trial and error" phase in developing new plastics could now be by-passed. He said, "By changing two or three numbers in the computer code, we can adapt all the predictions for new bio-polymer sources."

"This is a wonderful outcome of years of work by this extraordinary team. It's a testimony to the strong collaborative ethos of the UK research groups and global companies involved," he added.

Dr. Ian Robinson of Lucite International, one of the industrial participants in the wider project said, "The insights offered by this approach are comparable to cracking a plastics 'DNA.'"

The model was developed by Dr. Daniel Read, School of Mathematics, University of Leeds, Dr. Chinmay Das of the School of Physics & Astronomy, University of Leeds and Professor Tom McLeish, Department of Physics, Durham University. Their predictions were compared to the results of polymer analysis by Dr. Dietmar Auhl, at the time a physicist at Leeds.

The research was carried out at the University of Leeds, Durham University, LyondellBasell and Dow Chemical and was funded by the Engineering and Physical Sciences Research Council and the European Union.

The Microscale Polymer Processing collaboration includes researchers from the universities of Durham, Bradford, Cambridge, Leeds, Nottingham, Oxford, Reading, Sheffield and University College London alongside their industry counterparts from Lucite International, Ineos, LyondellBasell, BASF, Dow Chemical, DSM, and Mitsubishi.

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The above story is reprinted (with editorial adaptations by ScienceDaily staff) from materials provided by University of Leeds, via EurekAlert!, a service of AAAS.

Journal Reference:

D. J. Read, D. Auhl, C. Das, J. den Doelder, M. Kapnistos, I. Vittorias, T. C. B. McLeish. Linking Models of Polymerization and Dynamics to Predict Branched Polymer Structure and Flow. Science, 2011; 333 (6051): 1871 DOI: 10.1126/science.1207060

Note: If no author is given, the source is cited instead.

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Scientists and engineers create the 'perfect plastic'

ScienceDaily (Sep. 30, 2011) — Researchers at the University of Leeds and Durham University have solved a long-standing problem that could revolutionize the way new plastics are developed. The breakthrough will allow experts to create the 'perfect plastic' with specific uses and properties by using a high-tech 'recipe book.' It will also increase our ability to recycle plastics. The research paper is published in the journal Science on September 29.

The paper's authors form part of the Microscale Polymer Processing project, a collaboration between academics and industry experts which has spent 10 years exploring how to better build giant 'macromolecules.' These long tangled molecules are the basic components of plastics and dictate their properties during the melting, flowing and forming processes in plastics production.

Low-density polyethylenes (LDPEs) are used in trays and containers, lightweight car parts, recyclable packaging and electrical goods. Up until now, industry developed a plastic then found a use for it, or tried hundreds of different "recipes" to see which worked. This method could save the manufacturing industry time, energy and money.

The mathematical models used put together two pieces of computer code. The first predicts how polymers will flow based on the connections between the string-like molecules they are made from. A second piece of code predicts the shapes that these molecules will take when they are created at a chemical level. These models were enhanced by experiments on carefully synthesised 'perfect polymers' created in labs of the Microscale Polymer Processing project.

Dr. Daniel Read, from the School of Mathematics, University of Leeds, who led the research, said, "Plastics are used by everybody, every day, but until now their production has been effectively guesswork. This breakthrough means that new plastics can be created more efficiently and with a specific use in mind, with benefits to industry and the environment."

Professor Tom McLeish, formerly of the University of Leeds, now Pro-Vice Chancellor for Research at Durham University leads the Microscale Polymer Processing project. He said, "After years of trying different chemical recipes and finding only a very few provide useable products, this new science provides industry with a toolkit to bring new materials to market faster and more efficiently."

Professor McLeish added that as plastics production moves from oil-based materials to sustainable and renewable materials, the "trial and error" phase in developing new plastics could now be by-passed. He said, "By changing two or three numbers in the computer code, we can adapt all the predictions for new bio-polymer sources."

"This is a wonderful outcome of years of work by this extraordinary team. It's a testimony to the strong collaborative ethos of the UK research groups and global companies involved," he added.

Dr. Ian Robinson of Lucite International, one of the industrial participants in the wider project said, "The insights offered by this approach are comparable to cracking a plastics 'DNA.'"

The model was developed by Dr. Daniel Read, School of Mathematics, University of Leeds, Dr. Chinmay Das of the School of Physics & Astronomy, University of Leeds and Professor Tom McLeish, Department of Physics, Durham University. Their predictions were compared to the results of polymer analysis by Dr. Dietmar Auhl, at the time a physicist at Leeds.

The research was carried out at the University of Leeds, Durham University, LyondellBasell and Dow Chemical and was funded by the Engineering and Physical Sciences Research Council and the European Union.

The Microscale Polymer Processing collaboration includes researchers from the universities of Durham, Bradford, Cambridge, Leeds, Nottingham, Oxford, Reading, Sheffield and University College London alongside their industry counterparts from Lucite International, Ineos, LyondellBasell, BASF, Dow Chemical, DSM, and Mitsubishi.

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The above story is reprinted (with editorial adaptations by ScienceDaily staff) from materials provided by University of Leeds, via EurekAlert!, a service of AAAS.

Journal Reference:

D. J. Read, D. Auhl, C. Das, J. den Doelder, M. Kapnistos, I. Vittorias, T. C. B. McLeish. Linking Models of Polymerization and Dynamics to Predict Branched Polymer Structure and Flow. Science, 2011; 333 (6051): 1871 DOI: 10.1126/science.1207060

Note: If no author is given, the source is cited instead.

Disclaimer: Views expressed in this article do not necessarily reflect those of ScienceDaily or its staff.

View the original article here

Scientists observe how superconducting nanowires lose resistance-free state

ScienceDaily (Sep. 22, 2011) — Even with today's invisibility cloaks, people can't walk through walls. But, when paired together, millions of electrons can. The electrons perform this trick, called macroscopic quantum tunneling, when they pair up and move into a region of space that is normally off-limits under the laws of classical mechanics. The problem is that as millions of electrons collectively move through a superconducting nanowire, they use energy and give off heat.

The heat can build, transforming sections of the wire into a non-superconducting state. The process, called a phase slip, adds resistance to an electrical system and has implications for designing new nano-scale superconductors.

Now, scientists have observed individual phase slips in aluminum nanowires and characterized the nature and temperature at which they occur. This information could help scientists remove phase slips from nano-scale systems, which could lead to more reliable nanowires and more efficient nano-electronics, said Duke physicist Albert Chang.

The results appeared online Sept. 21 in Physical Review Letters.

The macroscopic quantum tunneling effect was first observed in a system called a Josephson junction. This device has a thin insulating layer connecting two superconductors, which are several nanometers wide and have a three-dimensional shape.

To study the tunneling and phase slips in a simpler system, however, Chang and his colleagues used individual, one-dimensional nanowires made of aluminum. The new observations are "arguably the first convincing demonstration of tunneling of millions of electrons in one-dimensional superconducting nanowires," said Chang, who led the study.

In the experiment, the wires ranged in length from 1.5 to 10 micrometers, with widths from five to 10 nanometers. Chang cooled the wires to a temperature close to absolute zero, roughly 1 degree Kelvin or -458 degrees Fahrenheit.

At this temperature, a metal's crystal lattice vibrates in a way that allows electrons to overcome their negative repulsion of one other. The electrons make pairs and electric current flows essentially resistance-free, forming a superconductor.

The electron pairs move together in a path in a quantum-mechanical space, which resembles the curled cord of an old phone. On their way around the path, all of the electrons have to scale a barrier or a wall. Moving past this wall collectively keeps the electrons paired and the superconducting current stable.

But, the collective effort takes energy and gives off heat. With successive scaling attempts, the heat builds, causing a section of the wire to experience a phase slip from a superconducting to a non-superconducting state.

To pinpoint precisely how phase slips happen, Chang varied the temperatures and amount of current run through the aluminum nanowires.

The experiments show that at higher temperatures, roughly 1.5 degrees Kelvin and close to the critical temperature where the wires naturally become non-superconducting, the electrons have enough energy to move over the wall that keeps the electrons paired and the superconducting current stable.

In contrast, the electrons in the nanowires cooled to less than 1 degree Kelvin do not have the energy to scale the wall. Instead, the electrons tunnel, or go through the wall together, all at once, said Duke physicist Gleb Finkelstein, one of Chang's collaborators.

The experiments also show that at the relatively higher temperatures, individual jumps over the wall don't create enough heat to cause a breakdown in superconductivity. But multiple jumps do.

At the lowest temperatures, however, the paired electrons only need to experience one successful attempt at the wall, either over or through it, to create enough heat to slip in phase and break the superconducting state.

Studying the electrons' behavior at specific temperatures provides scientists with information to build ultra-thin superconducting wires that might not have phase slips. Chang said the improved wires could soon play a role in ultra-miniaturized electrical components for ultra-miniaturized electronics, such as the quantum bit, used in a quantum computer.

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The above story is reprinted (with editorial adaptations by ScienceDaily staff) from materials provided by Duke University.

Journal Reference:

Peng Li, Phillip Wu, Yuriy Bomze, Ivan Borzenets, Gleb Finkelstein, A. Chang. Switching Currents Limited by Single Phase Slips in One-Dimensional Superconducting Al Nanowires. Physical Review Letters, 2011; 107 (13) DOI: 10.1103/PhysRevLett.107.137004

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